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White-color luminescence from a single material with harmony between order- and disorder-structures of luminogen aggregates

Research Project

Project/Area Number 15K05613
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionRitsumeikan University

Principal Investigator

TSUTSUMI Osamu  立命館大学, 生命科学部, 教授 (00313370)

Co-Investigator(Kenkyū-buntansha) 山田 重之  京都工芸繊維大学, 分子化学系, 助教 (10612252)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords発光 / 高分子 / 液晶 / 錯体 / 凝集誘起発光 / 発光材料
Outline of Final Research Achievements

Highly luminescent materials are of great interest for use in light-emitting devices. However, the luminescence intensity of most organic molecules is abruptly reduced in condensed phases owing to aggregation-caused quenching. Recently, some types of organic molecules have shown strong photoluminescence in the condensed phase, where aggregation enhanced the photoluminescence through a phenomenon called aggregation-induced emission (AIE). The structure of their molecular aggregates, as well as their own molecular structure, must strongly affect the luminescence of AIE materials. We have developed liquid-crystalline (LC) luminophores with the AIE property (AIEgen). We observed that acrylate polymers having an LC AIEgen in their side chain changed the luminescent color from blue to white by the glassy-to-LC phase transition.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (64 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (7 results) Journal Article (13 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 4 results,  Open Access: 1 results) Presentation (39 results) (of which Int'l Joint Research: 12 results,  Invited: 9 results) Remarks (3 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] Indian Institute of Technology Hyderabad(インド)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Assiut University (エジプト)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Indian Institute of Technology Hyderabad(インド)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Ecole Normale Superieure Paris-Saclay(フランス)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] University of Picardie Jules Verne/Ecole Normale Suprerieure de Cachan(フランス)

    • Related Report
      2015 Research-status Report
  • [Int'l Joint Research] IIT Hyderabad(インド)

    • Related Report
      2015 Research-status Report
  • [Int'l Joint Research] LG化学(韓国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Color tuning donor-acceptor-type azobenzene dyes by controlling the molecular geometry of the donor moiety2018

    • Author(s)
      Yamada Shigeyuki、Bessho Junko、Nakasato Hitoya、Tsutsumi Osamu
    • Journal Title

      Dyes and Pigments

      Volume: 150 Pages: 89-96

    • DOI

      10.1016/j.dyepig.2017.11.002

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Aromatic Core and Flexible Terminal Chain Structures on the Properties of Luminous Liquid-Crystalline Gold(I) Complexes for Functional Materials2018

    • Author(s)
      Anukul Preyanuch, Nana Sugimoto, Kaho Sakamoto, Yuki Rokusha, Kensuke Taneki, Kaori Fujisawa, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst, Liq. Cryst.

      Volume: - Issue: 1 Pages: 176-187

    • DOI

      10.1080/15421406.2018.1467615

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoluminescence Behavior of Liquid-Crystalline Gold(I) Complexes with Siloxane Group Controlled by Molecular Aggregated Structures in Condensed Phases2018

    • Author(s)
      Kaori Fujisawa, Fumika Mitsuhashi, Anukul Preeyanuch, Kensuke Taneki, Osama Younis, Osamu Tsutsumi
    • Journal Title

      Polym. J.

      Volume: - Issue: 8 Pages: 761-769

    • DOI

      10.1038/s41428-018-0060-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 白色発光を示す高分子化合物の開発2018

    • Author(s)
      三ッ橋史香,藤澤香織,堤治
    • Journal Title

      現代化学

      Volume: 4月号 Pages: 29-33

    • NAID

      40021493610

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 発光団の凝集構造制御による多色・白色発光材料の開発2018

    • Author(s)
      堤治,三ッ橋史香
    • Journal Title

      液晶

      Volume: -

    • NAID

      40021642756

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 凝集構造による発光挙動制御2018

    • Author(s)
      三ッ橋史香,藤澤香織,堤治
    • Journal Title

      プラスチック

      Volume: 5月号 Pages: 45-48

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Electron-density distribution tuning for enhanced thermal stability of luminescent gold complexes2017

    • Author(s)
      Yamada Shigeyuki、Yamaguchi Shun、Tsutsumi Osamu
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 5 Issue: 31 Pages: 7977-7984

    • DOI

      10.1039/c7tc00728k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesogenic Gold Complexes Showing Aggregation-Induced Enhancement of Phosphorescence in Both Crystalline and Liquid-Crystalline Phases2016

    • Author(s)
      Shigeyuki Yamada, Yuki Rokusha, Ryo Kawano, Kaori Fujisawa, and Osamu Tsutsumi
    • Journal Title

      Faraday Discussions

      Volume: 196 Pages: 269-283

    • DOI

      10.1039/c6fd00157b

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoluminescence from Au(I) Complexes Exhibiting Color Sensitivity to the Structure of the Molecular Aggregates2016

    • Author(s)
      Ryo Kawano, Osama Younis, Akihiro Ando, Yuki Rokusha, Shigeyuki Yamada, Osamu Tsutsumi
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 1 Pages: 66-68

    • DOI

      10.1246/cl.150944

    • NAID

      130005118760

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effects of molecular structure and aggregated structure on photoluminescence properties of liquid-crystalline gold(I) complexes with various aromatic rings2015

    • Author(s)
      Osama Younis, Yuki Rokusha, Nana Sugimoto, Kaori Fujisawa, Shigeyuki Yamada, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 617 Pages: 21-31

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hierarchical Self-Assembly of Oxomolybdate Monomers into a Stable Polyoxomolybdate Crystal with an Ordered Nanochannel Array2015

    • Author(s)
      Ryohei Watanabe, Kenjiro Uno, Makoto Muto, Shigeyuki Yamada, Osamu Tsutsumi
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 617 Issue: 1 Pages: 32-39

    • DOI

      10.1080/15421406.2015.1075368

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 金錯体を用いる新規発光材料の精密発光制御2015

    • Author(s)
      山田重之,堤 治
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 60 Pages: 573-581

    • Related Report
      2015 Research-status Report
  • [Journal Article] 機能材料としての金錯体―分子凝集によって制御可能な金錯体の発光挙動2015

    • Author(s)
      山田重之,堤 治
    • Journal Title

      化学

      Volume: 70 Pages: 70-71

    • Related Report
      2015 Research-status Report
  • [Presentation] 発光性金錯体の結晶化による発光色制御2018

    • Author(s)
      黒田由紀,中田真菜美,藤澤香織,堤治,川畑美絵,飴山恵
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラル液晶高分子の発光特性2018

    • Author(s)
      原田祥平,三ツ橋史香,藤澤香織,堤治
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photo Luminescence and Thermal Stability of Cyclic Tri Nuclear Gold (I) Complexes with N-Heterocyclic Carbene Ligand2018

    • Author(s)
      Arruri Sathyanarayana, Shin-ya Nakamura, Osamu Tsutsumi, Katam Srinivas, Ganesan Prabusankar
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液晶性を示す非π-共役系金錯体の発光挙動2018

    • Author(s)
      尾崎和久,新見涼子,藤澤香織,堤治
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] コレステリック液晶エラストマーのメカノオプティカル機能2018

    • Author(s)
      木村聖哉,具教先,藤澤香織,堤治,赤松範久,宍戸厚
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Solid-state white-light emission from single luminophore2018

    • Author(s)
      Osama Younis, Osamu Tsutsumi,
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 混合原子価金(I/III)錯体の凝集誘起発光挙動2018

    • Author(s)
      玉木優作,藤澤香織,堤治
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ソフトロボティクスを志向した応力・ひずみセンシングポリマーの開発2017

    • Author(s)
      堤治,木村聖哉
    • Organizer
      ソフトロボット:メカニカル材料シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Aggregation-Controlled Emission: Full-Color and White-Color Luminescence from a Single Liquid-Crystalline AIEgen2017

    • Author(s)
      Osamu Tsutsumi, Osama Younis, Fumika Mitsuhashi, Manami Nakata
    • Organizer
      9th International Conference on Materials for Advanced Technologies (The 3rd International Symposium on Aggregation-Induced Emission: Materials, Mechanisms and Applications)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子凝集制御を基盤とした機能性材料の創製2017

    • Author(s)
      堤治
    • Organizer
      機能性フィルム研究会2017年関西例会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Aggregation-Induced Emission from Liquid Crystals Controlled by Nano-Structure of Material2017

    • Author(s)
      Osamu Tsutsumi, Preeyanuch Anukul, Osama M. Younis, Fumika Mitsuhashi, Namami Nakata, Kaho Sakamoto
    • Organizer
      The 39th PIERS in Singapore
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単一化合物のみで白色発光を示す高分子液晶の凝集構造と発光挙動の相関2017

    • Author(s)
      三ッ橋史香,Younis Osama,工藤利輝,堤治
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photoluminescence Behavior of Rod-Shaped Gold(I) Complexes in Chiral Nematic Liquid Crystal2017

    • Author(s)
      Preeyanuch Anukul, Kaho Sakamoto and Osamu Tsutsumi
    • Organizer
      The 21st International Symposium on Advanced Display Materials & Devices
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 発光性金錯体の光物性と酸化数および凝集構造の相関2017

    • Author(s)
      玉木優作,堤治
    • Organizer
      錯体化学会第67回討論会,
    • Related Report
      2017 Annual Research Report
  • [Presentation] NHC金錯体の凝集構造に依存する発光特性2017

    • Author(s)
      中村晋也, Arruri Sathyanarayana, Katam Srinivas, Ganesan Prabusankar, 堤治
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液晶性金錯体のキラルネマチック液晶相における特異な発光挙動2017

    • Author(s)
      坂本果穂,Anukul Preeyanuch,堤治
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis and Luminescence Behavior of Trinuclear Gold NHC Complexes2017

    • Author(s)
      Arruri Sathyanarayana, Shin-ya Nakamura, Katam Srinivas, Ganesan Prabusankar, Osamu Tsutsumi
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液晶性発光団の凝集構造により誘起される側鎖型高分子の白色発光2017

    • Author(s)
      三ッ橋史香,Younis Osama,堤治
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] コレステリック液晶エラストマーのひずみ応答に伴う光学物性変化2017

    • Author(s)
      木村聖哉,堤治
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] White-Color Luminescence from a Single Liquid-Crystalline Polymer Exhibiting Color Sensitivity to the Aggregated Structure of Luminophores2017

    • Author(s)
      Osama Younis, Fumika Mitsuhashi, Osamu Tsutsumi
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 結晶サイズによる三核金錯体の固体発光挙動の制御2017

    • Author(s)
      中田真菜美,黒田由紀,堤治,太田美絵,飴山恵
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] コレステリック液晶エラストマーを用いたメカノオプティカル材料の創製2017

    • Author(s)
      木村聖哉,堤治
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 凝集構造制御による単一液晶性高分子の固体白色発光2017

    • Author(s)
      三ッ橋史香,Younis Osama,堤治
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金(III)錯体の凝集誘起発光挙動2017

    • Author(s)
      玉木優作,堤治
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Enhanced Photoluminescence of Rod-Shaped Gold(I) Complexes in Chiral Nematic Liquid-Crystalline Phase2017

    • Author(s)
      Preeyanuch Anukul, Kaho Sakamoto and Osamu Tsutsumi,
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mesogenic gold complexes showing aggregation-induced enhancement of phosphorescence in both crystalline and liquid- crystalline phases2016

    • Author(s)
      Shigeyuki Yamada, Yuki Rokusha, Ryo Kawano, Kaori Fujisawa, Osamu Tsutsumi
    • Organizer
      Aggregation Induced Emission: Faraday Discussion
    • Place of Presentation
      Guangzhou, China
    • Year and Date
      2016-11-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金錯体を導入した低分子ゲル化剤の発光特性2016

    • Author(s)
      福原良太,堤治
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都,江戸川区)
    • Year and Date
      2016-11-15
    • Related Report
      2016 Research-status Report
  • [Presentation] 機能材料としての遷移金属錯体:分子構造と分子凝集構造制御により創発する材料物性2016

    • Author(s)
      堤治
    • Organizer
      第42回 高分子講座
    • Place of Presentation
      岡山大学理学部(岡山県,岡山市)
    • Year and Date
      2016-09-30
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] White-Color Luminescence from a Single Polymer Material: Controlling the Luminescent Color with External Stimuli2016

    • Author(s)
      Osama Younis, Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      65th Symposium on Macromolecules, Society of Polymer Science
    • Place of Presentation
      Kanagawa University(Kanagawa,横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Luminous Gold Complexes Exhibiting Color Sensitivity to Structure of Molecular Aggregates2016

    • Author(s)
      Osamu Tsutsumi, Osama Younis, Shigeyuki Yamada
    • Organizer
      42nd International Conference on Coordination Chemistry (ICCC2016)
    • Place of Presentation
      Brest, France
    • Year and Date
      2016-07-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 凝集構造によって機能をチューニングできる発光材料の開発2016

    • Author(s)
      堤 治,山田重之
    • Organizer
      日本学術振興会 情報科学用有機材料142委員会
    • Place of Presentation
      森戸記念館第一フォーラム(東京都新宿区)
    • Year and Date
      2016-01-26
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] White-color emitting polymer materials containing liquid-crystalline gold complexes2015

    • Author(s)
      Osamu Tsutsumi, Osama Younis, Sho Tamai, Shigeyuki Yamada
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Perfluoroalkyl-substituted rod-shaped gold(I) complexes as new solid-state luminescent materials2015

    • Author(s)
      Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Luminescence from Liquid-Crystalline Gold Complexes Controlled by Aggregated Structure2015

    • Author(s)
      Osamu Tsutsumi, Osama Younis, Shigeyuki Yamada
    • Organizer
      Creating a Smart Life: 2015 Symposium of Smart Sensor and Its Application in Kitchen
    • Place of Presentation
      Xinxing, China
    • Year and Date
      2015-11-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Aggregation Controlled Luminescence of Liquid-Crystalline Gold Complexes2015

    • Author(s)
      Osamu Tsutsumi, Osama Younis, Shigeyuki Yamada
    • Organizer
      The international Conference on Small Science 2015
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2015-11-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 1)β-シトロネロールを柔軟鎖とした液晶性キラル金錯体の相転移挙動と発光特性2015

    • Author(s)
      坂本果穂,杉本菜々,山田重之,堤治
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Aggregation-Controlled White-Color Emission from a Single Polymer Material with Liquid-Crystalline Au Coplexes2015

    • Author(s)
      Osama Younis, Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県奈良市)
    • Year and Date
      2015-09-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Aggregation-Controlled Emission from Liquid-Crystalline Gold Complexes2015

    • Author(s)
      Osamu Tsutsumi
    • Organizer
      錯体化学会第65回討論会 シンポジウムS1 “The state of the art metal cluster chemistry: from synthetic methodology to new functionality”
    • Place of Presentation
      奈良女子大学(奈良)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Efficient Deep-Blue Emission from Liquid-Crystalline Polymers in Solid State2015

    • Author(s)
      Osama Younis, Shigeyuki Yamada, Osamu Tsutsumi
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 高分子材料化学研究室

    • Related Report
      2017 Annual Research Report
  • [Remarks] 高分子材料化学研究室

    • URL

      http://www.ritsumei.ac.jp/lifescience/achem/tsutsumi/jpn/index.html

    • Related Report
      2016 Research-status Report
  • [Remarks] 高分子材料化学研究室(堤研究室)|立命館大学

    • URL

      http://www.ritsumei.ac.jp/lifescience/achem/tsutsumi/

    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 円偏光発光用組成物2018

    • Inventor(s)
      堤治,坂本果穂,Anukul Preeyanuch
    • Industrial Property Rights Holder
      学校法人立命館
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-025262
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] フォトルミネッセント材料として有用なポリマー2016

    • Inventor(s)
      堤治,オサマ モハマド ユーニス
    • Industrial Property Rights Holder
      学校法人 立命館
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-142396
    • Filing Date
      2016-07-20
    • Related Report
      2016 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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