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Simulation study of the dynamics of entangled polymers under fast flow

Research Project

Project/Area Number 15K05619
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionYamagata University

Principal Investigator

Takimoto Junichi  山形大学, 大学院有機材料システム研究科, 教授 (50261714)

Co-Investigator(Kenkyū-buntansha) SUKUMARAN S.K.  山形大学, 大学院有機材料システム研究科, 准教授 (70598177)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords高分子ダイナミクス / 高速ずり流動 / 絡み合い / 回転運動 / 応力緩和 / 誘電緩和 / 分子動力学 / ずり流動 / 伸長流動 / 絡み合い高分子 / 分子動力学シミュレーション
Outline of Final Research Achievements

Entangled polymer chains relax by escaping from the entanglements by reptation motion under equilibrium. If flow faster than this relaxation is applied, it is believed that the chains are pulled out from the entanglements by flow and the relaxation is accelerated. This acceleration (known as CCR) is now considered as an essential ingredient of the polymer dynamics. In this study, we have shown by numerical simulation that stress and dielectric relaxations are indeed accelerated by flow. It is also found that polymer chains are rotating under shear flow, with the rotation frequency proportional to the square root of the shear rate.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (31 results)

All 2018 2017 2016 2015

All Journal Article (11 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Open Access: 7 results) Presentation (20 results) (of which Int'l Joint Research: 12 results,  Invited: 2 results)

  • [Journal Article] Re-examination of the effect of the Stretch/Orientation-Induced Reduction of Friction under Equi-biaxial Elongational Flow via Primitive Chain Network Simulation using Two Definitions of Orientation Anisotropy2018

    • Author(s)
      K. Takeda, Sathish K. Sukumaran, M. Sugimoto, K. Koyama, Y. Masubuchi
    • Journal Title

      日本レオロジー学会誌

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rheology and Foaming of Long-chain Branched Ethylene- tetrafluoroethylene Copolymer and its Blends2018

    • Author(s)
      E. Nishi, T. Satou, S. K. Sukumaran, T. Katou, M. Sugimoto, K. Koyama
    • Journal Title

      International Polymer Processing

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the particle diameter of the chemical forming agent on the forming process and cellular structure of one-shot compression molded polyethylene foams2018

    • Author(s)
      Junichiro Tateishi, Tyuyoshi Nishiwaki, Sathish K. Sukumaran, Masataka Sugimoto
    • Journal Title

      J. Polym. Eng.,

      Volume: 38 Pages: 41-50

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ジビニルモノマー変成エチレン-テトラフルオロエチレンのレオロジー挙動2017

    • Author(s)
      Eiichi Nishi, Takashi Satou, Satoru Imai, Sathish K. Sukumaran, Masataka Sugimoto, Kiyohito Koyama
    • Journal Title

      成形加工

      Volume: 29 Issue: 3 Pages: 97-102

    • DOI

      10.4325/seikeikakou.29.97

    • NAID

      130006694628

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Simulation Studies of the Rheology of Entangled Polymers2017

    • Author(s)
      Takimoto Jun-ichi
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 44 Issue: 5 Pages: 223-229

    • DOI

      10.1678/rheology.44.223

    • NAID

      130005290711

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2017 Annual Research Report
    • Open Access
  • [Journal Article] Effect of the particle diameter of the chemical foaming agent on the foaming process and the cellular structure of one-shot compression molded polyethylene foams2017

    • Author(s)
      Junichiro Tateishi, Tsuyoshi Nishiwaki, Sathish K. Sukumaran, Masataka Sugimoto
    • Journal Title

      Journal of Polymer Engineering

      Volume: 印刷中 Issue: 1 Pages: 41-50

    • DOI

      10.1515/polyeng-2016-0411

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Melt Rheology of Ethylen-tetrafluoroethylene (ETFE) Modified by Divinyl Monomer2017

    • Author(s)
      Eiichi Nishi, Takashi Satou, Satoru Imai, Sathish K. Sukumaran, Masataka Sugimoto, Kiyohito Koyama
    • Journal Title

      Seikei Kakou

      Volume: 29 Pages: 97-102

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Topological Analysis of Entanglements in Polymeric Liquids2016

    • Author(s)
      Sathish K. Sukumaran
    • Journal Title

      Sen'i Gakkaishi

      Volume: 72 Issue: 12 Pages: P-563-P-564

    • DOI

      10.2115/fiber.72.P-563

    • NAID

      130005250963

    • ISSN
      0037-9875, 1884-2259
    • Related Report
      2016 Research-status Report
    • Open Access
  • [Journal Article] シミュレーションに基づく絡み合い高分子のレオロジーの研究2016

    • Author(s)
      滝本淳一
    • Journal Title

      日本レオロジー学会誌

      Volume: 44 Pages: 23-229

    • Related Report
      2016 Research-status Report
    • Open Access
  • [Journal Article] Test of the Stretch/Orientation-Induced Reduction of Friction for Biaxial Elongational Flow via Primitive Chain Network Simulation2015

    • Author(s)
      Keiko Takeda, Sathish Kumar Sukumaran, Masataka Sugimoto, Kiyohito Koyama, Yuichi Masubuchi
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 43 Issue: 3_4 Pages: 63-39

    • DOI

      10.1678/rheology.43.63

    • NAID

      130005097256

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Primitive chain network simulations for elongational viscosity of bidisperse polystyrene melts2015

    • Author(s)
      K. Takeda, S. K. Sukumaran, M. Sugimoto, K. Koyama, Y. Masubuchi
    • Journal Title

      Advanced Modeling and Simulation in Engineering Sciences

      Volume: 2 Issue: 1 Pages: 11-24

    • DOI

      10.1186/s40323-015-0035-7

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Stress relaxation of polymer melts under fast shear flow: a simulation study2018

    • Author(s)
      Jun-ichi Takimoto
    • Organizer
      Annual European Rheology Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diffusion of particles in polymer melts under fast shear flow: a simulation study2017

    • Author(s)
      Yutaro Mori
    • Organizer
      12th International Workshop for East Asian Young Rheologists
    • Place of Presentation
      Ambassador City Jomtien Hotel, タイ
    • Year and Date
      2017-02-10
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Entanglements in polymer blends: insights from molecular simulations2017

    • Author(s)
      S. K. Sukumaran
    • Organizer
      Complex Fluids, CompFlu-2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子溶融体のずり流動下での応力緩和のシミュレーションによる研究2017

    • Author(s)
      滝本淳一
    • Organizer
      第65回レオロジー討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子液体中の粒子のずり流動下での拡散のシミュレーションによる研究2016

    • Author(s)
      森祐太郎
    • Organizer
      第64回レオロジー討論会
    • Place of Presentation
      大坂大学
    • Year and Date
      2016-10-29
    • Related Report
      2016 Research-status Report
  • [Presentation] Slip and Roughness at the Interface between Immiscible Polymer Liquids2016

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      4th International Conference on Smart Systems Engineering
    • Place of Presentation
      山形大学
    • Year and Date
      2016-10-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ずり流動が高分子溶融体中の粒子拡散に与える影響の シミュレーションによる研究2016

    • Author(s)
      森祐太郎
    • Organizer
      平成28年度繊維学会秋期研究発表会
    • Place of Presentation
      山形大学
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] 高速ずり流動下での高分子鎖の回転運動2016

    • Author(s)
      滝本淳一
    • Organizer
      平成28年度繊維学会秋期研究発表会
    • Place of Presentation
      山形大学
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] 相溶高分子ブレンドにおける絡み合い2016

    • Author(s)
      滝本淳一
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Correlation between Chains and Coarsegraining in Entangled Polymer Liquids2016

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      XVIIth international Congress on Rheology
    • Place of Presentation
      京都テルサ
    • Year and Date
      2016-08-12
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Simulation Study of Rotation of Polymer Chains under Fast Shear Flow2016

    • Author(s)
      Jun-ichi Takimoto
    • Organizer
      XVIIth international Congress on Rheology
    • Place of Presentation
      京都テルサ
    • Year and Date
      2016-08-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Slip and Roughness at the Interface between Polymeric Liquids during Capillary Flow2016

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      32nd PPS International Conference
    • Place of Presentation
      Lyon Convention Centre, フランス
    • Year and Date
      2016-07-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] シミュレーションに基づく絡み合い高分子のレオロジーに関する研究2016

    • Author(s)
      滝本淳一
    • Organizer
      日本レオロジー学会43回年会
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2016-06-12
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Entanglements in binary polymer blends: Mixing rules for blends of flexible and stiff polymers2016

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      Complex Fluid: CompFlu-2016
    • Place of Presentation
      Indian Institute of Science Education and Research (インド)
    • Year and Date
      2016-01-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Rotational motion of polymer chains under simple shear flow2015

    • Author(s)
      Jun-ichi Takimoto
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ハワイ・コンベンションセンター(アメリカ合衆国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Primitive path analysis of entanglements in polymer blends2015

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ハワイ・コンベンションセンター(アメリカ合衆国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高速ずり流動下での分子鎖の回転と誘電緩和2015

    • Author(s)
      瀧本淳一
    • Organizer
      第63回レオロジー討論会
    • Place of Presentation
      神戸大学
    • Year and Date
      2015-09-23
    • Related Report
      2015 Research-status Report
  • [Presentation] Structure of entanglements in binary blends: Mixing rules for blends of flexible and stiff polymers2015

    • Author(s)
      Sathish K. Sukumaran
    • Organizer
      International Symposium on Rheology
    • Place of Presentation
      神戸大学
    • Year and Date
      2015-09-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Rotation of polymer chains under fast shear flow2015

    • Author(s)
      Jun-ichi Takimoto
    • Organizer
      PPS 31
    • Place of Presentation
      International Convention Center JEJU(韓国)
    • Year and Date
      2015-06-09
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高速ずり流動下での高分子鎖の回転運動2015

    • Author(s)
      瀧本淳一
    • Organizer
      日本レオロジー学会42回年会
    • Place of Presentation
      京都大学・宇治キャンパス
    • Year and Date
      2015-05-14
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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