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Nano-pore size control and crash by Laplace-pressure in fibers

Research Project

Project/Area Number 15K05624
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionGifu University

Principal Investigator

TAKENO Akiyoshi  岐阜大学, 工学部, 教授 (70227049)

Co-Investigator(Kenkyū-buntansha) 高橋 紳矢  岐阜大学, 工学部, 助教 (40377700)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsナノ多孔 / ポリプロピレン / ラプラス圧 / 電池セパレータ / アスタキサンチン / クレーズ / ヒーリング温度 / 多孔繊維 / リチウムイオン電池セパレータ / メソポーラス / 薬剤固定 / 繊維 / フィルム / 気体透過性 / 液体透過性 / ボイド
Outline of Final Research Achievements

The pore size of voids in crazed polypropylene (PP) was controlled by Laplace-pressure. Void diameter decreased and dropped out at 100 degrees lower temperature from the melting point of PP. These crazed PP are adequate to various supporting materials of functional matter for the application. we attempted to control the pore size by Laplace-pressure and support various matters in polymer. We investigated to extend the craze area for high porosity. New voids were generated and grown around existing voids, and the number of voids per unit area was increased while maintaining the average void diameter. Healing temperature (Pore diameter decreasing temperature) of the crazed PP films by Laplace-pressure was 60 °C in air, however 110-135 °C in electrolytic solutions. This craze healing temperature depended on the interface tension. These Nano porous PP fibers were composited astaxanthine which is carotenoid group and antioxidation for cosmetic and supplement items.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2018 2017 2016 2015

All Journal Article (1 results) Presentation (16 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] クレーズによる多孔高分子フイルムの作製技術と特徴2018

    • Author(s)
      武野明義
    • Journal Title

      工業材料

      Volume: 66(3) Pages: 21-25

    • Related Report
      2017 Annual Research Report
  • [Presentation] Growth of craze phase and control of void diameter by Laplace-pressure in crazing films2018

    • Author(s)
      Yui HORIGUCHI, Shinpei TSUZI, Shinya TAKAHASHI and Akiyoshi TAKENO
    • Organizer
      the 10th International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials (ISplasma2018)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 自由に開閉できるナノの孔を持つ繊維クレーズナノ多孔ファイバー2018

    • Author(s)
      武野明義
    • Organizer
      岐阜地域産学官連携交流会
    • Related Report
      2017 Annual Research Report
  • [Presentation] プラスチックの白化現象クレージングを利用した多孔フィルム2017

    • Author(s)
      武野明義
    • Organizer
      イノベーション・ジャパン2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] クレーズによる多孔高分子フィルムの界面とその応用2017

    • Author(s)
      武野明義
    • Organizer
      粘着研究会第155回例会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] クレージングフィルムの細孔特性評価と電池セパレーターへの応用2017

    • Author(s)
      堀口結以、辻真平、高橋紳矢、武野明義
    • Organizer
      第47回繊維学会夏季セミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] 表面形状や厚さの異なる高分子フィルムに生じるクレーズの複合性2017

    • Author(s)
      青山洸樹,高橋紳矢,武野明義
    • Organizer
      第47回繊維学会夏季セミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] ラプラス圧による孔径制御と電池セパレーターへの応用2017

    • Author(s)
      堀口結以、辻 真平、高橋紳矢、武野明義
    • Organizer
      平成29年度繊維学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Orientation control of polypropylene film by crystal nucleating agent and healing properties of craze phase2017

    • Author(s)
      Yui Horiguchi, Shinya TakahashiI and Akiyoshi Takeno
    • Organizer
      Chonnam National University - Gifu Univerity Joint Symposium
    • Place of Presentation
      Gifu
    • Related Report
      2016 Research-status Report
  • [Presentation] Healing properties of crazed porous polypropylene - Application to the battery separator -2016

    • Author(s)
      Akiyoshi Takeno, Shinpei Tsuji
    • Organizer
      Malaysia-Thailand-Japan International Conference on Science and Technology
    • Place of Presentation
      Malaysia
    • Year and Date
      2016-09-28
    • Related Report
      2016 Research-status Report
  • [Presentation] クレーズ相のボイドにはたらくラプラス圧と多孔ポリプロピレンの特性2016

    • Author(s)
      堀口結以,三谷亮,高橋紳矢,武野明義
    • Organizer
      日本接着学会
    • Place of Presentation
      東京
    • Year and Date
      2016-06-16
    • Related Report
      2016 Research-status Report
  • [Presentation] クレーズ相のボイドに働くラプラス圧と多孔ポリプロピレンの力学特性2016

    • Author(s)
      堀口結以, 三谷亮, 高橋紳矢, 武野明義
    • Organizer
      繊維学会
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Research-status Report
  • [Presentation] クレーズ相による電池セパレータフィルムの気体透過性の改善2015

    • Author(s)
      辻 真平、高橋 紳矢、武野 明義
    • Organizer
      接着学会(中部支部)
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
  • [Presentation] Molecular orientation control by crystal nucleating agent and healing property of craze phase2015

    • Author(s)
      Yui HORIGUCHI, Shinya TAKAHASHI and Akiyoshi TAKENO
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Hawaii Convention Center(Hawaii,USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 針状核剤を用いた高分子中の高次構造制御および多孔化2015

    • Author(s)
      堀口結以、高橋紳矢、武野明義
    • Organizer
      繊維学会(東海支部)
    • Place of Presentation
      金城学院大学(愛知県名古屋市)
    • Year and Date
      2015-12-12
    • Related Report
      2015 Research-status Report
  • [Presentation] クレーズナノ多孔ファイバー2015

    • Author(s)
      武野明義
    • Organizer
      岐阜テクノフェア2015
    • Place of Presentation
      メモリアルセンター(岐阜県岐阜市)
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 電池セパレータフィルムの気体透過性向 とクレーズ相のボイド構造2015

    • Author(s)
      辻 真平、高橋 紳矢、武野 明義
    • Organizer
      繊維学会
    • Place of Presentation
      京都工芸繊維大学(京都府京都市)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 微多孔性フィルム及びその製造方法並びに電池用セパレータ2017

    • Inventor(s)
      武野明義
    • Industrial Property Rights Holder
      国立大学法人岐阜大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-099376
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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