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Effects of addition of topological molecules on crystallization of polymers

Research Project

Project/Area Number 15K05634
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionThe University of Shiga Prefecture

Principal Investigator

TAKESHITA Hiroki  滋賀県立大学, 工学部, 准教授 (80313568)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords高分子 / 結晶化 / トポロジカル分子 / SAXS / 球晶成長 / 環状高分子 / 星型高分子 / 小角X線散乱 / 核形成 / 高分子ブレンド / からみ合い
Outline of Final Research Achievements

Effects of addition of cyclic and star-shaped poly(ethylene glycol) (PEG) were investigated for crystallization of linear PEG.
While, by the addition of cyclic and star-shaped PEG, crystal structure and higher-order structure were not effected, crystallization kinetics strongly showed strong dependence on the addition of such topological molecules.
Addition of cyclic molecules suppressed the growth rate of the spherulite, especially for a cyclic PEG with a certain molecular weight. This may be because of increase of entanglement by topological effects.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (9 results)

All 2018 2017 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (7 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Anionic polymerization of 2-hexyl[3]dendralene2018

    • Author(s)
      Y, Takamura, K. Takenaka, T. Toda, H. Takeshita, M. Miya, T. Shiomi
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 219 Issue: 1 Pages: 1700046-1700046

    • DOI

      10.1002/macp.201700046

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 高分子マイクロゲル濃厚分散系のコロイド結晶化過程2017

    • Author(s)
      園田浩平、竹下宏樹、徳満勝久
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子マイクロゲル濃厚分散系のコロイドガラス化挙動2017

    • Author(s)
      柴崎和樹、竹下宏樹、徳満勝久
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子の結晶化における環状分子添加の効果2017

    • Author(s)
      竹下宏樹、土田紗栄、伊藤博俊、徳満勝久
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report 2016 Research-status Report
  • [Presentation] 高分子マイクロゲルのコロイド結晶化動力学と構造形成2017

    • Author(s)
      柴崎和樹、竹下宏樹、徳満勝久
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子マイクロゲル分散系の流動性と粒子拡散挙動2017

    • Author(s)
      柴﨑 和樹、竹下 宏樹、徳満 勝久、平尾 浩一
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子マイクロゲル濃厚分散系におけるコロイド結晶化挙動2017

    • Author(s)
      竹下宏樹、園田浩平、柴﨑和樹、徳満勝久
    • Organizer
      成形加工シンポジア’17
    • Related Report
      2017 Annual Research Report
  • [Presentation] 放射光 SAXS によるナノサイズ相空間内における液晶相転移と配向挙動
2017

    • Author(s)
      竹下 宏樹、稲畑 哲、徳満 勝久、竹中 克彦、塩見 友雄
    • Organizer
      第60回放射線化学討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Remarks] 滋賀県立大学工学部材料科学科有機複合材料研究室

    • URL

      http://www.mat.usp.ac.jp/polymer-composite/

    • Related Report
      2017 Annual Research Report 2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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