• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Polymerization of surface-functionalized monodisperse nanoparticles and synthesis of porous solids

Research Project

Project/Area Number 15K05640
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionYokohama National University

Principal Investigator

Yoshitake Hideaki  横浜国立大学, 大学院工学研究院, 教授 (20230716)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords微粒子重合 / メソ細孔性シリカ / 粉体混合 / メソ細孔性物質 / 表面反応 / 固体反応 / シリカ粒子重合 / 固体表面間反応 / 低温固体反応 / mesoporous materails / silane
Outline of Final Research Achievements

Two kinds of monodisperse silica nanoparticles were functionalized with different organosilanes, whose organic groups can mutually be reacted. These silica paritcles were reacted by mortar-and-pestle mixing at room temperature. The polymerization of nanoparticles was confirmed by SEM and nitrogen adsorption/desorption. The combination of 20 nm-silica and 100 nm-silica nanoparticles provided a new mesoporous structure, while the mixing did not occur in the nanoscopic level for the same silica nanoparticles without functionalization. This is one of the best ways to reduce the surface energy and to mix two kinds of silica nanoparticles uniformly. Most of the amino functional groups in the organic chains were active for the adsorption of aqueous heavy metal ions and a high adsorption capacity was obtained.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (6 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (5 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Polysilsesquioxanes with mixed self-assembled organic tethers: Alkyl chains and alkanoate-aminopropyl pairs2016

    • Author(s)
      H. Yoshitake, T. Kodate, T.Takagi, I. Kawamura, A. Naito
    • Journal Title

      Reactive and Functional Polymers

      Volume: 99 Pages: 9-16

    • DOI

      10.1016/j.reactfunctpolym.2015.12.002

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 有機修飾単分散シリカ微粒子間の表面反応によるポーラス物質の合成2017

    • Author(s)
      福田圭佑, 吉武英昭
    • Organizer
      横浜国立大学横浜市立大学 第12回ナノテク交流シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機修飾単分散シリカ微粒子間の表面反応によるメソポーラス物質2017

    • Author(s)
      福田圭佑・吉武英昭
    • Organizer
      第33回ゼオライト研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Polymerization of silica nanoparticles into mesoporous solids2016

    • Author(s)
      Hideaki Yoshitake, Shun-ichiro Koga, Keisuke Fukuda
    • Organizer
      18th International Zeolite Conference, (IZC18)
    • Place of Presentation
      Rio de Janeiro
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Polymerization of silica nanoparticles into mesoporous solids2016

    • Author(s)
      Hideaki Yoshitake, Shun-ichiro Koga, Keisuke Fukuda
    • Organizer
      18th International Zeolite Conference
    • Place of Presentation
      Rio de Janeiro
    • Year and Date
      2016-06-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Reactions of alpha, beta-unsaturated aldehydes in methanol on mesoporous2015

    • Author(s)
      Shota Kenjo, Hideaki Yoshitake
    • Organizer
      International Mesostructured Materials Symposium 9
    • Place of Presentation
      Brisbane Convention and Exhibition Centre
    • Year and Date
      2015-08-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi