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Development of nanostructural controlled silver bromide/silver phosphate thin films as a photo-anode for water splitting under visible-light

Research Project

Project/Area Number 15K05642
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionMie University

Principal Investigator

Katsumata Hideyuki  三重大学, 工学研究科, 准教授 (10335143)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsリン酸銀薄膜 / ナノ構造制御 / 光アノード / 水分解 / 可視光応答 / 光触媒 / 水素生成 / リン酸銀 / 可視光 / 臭化銀 / 薄膜
Outline of Final Research Achievements

A facile and efficient process for the large-scale synthesis of Ag3PO4 cube structures thin films exposed with {100} facets was prepared by the direct oxidation of Ag foils with H2O2 at room temperature. The photoelectrochemical performance of the thin film electrodes for water splitting that took place in Na2HPO4 aqueous solution was strongly dependent on the polyvinylpyrrolidone concentration used for the direct oxidation process. The photo-anode exhibited the bandgap of 2.2 eV and high photocatalytic efficiency, as well as an incident photon-to-current conversion efficiency (IPCE) of 57%, for the photoelectrochemical oxidation of water.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (43 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 2 results) Presentation (37 results) (of which Int'l Joint Research: 23 results,  Invited: 3 results)

  • [Journal Article] Visible-Light-Induced AgI/Bi7O9I3 Composites with Enhanced Photocatalytic Activity2017

    • Author(s)
      Tateishi Ikki、Katsumata Hideyuki、Suzuki Tohru、Kaneco Satoshi
    • Journal Title

      Catalysis Letters

      Volume: 147 Issue: 6 Pages: 1503-1509

    • DOI

      10.1007/s10562-017-2059-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Z-scheme photocatalytic activity of g-C 3 N 4 /tetrahedral Ag 3 PO 4 hybrids under visible light2017

    • Author(s)
      Tateishi Ikki、Katsumata Hideyuki、Suzuki Tohru、Kaneco Satoshi
    • Journal Title

      Materials Letters

      Volume: 201 Pages: 66-69

    • DOI

      10.1016/j.matlet.2017.04.138

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Visible-Light-Driven Photocatalytic H2Production Using Carbon Particle/g-C3N4Photocatalysts with an Electron Donor2017

    • Author(s)
      Nakai Yuto、Katsumata Hideyuki、Suzuki Tohru、Kaneco Satoshi
    • Journal Title

      ECS Transactions

      Volume: 75 Issue: 50 Pages: 75-84

    • DOI

      10.1149/07550.0075ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Photocatalytic Activity of Phosphorus-Chlorine Codoped Graphitic Carbon Nitride under Visible Light Irradiation2017

    • Author(s)
      Mitsuyama Tomoki、Katsumata Hideyuki、Suzuki Tohru、Kaneco Satoshi
    • Journal Title

      ECS Transactions

      Volume: 75 Issue: 50 Pages: 47-56

    • DOI

      10.1149/07550.0047ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Photocatalytic Hydrogen Production over PdS@CdS+ZnS(en)0.5 Photocatalyst under Visible Light Irradiation2015

    • Author(s)
      H. Katsumata, H. Ando, T. Suzuki, S. Kaneco
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 54 Issue: 13 Pages: 3532-3535

    • DOI

      10.1021/acs.iecr.5b00451

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] AgI/Ag3PO4 hybrids with highly efficient visible-light driven photocatalytic activity2015

    • Author(s)
      H. Katsumata, T. Hayashi, M. Taniguchi, T. Suzuki, S. Kaneco
    • Journal Title

      Materials Research Bulletin

      Volume: 63 Pages: 116-122

    • DOI

      10.1016/j.materresbull.2014.11.040

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 塩基処理炭素粒子担持グラファイト状窒化炭素による可視光水分解2017

    • Author(s)
      中井優人・勝又英之・鈴木透・古川真衣・金子聡
    • Organizer
      第36回分析化学中部夏期セミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] Cu,Ni-dopedCd0.5Zn0.5S 光触媒を用いた水素生成法の開発2017

    • Author(s)
      坂本惇平・勝又英之・鈴木透・古川真衣・ 金子聡
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Bi4NbO8Cl ヘテロ接合光触媒の可視光活性2017

    • Author(s)
      辻本駿弥・勝又英之・鈴木透・古川真衣・ 金子聡
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 光触媒薄膜による環境問題解決の糸口2017

    • Author(s)
      勝又英之
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 尿素から合成した g-C3N4の光触媒活性2017

    • Author(s)
      東史哉・勝又英之・鈴木透・古川真衣・ 金子聡
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 塩基処理炭素粒子担持窒化炭素による光触媒的水素生成法の開発2017

    • Author(s)
      中井優人・勝又英之・鈴木透・古川真衣・ 金子聡
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Facile Preparation of Nanostructural Controlled Ag3PO4 Photo-Anodes for Enhanced Photoelectrochemical Water Splitting under Visible-Light2017

    • Author(s)
      H. Katsumata, T. Suzuki, S. Kaneco
    • Organizer
      The 2nd International Conference on Material and Chemical Engineering
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced Photocatalytic Activity of Alkaline Treated Carbon Dots/g-C3N42017

    • Author(s)
      Y. Nakai, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      The 2nd International Conference on Material and Chemical Engineering
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic Activity of g-C3N4 Synthesized from Urea2017

    • Author(s)
      F. Higashi, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      The 2nd International Conference on Material and Chemical Engineering
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced Photocatalytic Hydrogen Production Over Alkaline treated Carbon particles / g-C3N4 Composite Under Visible Light Irradiation2017

    • Author(s)
      Y. Nakai, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      13th IUPAC International Conference on Novel Materials and their Synthesis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic H2 production with Cu, Ni-codoped Cd0.5Zn0.5S2017

    • Author(s)
      J. Sakamoto, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      13th IUPAC International Conference on Novel Materials and their Synthesis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visible Light Activity of Bi4NbO8Cl-based Heterojunction Photocatalysts2017

    • Author(s)
      S. Tsujimoto, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      13th IUPAC International Conference on Novel Materials and their Synthesis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Nitrogen Deficient Hydroxy Group Doped g-C3N4 and Photocatalytic Activity2017

    • Author(s)
      F. Higashi, H. Katsumata, T. Suzuki, M. Furukawa, S. Kaneco
    • Organizer
      13th IUPAC International Conference on Novel Materials and their Synthesis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of nanostructural controlled silver phosphate thin films as a photo-anode for water splitting under visible-light2016

    • Author(s)
      Hideyuki Katsumata; Takahiro Hayashi; Tohru Suzuki; Satoshi Kaneco
    • Organizer
      The 13th Asian Conference on Analytical Sciences
    • Place of Presentation
      Chiang Mai (Thailand)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhanced photocatalytic activity of carbon particles loading g-C3N42016

    • Author(s)
      Yuto Nakai; Hideyuki Katsumata; Tohru Suzuki; Satoshi Kaneco
    • Organizer
      The 13th Asian Conference on Analytical Sciences
    • Place of Presentation
      Chiang Mai (Thailand)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhanced photocatalytic activity of P, Cl-modified graphitic carbon nitride under visible light irradiation2016

    • Author(s)
      Tomoki Mitsuyama; Hideyuki Katsumata; Tohru Suzuki; Satoshi Kaneco
    • Organizer
      The 13th Asian Conference on Analytical Sciences
    • Place of Presentation
      Chiang Mai (Thailand)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Band-gap Engineering of Cu, Ca-doped ZnIn2S4 photocatalysts for highly efficient visible light hydrogen production2016

    • Author(s)
      Ikki Tateishi; Hideyuki Katsumata; Tohru Suzuki; Satoshi Kaneco
    • Organizer
      The 13th Asian Conference on Analytical Sciences
    • Place of Presentation
      Chiang Mai (Thailand)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Zn(1-2x)(CuCa)xIn2S4による可視光下水素生成能向上研究2016

    • Author(s)
      立石一希・勝又英之・鈴木 透・金子 聡
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県・豊橋市)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 非金属ドープされたグラファイト状窒化炭素の光触媒活性の向上2016

    • Author(s)
      三ツ山智貴・勝又英之・鈴木 透・金子 聡
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県・豊橋市)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 炭素粒子担持による窒化炭素の光触媒活性の向上2016

    • Author(s)
      中井 優人・ 勝又 英之・ 鈴木 透・ 金子 聡
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県・豊橋市)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] リン酸銀ベースハイブリッド光触媒の合成と可視光活性2016

    • Author(s)
      松田 隼門・ 勝又 英之・ 鈴木 透・ 金子 聡
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県・豊橋市)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Highly efficient photocatalytic activity of Ag3PO4-based photocatalysts under visible light2016

    • Author(s)
      Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco
    • Organizer
      IUPAC 12th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      Changsha (China)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly efficient H2 production over carbon dots/g-C3N4 hybrids under visible light irradiation2016

    • Author(s)
      Yuto Nakai, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco
    • Organizer
      IUPAC 12th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      Changsha (China)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhancement of photocatalytic H2 evolution on photoresponsive ZnIn2S4 doped with Cu and Ca2016

    • Author(s)
      Ikki Tateishi, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco
    • Organizer
      IUPAC 12th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      Changsha (China)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhaced photocatalytic sctivity of non-metal doped graphitic carbon nitride2016

    • Author(s)
      Tomoki Mitsuyama, Hideyuki Katsumata, Tohru Suzuki, and Satoshi Kaneco
    • Organizer
      IUPAC 12th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      Changsha (China)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Enhanced Photocatalytic Activity of Phosphorus-Doped Graphitic Carbon Nitride Under Visible Light Irradiation2016

    • Author(s)
      Tomoki Mitsuyama, Hideyuki Katsumata, Tohru Suzuki, and Satoshi Kaneco
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Highly Efficient Visible-Light Driven Carbon Particles/g-C3N4 Photocatalysts with Enhanced Photocatalytic H2 Production2016

    • Author(s)
      Yuto Nakai, Hideyuki Katsumata, Tohru Suzuki, and Satoshi Kaneco
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] PHOTOCATALYTIC HYDROGEN PRODUCTION OVER CARBON PARTICLES/G-C3N4 UNDER VISIBLE LIGHT2016

    • Author(s)
      Yuto Nakai, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco
    • Organizer
      3rd International Conference on Engineering Technology
    • Place of Presentation
      Kemaman (Malaysia)
    • Year and Date
      2016-08-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] PHOTOCATALYTIC DEGRADATION OF BISPHENOL A OVER AGI/BISMUTH OXY IODIDES2016

    • Author(s)
      Hideyuki Katsumata; Takahiro Sasaki; Tohru Suzuki; Satoshi Kaneco
    • Organizer
      3rd International Conference on Engineering Technology
    • Place of Presentation
      Kemaman (Malaysia)
    • Year and Date
      2016-08-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] MoS2/g-C3N4/Ag3PO4三元系光触媒の可視光活性2016

    • Author(s)
      松田 隼門・ 勝又 英之・ 鈴木 透・ 金子 聡
    • Organizer
      第76回分析化学討論会
    • Place of Presentation
      岐阜薬科大学(岐阜県・岐阜市)
    • Year and Date
      2016-05-28
    • Related Report
      2016 Research-status Report
  • [Presentation] 炭素粒子担持窒化炭素による光触媒的水素生成2016

    • Author(s)
      中井 優人・ 勝又 英之・ 鈴木 透・ 金子 聡
    • Organizer
      第76回分析化学討論会
    • Place of Presentation
      岐阜薬科大学(岐阜県・岐阜市)
    • Year and Date
      2016-05-28
    • Related Report
      2016 Research-status Report
  • [Presentation] Synthesis of N-Defect and O-Doping g-C3N4 and its Visible Light Photocatalytic Activity2015

    • Author(s)
      T. Mitsuyama, H. Katsumata, T. Suzuki, S. Kaneco
    • Organizer
      International Chemical Congress of Pacific Basin Societies (PACIFICHEM)
    • Place of Presentation
      Hawaii (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 有機-無機ハイブリッド光触媒の合成とその分析化学的特徴2015

    • Author(s)
      勝又英之・鈴木透・金子聡
    • Organizer
      第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学(三重県・津市)
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Photocatalytic Degradation of Bisphenol A over AgI/Bi7O9I32015

    • Author(s)
      T. Sasaki, H. Katsumata, T. Suzuki, S. Kaneco
    • Organizer
      11th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XI)
    • Place of Presentation
      Qinhuangdao (China)
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic H2 Prodcution with WO3/G-C3N4 Composite from Aqueous Solution2015

    • Author(s)
      Y. Tachi, H. Katsumata, T. Suzuki, S. Kaneco
    • Organizer
      11th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XI
    • Place of Presentation
      Qinhuangdao (China)
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic H2 Production of Cu and Ga Doped ZnIn2S4 under Visible Light Irradiation2015

    • Author(s)
      I. Tateishi, H. Katsumata, T. Suzuki, S. Kaneco
    • Organizer
      11th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XI
    • Place of Presentation
      Qinhuangdao (China)
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] グラファイト状窒化炭素を用いた水の分解による水素生成2015

    • Author(s)
      舘裕介・勝又英之・鈴木透・金子聡
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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