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Diffusion and Reaction between Bismuth-based Lead-free Piezoelectric Ceramics and Electrodes

Research Project

Project/Area Number 15K05667
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionTokyo University of Science

Principal Investigator

Nagata Hajime  東京理科大学, 理工学部電気電子情報工学科, 教授 (70339117)

Project Period (FY) 2015-10-21 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords非鉛圧電セラミックス / ビスマス系ペロブスカイト強誘電体セラミックス / 積層セラミックアクチュエータ / 拡散 / 銀電極 / 低温焼結 / Bi系ペロブスカイト型強誘電体 / 電極 / 反応
Outline of Final Research Achievements

In this study, lead-free piezoelectric ceramics such as (Bi1/2K1/2)TiO3 (BKT) and (Bi1/2Na1/2)TiO3 (BNT) were focused aiming to the environmental protection. Particularly for the practical applications, it is considered that we need to address the issue about co-firing multilayer structure of these ceramics with electrodes such as silver (Ag). Then we clarified the silver diffusion behavior into these ceramics and understood that low temperature sintering of these ceramics was important for avoid the silver diffusion issue. After that, we also found effective dopants for lowering the sintering temperature of these ceramics, which was good for fabricating the multi-layer structure with suppressing the silver diffusion.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (19 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Int'l Joint Research: 7 results,  Invited: 5 results)

  • [Journal Article] Mechanical bending strength of (Bi 0.5 Na 0.5 ) TiO 3 -based lead-Free piezoelectric ceramics2017

    • Author(s)
      Takahashi Hiroaki、Nagata Hajime、Takenaka Tadashi
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 5 Issue: 3 Pages: 242-246

    • DOI

      10.1016/j.jascer.2017.03.002

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quenching effects on piezoelectric properties and depolarization temperatures of (Bi0.5Na0.5)TiO3-based solid solution systems2017

    • Author(s)
      Tatsuki Miura, Hajime Nagata, and Tadashi Takenaka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56

    • NAID

      210000148373

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diffusion behavior of Ag electrodes into (Bi<sub>1/2</sub>Na<sub>1/2</sub>)TiO<sub>3</sub> ceramics2016

    • Author(s)
      Naoki IWAGAMI, Hajime NAGATA, Isao SAKAGUCHI and Tadashi TAKENAKA
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 6 Pages: 644-647

    • DOI

      10.2109/jcersj2.16016

    • NAID

      130005155662

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quenching Effects of Piezoelectric Properties on Lead-Free (Bi1/2Na1/2)TiO3 ceramics2016

    • Author(s)
      Hiroki MURAMATSU, Hajime NAGATA, and Tadashi TAKENAKA
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 10S Pages: 10TB07-10TB07

    • DOI

      10.7567/jjap.55.10tb07

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Diffusion Behavior of Ag Electrodes into (Bi1/2Na1/2)TiO3 Ceramics2016

    • Author(s)
      Naoki Iwagami, Hajime Nagata, Isao Sakaguchi and Tadashi Takenaka
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124

    • NAID

      130005155662

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Diffusion Behavior of Ag Electrodes into (Bi1/2K1/2)TiO3 Ceramics2015

    • Author(s)
      Naoki Iwagami, Hajime Nagata, Isao Sakaguchi and Tadashi Takenaka
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 123 Pages: 645-617

    • NAID

      130005085528

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] (Bi0.5Na0.5)TiO3系セラミックスの焼成温度と電気的特性に及ぼす銅の添加効果2017

    • Author(s)
      中田 諒, 永田 肇, 竹中 正
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川、横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] (Bi1/2Na1/2)TiO3系固溶体ラミックスの電気的諸特性に及ぼすクエンチ効果2017

    • Author(s)
      永田 肇、村松啓貴、三浦樹生、竹中 正
    • Organizer
      第34回 強誘電体応用会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mechanical Fracture Properties on (Bi0.5Na0.5)TiO3-Based Lead-Free Piezoelectric Ceramics2017

    • Author(s)
      Hajime Nagata and Tadashi Takenaka
    • Organizer
      The 4th International Conference on Advanced Electromaterials(ICAE 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low Sintering Temperatures and Electrical Properties on Cu-doped (Bi0.5Na0.5)TiO3-based Ceramics2017

    • Author(s)
      Ryo Nakada, Hajime Nagata and Tadashi Takenaka
    • Organizer
      The 4th International Conference on Advanced Electromaterials(ICAE 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-Power Piezoelectric Characteristics of Bi-based Lead-free Piezoelectric Ceramics2017

    • Author(s)
      Hajime NAGATA
    • Organizer
      2017 International Congress on Ultrasonics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] クエンチ処理した(Bi1/2Na1/2)TiO3系セラミックスの結晶構造解析2017

    • Author(s)
      永田 肇、三浦 樹生、竹中 正
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ビスマス系非鉛強誘電体セラミックスのハイパワー圧電特性2017

    • Author(s)
      永田 肇, 竹中 正
    • Organizer
      日本音響学会愛媛大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Quenching Effects for Electrical Properties on Lead-Free (Bi1/2Na1/2)TiO3-Based Ceramics2016

    • Author(s)
      Hajime Nagata, Hiroki Muramatsu, and Tadashi Takenaka
    • Organizer
      IUMRS-17th International Conference in Asia
    • Place of Presentation
      Quindao, China
    • Year and Date
      2016-10-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of Li-substitution and Sintering Process for (Bi0.5K0.5)TiO3 Ceramics2016

    • Author(s)
      M. Tanaka, H. Nagata, and T. Takenaka
    • Organizer
      The 8th Japan-China Symposium on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2016-09-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] (Bi1/2Na1/2)TiO3セラミックスへの銀の拡散挙動2016

    • Author(s)
      永田 肇、岩上直樹、坂口勲、竹中正
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県、東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Silver Diffusion behavior into Bi-based perovskite-type Lead-free Ferroelectric Ceramics2016

    • Author(s)
      Hajime NAGATA, Naoki Iwagami, Isao Sakaguchi, and Tadashi TAKENAKA
    • Organizer
      2016 IEEE International Symposium on the Application of Ferroelectrics
    • Place of Presentation
      Darmstadt, Germany
    • Year and Date
      2016-08-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Silver Diffusion Behavior into Bi-based perovskite-type Lead-free Ferroelectric Ceramics2016

    • Author(s)
      Hajime Nagata, Naoki Iwagami, Isao Sakaguchi and Tadashi Takenaka
    • Organizer
      2016 IEEE International Symposium on the Applications of Ferroelectrics
    • Place of Presentation
      Darmstadt, Germany
    • Year and Date
      2016-08-21
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ビスマス系ペロブスカイト型強誘電体セラミックス中へのAg電極の拡散2016

    • Author(s)
      永田 肇,岩上直樹,坂口 勲,竹中 正
    • Organizer
      第45回EMシンポジウム
    • Place of Presentation
      森戸記念館(東京都、新宿区)
    • Year and Date
      2016-06-17
    • Related Report
      2016 Research-status Report

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Published: 2015-10-21   Modified: 2019-03-29  

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