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Pseudo-catalysis reaction at a plasma interface

Research Project

Project/Area Number 15K05833
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thermal engineering
Research InstitutionEhime University

Principal Investigator

Nomura Shinfuku  愛媛大学, 理工学研究科(工学系), 教授 (20263957)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsプラズマ / 液中プラズマ / 誘電体バリア放電 / セルロース / リグニン / クメン法 / バイオマス / セルロース分解 / 水素 / 超音波 / 芳香族 / グルコース / 分解 / 分光測定 / HMF
Outline of Final Research Achievements

The purpose of this research is to synthesize chemical substances and fuel gases from cellulose or lignin in inedible biomass under conditions that rely as little as possible on a catalyst and biodegradation. A pseudo-catalysis reaction at a plasma interface which incorporates a great variety of radicals by using in-liquid plasma is proposed for decomposition of substances that are normally very difficult to decompose. Cellulose suspensions can be decomposed by using the in-liquid plasma method to produce H2 gas along with 5-hydroxymethylfurfural (5-HMF), furfural.In these findings, one-step phenol production from a water-benzene mixture was achieved by using DVD plasma.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (11 results) (of which Int'l Joint Research: 6 results) Remarks (3 results)

  • [Journal Article] Catalytic effect on ultrasonic decomposition of cellulose2018

    • Author(s)
      Shinfuku Nomura, Kousuke Wakida, Shinobu Mukasa, and Hiromichi Toyota
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57

    • NAID

      210000149327

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of hydrogen and monomer aromatics by in-liquid plasma treatment of lignin2018

    • Author(s)
      Kazuki Tange, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota
    • Journal Title

      Journal of the Japan Institute of Energy

      Volume: 97

    • NAID

      130007428376

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] One-Step Phenol Production from Water-Toluene Mixture Using Radio Frequency In-Liquid Plasma2017

    • Author(s)
      Muhammad Agung, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota,Otsuka Kazuhiko and Hidekazu Goto
    • Journal Title

      Plasma Science and Technology

      Volume: 19 Issue: 5 Pages: 055503-055503

    • DOI

      10.1088/2058-6272/aa5fc6

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Pretreatment by Sulfuric Acid on Cellulose Decomposition Using the In-Liquid Plasma Method2016

    • Author(s)
      Kazuki TANGE, Shinfuku NOMURA, Shinobu MUKASA, Hiromichi TOYOTA, Fadhli SYAHRIAL
    • Journal Title

      Journal of the Japan Institute of Energy

      Volume: 95 Issue: 12 Pages: 1105-1109

    • DOI

      10.3775/jie.95.1105

    • NAID

      130005286347

    • ISSN
      0916-8753, 1882-6121
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Decomposition of cellulose by ultrasonic welding in water2016

    • Author(s)
      Shinfuku Nomura, Seiya Miyagawa, Shinobu Mukasa, and Hiromichi Toyota
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55

    • NAID

      210000146809

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fuel Gas Production from Biomass Sources by Radio Frequency In-Liquid Plasma Method2015

    • Author(s)
      Ismail Rahim, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota,Katsunori Kawanishi, Yoshihiko Makiura, Kazuhiko Kogoh, Kunihiro Ohshima, Susumu Katsuen,
    • Journal Title

      Journal of Power and Energy Engineering

      Volume: 3 Issue: 08 Pages: 28-35

    • DOI

      10.4236/jpee.2015.38004

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrogen Production from Glucose and Cellulose Using Radio Frequency In-Liquid Plasma and Ultrasonic Irradiation2014

    • Author(s)
      Fadhli Syahrial, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota, Kei Okamoto
    • Journal Title

      Journal of the Japan Institute of Energy

      Volume: 93 Issue: 11 Pages: 1207-1212

    • DOI

      10.3775/jie.93.1207

    • NAID

      130004713973

    • ISSN
      0916-8753, 1882-6121
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Characteristics of hydroxyl radical by dielectric barrier discharge of argon-water vapo2018

    • Author(s)
      Shinji NAGAO, Shinfuku NOMURA, Shinobu MUKASA, Hiromichi TOYOTA
    • Organizer
      The 6th Joint Conference on Renewable Energy and Nanotechnology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic Effect on Ultrasonic Decomposition of Cellulose2018

    • Author(s)
      Shinfuku Nomura, Kosuke Wakida, Shinobu Mukasa, Hiromichi Toyota
    • Organizer
      第38回超音波エレクトロニクスの基礎と応用に関するシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 野村 信福, 山根 諒介, 向笠 忍, 豊田 洋通, 川向 浩司, n-ドデカンと水界面で発生させた高周波プラズマによる水蒸気改質反応, 第54回日本2018

    • Author(s)
      野村 信福, 山根 諒介, 向笠 忍, 豊田 洋通
    • Organizer
      第54回日本伝熱シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水添加アルゴン中での誘電体バリア放電によるOH ラジカルの生成に関する研究2017

    • Author(s)
      坂田 啓一, 向笠 忍,長尾 真次, 豊田 洋通, 野村 信福
    • Organizer
      日本機械学会中国四国支部第55期総会・講演会
    • Place of Presentation
      広島工業大学(広島県・広島市)
    • Year and Date
      2017-03-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Fadhli Syahrial, Kazuki Tange, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota, Investigation of the Effects of Ultrasonic Vibration and Sodium Hydroxide on Decomposition of Cellulose Suspension by using RF In-Liquid Plasma for Hydrogen Production at Atmospheric Pressure2016

    • Author(s)
      Fadhli Syahrial, Kazuki Tange, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota
    • Organizer
      The 5th Joint Conference on Renewable Energy and Nanotechnology
    • Place of Presentation
      Kuala Lumpur( Malaysia)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電解質中に分散させたセルロースのプラズマ分解2016

    • Author(s)
      丹下 和樹, 野村 信福, 向笠 忍, 豊田 洋通
    • Organizer
      日本機械学会熱工学コンファレンス2016
    • Place of Presentation
      愛媛大学城北キャンパス(愛媛県松山市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Research-status Report
  • [Presentation] プラズマによる芳香族化合物からのフェノール合成2016

    • Author(s)
      大塚 和彦, 野村 信福, 向笠 忍, 豊田 洋通
    • Organizer
      日本機械学会熱工学コンファレンス2016
    • Place of Presentation
      愛媛大学城北キャンパス(愛媛県松山市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of pretreatment by sulfuric acid on cellulose decomposition using the in-liquid plasma method2015

    • Author(s)
      Kazuki Tange, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota, Fadhli Syahrial
    • Organizer
      The 4th Joint Conference on Renewable Energy and Nanotechnology
    • Place of Presentation
      愛媛県松山市
    • Year and Date
      2015-12-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Experimental Research on Hydrogen Production using the Steam Reforming Method in-Liquid Plasma2015

    • Author(s)
      Andi Amijoyo Mochtar, Shinfuku Nomura, Shinobu Mukasa, Hiromichi Toyota, Kohji Kawamukai, Seitaro Furusho,
    • Organizer
      The 4th Joint Conference on Renewable Energy and Nanotechnology
    • Place of Presentation
      愛媛県松山市
    • Year and Date
      2015-12-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] One-Step Phenol Production from Toluene Solution Using RF In-Liquid Plasma2015

    • Author(s)
      Muhammad Agung, S. Nomura, S. Mukasa, H. Toyota, H. Goto, O. Kazuhiko
    • Organizer
      33rd Symposium on Plasma Processing
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Improvement of hydrogen production from glucose by radio-freqeuncy in-liquid plasma at atmospheric pressure2015

    • Author(s)
      F. Syahrial, S. Nomura, S. Mukasa and H. Toyota
    • Organizer
      22nd International Symposium on Plasma Chemistry
    • Place of Presentation
      アントワープ(ベルギー)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] Heat & Mass Transfer Laboratory

    • URL

      https://www.me.ehime-u.ac.jp/labo/kikaiene/netubutu/achievements/

    • Related Report
      2017 Annual Research Report
  • [Remarks] Heat& Mass Transfwer Laboratory

    • URL

      http://www.me.ehime-u.ac.jp/labo/kikaiene/netubutu/achievements.html

    • Related Report
      2016 Research-status Report
  • [Remarks] 愛媛大学 熱及び物質移動学研究室

    • URL

      http://www.me.ehime-u.ac.jp/labo/kikaiene/netubutu/index.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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