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Low temperature deposition of barrierless insulating film applicable to 3D and 2.5 D-IC

Research Project

Project/Area Number 15K05975
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKitami Institute of Technology

Principal Investigator

Takeyama Mayumi B.  北見工業大学, 工学部, 准教授 (80236512)

Co-Investigator(Kenkyū-buntansha) 佐藤 勝  北見工業大学, 工学部, 助教 (10636682)
野矢 厚  北見工業大学, 工学部, 特任教授 (60133807)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords3次元集積回路 / 絶縁膜 / シリコン貫通ビア配線 / 低温作製 / バリヤレス / シリコン貫通ビア / バリア絶縁膜 / SiNx膜 / 表面・界面物性 / 拡散
Outline of Final Research Achievements

In the Si-semiconductor field, miniaturization in accordance with the conventional Moore's law is becoming difficult, and it is beginning to shift to a three-dimensional LSI that does not rely on miniaturization. In order to realize this, a through-silicon via (TSV) that connects chips or wafers in the shortest is indispensable.
In order to realize a three-dimensional integrated circuit with high yield, we cosider that the via-last process which fabricates the LSI first and then processes the TSV later is ideal, and the insulation barrier is heated to 200℃ or lower We examined for the purpose of functioning as an excellent barrier exhibiting good characteristics even at low temperatures and suppressing the diffusion of Cu even in the state where no diffusion barrier material is interposed and developing an excellent insulation barrier even at low temperature.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (29 results)

All 2018 2017 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (24 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Journal Article] Relationship between TiN films with different orientations and their barrier properties2018

    • Author(s)
      Masaru Sato and Mayumi B. Takeyama
    • Journal Title

      J. Jpn. Appl. Phys

      Volume: 57

    • NAID

      210000149379

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111)-oriented Cu layer on thin TaWN films2017

    • Author(s)
      Mayumi B. Takeyama and Masaru Sato
    • Journal Title

      J. Jpn. Appl. Phys

      Volume: 56 Issue: 7S2 Pages: 07KC03-07KC03

    • DOI

      10.7567/jjap.56.07kc03

    • NAID

      210000148102

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature-deposited insulating films of silicon nitride by reactive sputtering and plasma-enhanced CVD: Comparison of characteristics2016

    • Author(s)
      M. Sato, M. B. Takeyama, Y. Nakata, Y. Kobayashi, T. Nakamura, A. Noya
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55

    • NAID

      210000146285

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Room-temperature deposition of HfNx barrier by radical-assisted surface reaction for through-silicon-via in three-dimensional LSI2016

    • Author(s)
      M. Sato, M. B. Takeyama, A. Noya
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 2S Pages: 02BC21-02BC21

    • DOI

      10.7567/jjap.55.02bc21

    • NAID

      210000146090

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Low-temperature-deposited insulating films of silicon nitride by reactive sputtering and plasma-enhanced CVD: Comparison of characteristics2016

    • Author(s)
      Masaru Sato, Mayumi B. Takeyama, Yoshihiro Nakata, Yasushi Kobayashi, Tomoji Nakamura, and Atsushi Noya
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55

    • NAID

      210000146285

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 反応性スパッタ法によるTiNx膜の低温作2017

    • Author(s)
      佐藤勝、武山真弓
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 組成の違いによるTiHfN合金膜のキャラクタリゼーション2017

    • Author(s)
      佐藤勝、武山真弓
    • Organizer
      電気学会会 電子・情報・システム部門大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Characterization of TiHfN ternary alloy films as a new barrier2017

    • Author(s)
      Mayumi B. Takeyama and Masaru Sato
    • Organizer
      2017 International Conference on Solid State Devices and Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relation between TiN films with different texture and its barrier properties2017

    • Author(s)
      Masaru Sato and Mayumi B. Takeyama
    • Organizer
      Advanced Metallization Conference 2017: 27th Asian Session
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低温作製されたTiNx 膜の特性2017

    • Author(s)
      佐藤勝、武山真弓
    • Organizer
      電子情報通信学会総合大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Cuプラグに適用可能なTiHfN合金膜のバリヤ特性2016

    • Author(s)
      佐藤勝、青柳英二、野矢厚、武山真弓
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      金沢工業大学(石川県野々市市)
    • Year and Date
      2016-11-18
    • Related Report
      2016 Research-status Report
  • [Presentation] Barrierproperties of TiHfN ternary alloy films against Cu diffusion in Cu/Si contact system2016

    • Author(s)
      M. Sato, E. Aoyagi, and M. B. Takeyama
    • Organizer
      Advanced Metallization Conference 2016: 26th Asian Session
    • Place of Presentation
      東京大学(東京都)
    • Year and Date
      2016-10-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] The effect of the HfNx barrier thickness on the Cu grain orientation control2016

    • Author(s)
      M. Sato, E. Aoyagi, and M. B. Takeyam
    • Organizer
      2016 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Tsukuba International Congress Center(茨城県つくば市)
    • Year and Date
      2016-09-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 薄いHfNx膜上のCu(111)面高配向成長2016

    • Author(s)
      佐藤勝、青柳英二、武山真弓
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2016-07-22
    • Related Report
      2016 Research-status Report
  • [Presentation] 低温作製されたSiNx膜の安定性2016

    • Author(s)
      武山真弓、佐藤勝
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2016-07-22
    • Related Report
      2016 Research-status Report
  • [Presentation] 低温SiNx膜における表面ラジカル処理の効果2016

    • Author(s)
      武山真弓、佐藤勝
    • Organizer
      Cat-CVD研究会
    • Place of Presentation
      北見工業大学(北海道北見市)
    • Year and Date
      2016-07-08
    • Related Report
      2016 Research-status Report
  • [Presentation] ラジカル処理によって得られた薄いHfNx膜のバリヤ特性2016

    • Author(s)
      佐藤勝、武山真弓
    • Organizer
      Cat-CVD研究会
    • Place of Presentation
      北見工業大学(北海道北見市)
    • Year and Date
      2016-07-08
    • Related Report
      2016 Research-status Report
  • [Presentation] ナノ結晶HfNx膜上のCu膜の組織観察2016

    • Author(s)
      佐藤 勝、武山真弓、青柳英二、野矢 厚
    • Organizer
      電子情報通信学会総合大会
    • Place of Presentation
      福岡県福岡市
    • Year and Date
      2016-03-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 低温作製された窒化物薄膜の特性2016

    • Author(s)
      武山真弓、佐藤 勝、小林靖志、中田義弘、中村友二、野矢 厚
    • Organizer
      電子情報通信学会シリコン材料・デバイス研究会
    • Place of Presentation
      東京都
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ラジカル処理を用いた低温TiNx膜の特性評価2016

    • Author(s)
      佐藤 勝、武山真弓、野矢 厚
    • Organizer
      電子情報通信学会シリコン材料・デバイス研究会
    • Place of Presentation
      東京都
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
  • [Presentation] ラジカル処理によるHfNx膜の室温作製2015

    • Author(s)
      佐藤 勝、武山真弓、野矢 厚
    • Organizer
      電気・情報関係学会北海道支部連合大会
    • Place of Presentation
      北海道北見市
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 室温成膜したSiNx膜の特性評価2015

    • Author(s)
      佐藤 勝、武山真弓、小林靖志、中田義弘、中村友二、野矢 厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      新潟県長岡市
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
  • [Presentation] ラジカル窒化による遷移金属窒化物の有用性2015

    • Author(s)
      武山真弓、佐藤 勝、青柳英二、野矢 厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      新潟県長岡市
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
  • [Presentation] Preparation of high performance SiNx films deposited by reactive sputtering and PECVD at low temperatures2015

    • Author(s)
      M. Sato, M. B. Takeyama, Y. Nakata, Y. Kobayashi, t. Nakamura, A. Noya
    • Organizer
      2015 International Conference on Solid State Devices and Materials
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2015-09-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 窒化物薄膜の微細構造制御とラジカルを用いた低温での成膜方法2015

    • Author(s)
      武山真弓、佐藤 勝、野矢 厚
    • Organizer
      化学工学会
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ラジカル反応を用いたHfNx膜の低温作製2015

    • Author(s)
      佐藤 勝、武山真弓、野矢 厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      青森県弘前市
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 絶縁バリアとしてのSiNx膜の低温作製2015

    • Author(s)
      武山真弓、佐藤 勝、小林靖志、中田義弘、中村友二、野矢 厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      青森県弘前市
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
  • [Presentation] ラジカルを用いた表面窒化反応によるHfNx膜の低温作製2015

    • Author(s)
      佐藤 勝、武山真弓、野矢 厚
    • Organizer
      Cat-CVD研究会
    • Place of Presentation
      愛知県名古屋市
    • Year and Date
      2015-07-03
    • Related Report
      2015 Research-status Report
  • [Presentation] 室温堆積によるSiNx膜の特性評価2015

    • Author(s)
      武山真弓、佐藤 勝、小林靖志、中田義弘、中村友二、野矢 厚
    • Organizer
      Cat-CVD研究会
    • Place of Presentation
      愛知県名古屋市
    • Year and Date
      2015-07-03
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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