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Investigation of defect reduction mechanism and develompment of high efficiency rare-metal free and environmentally friendly solar cell

Research Project

Project/Area Number 15K05980
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNagaoka University of Technology

Principal Investigator

Tanakaka Kunihiko  長岡技術科学大学, 工学研究科, 准教授 (30334692)

Co-Investigator(Kenkyū-buntansha) 安井 寛治  長岡技術科学大学, 工学研究科, 教授 (70126481)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords薄膜太陽電池 / ポテンシャル搖動 / 発光スペクトル / Cu2ZnSnS4 / CZTS / 発光分光
Outline of Final Research Achievements

Potential fluctuations have been suspected that one of the cause of low efficiency of Cu2ZnSnS4 solar cells. In this study photoluminescence of samples with various chemical composition was investigated to reveal how to reduce potential fluctuations. Chemical composition dependence of potential fluctuations estimated from the photoluminescence showed that potential fluctuation could be reduced by Cu-poor chemical compositions. Grwoth temperature dependence of potential fluctuations was investigated from obsrevation of photoluminecence. As a result, the potential fluctuations were almost not depend on growth temperature. From the observation of the emission spectrum, it was also confirmed that the amount of potential fluctuation was reduced by post annealing.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Open Access: 1 results,  Peer Reviewed: 1 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] 光分光法によるCu2ZnSnS4 の欠陥低減機構の検討2017

    • Author(s)
      髙松良春,田中久仁彦
    • Journal Title

      平成29年度多元系化合物・太陽電池研究会年末講演会 論文集

      Volume: - Pages: 13-16

    • Related Report
      2017 Annual Research Report
    • Open Access
  • [Journal Article] Chemical composition dependence of photoluminescence from Cu2ZnSnS4 thin films with potential fluctuations2017

    • Author(s)
      Kunihiko Tanaka, Yoshiharu Takamatsu, Shinya Miura
    • Journal Title

      Physica Status Solidi c

      Volume: 印刷中 Issue: 6

    • DOI

      10.1002/pssc.201600138

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 発光分光によるCu2ZnSnS4 薄膜中における欠陥の調査2015

    • Author(s)
      三浦 進也, 髙松 良春, 田中久仁彦
    • Journal Title

      平成27年度多元系化合物・太陽電池研究会年末講演会 論文集

      Volume: なし Pages: 96-99

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] Cu2ZnSnS4発光スペクトルの成長温度依存性の検討2017

    • Author(s)
      髙松良晴,田中久仁彦
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      横浜市
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] Investigation of Photoluminescence from Cu2ZnSnS4 Depending on Growth Temperature2017

    • Author(s)
      Yoshiharu Takamatsu, Kunihiko Tanaka
    • Organizer
      2017 International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 発光分光法によるCu2ZnSnS4の陥低減機構の検討2017

    • Author(s)
      髙松良春,田中久仁彦
    • Organizer
      平成29 年度多元系化合物・太陽電池研究会年末講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Chemical Composition Dependence of Photoluminescence from Cu2ZnSnS4 Thin Films with potential fluctuation2016

    • Author(s)
      Kunihiko Tanaka, Yoshiharu Takamatsu, Shinya Miura
    • Organizer
      International Conference on Ternarly and Multinary Compounds 20
    • Place of Presentation
      Halle, Germany
    • Year and Date
      2016-09-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chemical Composition Dependence of Photoluminescence from Cu2ZnSnS4 Thin Films with potential fluctuation2016

    • Author(s)
      Kunihiko Tanaka, Yoshiharu Takamastu, Shinya Miura
    • Organizer
      20th International Conference on Ternary and Multinary Compounds
    • Place of Presentation
      Halle (Saale), Germany
    • Year and Date
      2016-09-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 化学量論比組成に近い組成を持つCu2ZnSnS4薄膜発光の組成比依存2016

    • Author(s)
      田中久仁彦,三浦進也,髙松良春
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京都目黒区東京工業大学大岡山キャンパス
    • Year and Date
      2016-03-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 発光分光によるCu2ZnSnS4 薄膜中における欠陥の調査2015

    • Author(s)
      三浦 進也, 髙松 良春, 田中久仁彦
    • Organizer
      平成27年度多元系化合物・太陽電池研究会年末講演会
    • Place of Presentation
      新潟県長岡市アオーレ長岡
    • Year and Date
      2015-12-11
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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