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Functionalized ligands of colloidal nano-dots for application to thin-film devices

Research Project

Project/Area Number 15K05986
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionWakayama University

Principal Investigator

Tanaka Ichiro  和歌山大学, システム工学部, 教授 (60294302)

Co-Investigator(Renkei-kenkyūsha) Kamiya Itaru  豊田工業大学, 工学(系)研究科(研究院), 教授 (10374018)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsコロイダルナノドット / 半導体 / 配位子 / 薄膜 / トランジスタ / キャリア移動度 / 半導体コロイダルナノドット / 電界効果トランジスタ / 有機メモリトランジスタ
Outline of Final Research Achievements

Semiconductor colloidal nano-dots (CND) are expected to be useful for low-cost thin-film devices. However, they are highly insulating and not suitable for electronic devices as they are. In this study, we increased the conductivity of CND films and fabricated thin film transistors (TFTs). At first, we tried to exchange insulating ligands with more conductive ones, but it was not successful because it was difficult to obtain well dispersed CND solution. We therefore removed ligand molecules from CNDs using ammonium sulfide solution. The CND films formed by horizontal lifting method were dipped in an ammonium sulfide solution for 2 s to eliminate ligand molecules. Then, source and drain electrodes were deposited to fabricate TFTs. Finally, the carrier mobility was measured with a semiconductor parameter analyzer; it reached 0.0011 cm2/Vs after the fabrication process was improved.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results) Remarks (5 results)

  • [Journal Article] 硫化アンモニウム処理したPbSコロイダルナノドット薄膜を用いた電界効果トランジスタ2018

    • Author(s)
      竹市祐実、三谷展弘、宇野和行、田中一郎
    • Journal Title

      材料

      Volume: 67

    • NAID

      130007485386

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pentacene memory transistors with a monolayer of ligand-removed semiconductor colloidal nano-dots used as a charge-trapping layer2017

    • Author(s)
      Fumihoru Nakano, Kazuyuki Uno, and Ichiro Tanaka
    • Journal Title

      Physica Status Solidi (a)

      Volume: 214 Issue: 3

    • DOI

      10.1002/pssa.201600545

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] PbSコロイダルナノドット薄膜を用いた電界効果トランジスタの硫化アンモニウム処理条件の検討2018

    • Author(s)
      竹市祐実、宇野和行、田中一郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] コロイダルナノドット単粒子膜を用いた有機メモリトランジスタの特性に対するドットサイズの影響2017

    • Author(s)
      中野史掘、宇野和行、田中一郎
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 硫化アンモニウム処理したPbSコロイダルナノドット薄膜を用いた電界効果トランジスタ2017

    • Author(s)
      竹市祐実、三谷展弘、宇野和行、田中一郎
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 硫化アンモニウム処理したPbSコロイダルナノドット薄膜を用いた電界効果トランジスタ2017

    • Author(s)
      竹市祐実、三谷展弘、宇野和行、田中一郎
    • Organizer
      薄膜材料デバイス研究会第14回研究集会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 配位子除去をした半導体コロイダルナノドット単粒子膜をフローティングゲートに用いたペンタセンメモリトランジスタ2016

    • Author(s)
      中野史掘、宇野和行、田中一郎
    • Organizer
      薄膜材料デバイス研究会第13回研究集会
    • Place of Presentation
      龍谷大学 響都ホール校友会館
    • Year and Date
      2016-10-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Pentacene Memory Transistors Using Monolayer of Ligand-removed Semiconductor Colloidal Nano-dots as a Floating Gate2016

    • Author(s)
      Fumihoru Nakano, Kazuyuki Uno, and Ichiro Tanaka
    • Organizer
      The 43th Internatinal Symposium on Compound Semiconductor (ISCS2016)
    • Place of Presentation
      Toyama International Conference Center, Japan
    • Year and Date
      2016-07-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] コロイダルナノドット単粒子膜をフローティングゲート層に用いた有機メモリトランジスタ2016

    • Author(s)
      中野史掘、阪川秀紀、宇野和行、田中一郎
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Writing characteristics of organic memory transistors with embedded monolayer of semiconductor colloidal nano-dots2015

    • Author(s)
      Fumihoru Nakano, Hideki Sakagawa, Kazuyuki Uno, Ichiro Tanaka
    • Organizer
      17th International Conference on Modulated Semiconductor Structures
    • Place of Presentation
      Sendai International Center
    • Year and Date
      2015-07-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 和歌山大学 研究者総覧

    • URL

      http://wakarid.center.wakayama-u.ac.jp

    • Related Report
      2017 Annual Research Report
  • [Remarks] 和歌山大学システム工学部 電子材料グループホームページ

    • URL

      http://portal.sys.wakayama-u.ac.jp/mc/semiG/index.php

    • Related Report
      2017 Annual Research Report
  • [Remarks] 和歌山大学 研究者総覧

    • URL

      http://wakarid.center.wakayama-u.ac.jp/WwwIndex.html

    • Related Report
      2016 Research-status Report
  • [Remarks] 和歌山大学システム工学部精密物質学科 電子材料グループホームページ

    • URL

      http://portal.sys.wakayama-u.ac.jp/mc/semiG/index.php

    • Related Report
      2016 Research-status Report
  • [Remarks] 和歌山大学システム工学部 精密物質学科 電子材料グループ

    • URL

      http://portal.sys.wakayama-u.ac.jp/mc/semiG/index.php?FrontPage

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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