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Synthesis of next genration cuprate-superconductors without rare-earth elements using soft-chemical processes

Research Project

Project/Area Number 15K06433
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

Kato Masatsune  東北大学, 工学研究科, 准教授 (50211850)

Co-Investigator(Renkei-kenkyūsha) KAJITA Tetsuya  東北大学, 学際科学フロンティア, 助教 (50729233)
TAKAMATSU Tomohisa  東北大学, 大学院工学研究科, 助教 (60708428)
YAGYU Hotaka  仙台高等専門学校, 電気システム工学科, 助教 (30736369)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords超伝導体 / 希土類フリー / ソフト化学合成 / 超伝導 / 銅酸化物 / フッ素 / 低温合成
Outline of Final Research Achievements

The purpose of this research is to synthesize new cuprate superconductors without expensive rare earth elements with a superconducting transition temperature Tc above 100 K.
In Sr2-xBaxCuO2F2+d, the maximum Tc is as low as 65 K because the Cu-O distance in the conducting plane is too long for hole carriers to be supplied. In (Bi,Pb)2Sr2CaCu2O8+d, Tc has increased up to 102 K by removing the excess oxygen completely and optimizing the hole concentration. The present compound is the first superconductor with Tc above 100 K in the Bi-2212 phase. In Ca-substituted (RE,Ca)(Ba,Sr)2Cu3O6.0 with reduced RE-content, Tc has increased greatly from 50 K up to 72 K. It has been found that further increase in Tc can be expected by reducing the lattice.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (19 results)

All 2018 2017 2016

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (16 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Superconductivity above 100 K in the Bi-2212 Phase of (Bi,Pb)2Sr2CaCu2O82018

    • Author(s)
      K. Sugawara, C. Sugimoto, T. Luo, T. Kawamata, T. Noji, M. Kato, Y. Koike
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of the Ba-substitution for Sr in the Bi-2201 Phase of BiPb(Sr,La)2CuO6+δ2018

    • Author(s)
      D. Hayakawa, T. Watanabe, T. Luo, T. Kawamata, T. Noji, M. Kato, Y. Koike
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of Tc on the RE-ion Size in (RE,Ca)Ba2Cu3O62018

    • Author(s)
      K. Nakagawa, Y. Sumino, H. Chiba, K. Kim, T. Noji, M. Kato, Y. Koike
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Bi-2212相BiPbSr2-xBaxRECu2O8+δの合成2018

    • Author(s)
      渡邉知晟、高野宏輝、菅原慧一、杉本千明、野地尚、加藤雅恒、小池洋二
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 格子縮小による(RE,Ca)(Ba,Sr)2Cu3O6.0のTc上昇2018

    • Author(s)
      仲川晃平、住野義樹、加藤雅恒、野地尚、小池洋二
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dependence of Tc on the RE-ion Size in (RE,Ca)Ba2Cu3O62017

    • Author(s)
      K. Nakagawa, Y. Sumino, H. Chiba, K. Kim, T. Noji, M. Kato, Y. Koike
    • Organizer
      The 30th International Symposium on Superconductivity
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Superconductivity above 100 K in the Bi-2212 Phase of (Bi,Pb)2Sr2CaCu2O82017

    • Author(s)
      K. Sugawara, C. Sugimoto, T. Luo, T. Noji, M. Kato, Y. Koike
    • Organizer
      The 30th International Symposium on Superconductivity
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Ba-substitution for Sr in the Bi-2201 Phase of BiPb(Sr,La)2CuO6+δ2017

    • Author(s)
      D. Hayakawa, T. Watanabe, T. Luo, T. Kawamata, T. Noji, M. Kato, Y. Koike
    • Organizer
      The 30th International Symposium on Superconductivity
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 100 Kを超える超伝導転移温度を有するBi-2212相(Bi,Pb)2Sr2CaCu2O8の合成2017

    • Author(s)
      菅原慧一、杉本千明、羅添文、野地尚、加藤雅恒、小池洋二
    • Organizer
      電気学会 金属・セラミックス/超電導機器合同研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超伝導転移温度の向上を目指した(RE,Ca)Ba2Cu3O6の合成2017

    • Author(s)
      仲川晃平、住野義樹、野地尚、加藤雅恒、小池洋二
    • Organizer
      電気学会 金属・セラミックス/超電導機器合同研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 銅酸化物超伝導体Bi-2201相 BiPb(Sr,La)2CuO6+δにおけるSrのBa置換効果2017

    • Author(s)
      早川大貴、渡邉知晟、羅添文、川股隆行、野地尚、加藤雅恒、小池洋二
    • Organizer
      電気学会 金属・セラミックス/超電導機器合同研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超伝導転移温度向上を目指した(RE,Ca)Ba2Cu3O6.0の合成2017

    • Author(s)
      仲川晃平、住野義樹、野地尚、加藤雅恒、小池洋二
    • Organizer
      第72回応用物理学会東北支部学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超伝導転移温度向上を目指したSr2CuO2F2+δとBiPb(Sr,La)2CuO6+δにおけるSrサイトのBa置換2017

    • Author(s)
      早川大貴、渡邉知晟、住野義樹、羅添文、川股隆行、野地尚、加藤雅恒、小池洋二
    • Organizer
      第72回応用物理学会東北支部学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 100 Kを超える超伝導転移温度を有するBi-2212相(Bi,Pb)2Sr2CaCu2O8の合成2017

    • Author(s)
      菅原慧一、杉本千明、羅添文、野地尚、加藤雅恒、小池洋二
    • Organizer
      第72回応用物理学会東北支部学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 希土類フリー銅酸化物Sr2-xBaxCuO2F2+δの超伝導転移温度向上の試み2017

    • Author(s)
      早川大貴、住野義樹、加藤雅恒、野地尚、小池洋二
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超伝導転移温度向上を目指したBi-2201相におけるSrサイトのBa置換2017

    • Author(s)
      早川大貴、渡邉知晟、羅添文、野地尚、加藤雅恒、小池洋二
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] (RE,Ca)Ba2Cu3O6における超伝導転移温度向上の試み2017

    • Author(s)
      仲川晃平、住野義樹、加藤雅恒、野地尚、小池洋二
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 転移温度向上を目指したBi系、Y系銅酸化物超伝導体における元素置換2017

    • Author(s)
      仲川晃平、羅添文、杉本千明、住野義樹、野地尚、加藤雅恒、小池洋二
    • Organizer
      第2回固体化学フォーラム研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] (Y,Ca)Ba2Cu3O6の水素化による超伝導化2016

    • Author(s)
      住野義樹、柳生穂高、加藤雅恒、野地尚、小池洋二
    • Organizer
      日本物理学会
    • Place of Presentation
      東北学院大学(宮城県)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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