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A study on the direct transformation to amorphous diamond by piling up non-equilibrium processes

Research Project

Project/Area Number 15K06440
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionHyogo University of Teacher Education

Principal Investigator

Keisuke Niwase  兵庫教育大学, 学校教育研究科, 教授 (50198545)

Co-Investigator(Renkei-kenkyūsha) HONDA Shin-ichi  兵庫県立大学, 工学部, 教授 (90324821)
Ohfuji Hiroaki  愛媛大学, 地球深部ダイナミック研究センター, 教授 (80403864)
Project Period (FY) 2015-10-21 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsダイヤモンド / 黒鉛 / 圧縮黒鉛 / 高圧高温 / 変換 / 照射欠陥 / 中性子照射 / 高圧実験 / 多結晶 / 欠陥 / X線回折 / アモルファスダイヤモンド / 衝撃圧縮 / 静水圧 / ラマン分光法 / 格子欠陥 / ナノ材料 / 照射
Outline of Final Research Achievements

We have so far been discovered the transformation from neutron-irradiated highly oriented pyrolytic graphite (HOPG) to amorphous diamond. Here, we have investigated the change of the neutron-irradiated HOPG under high pressure in high temperature (HPHT) condition. At 2300℃/15GPa, we observed transformation to a polycrystalline diamond. At 1500℃/15GP, we observed the formation of compressed graphite. The structural changes are considered to originate in some effect of neutron irradiation-induced defects.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (12 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results) Presentation (9 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Int'l Joint Research] ITER機構(フランス)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Quenchable compressed graphite synthesized from neutron-irradiated highly oriented pyrolytic graphite in high pressure treatment at 1500℃2018

    • Author(s)
      Niwase Keisuke、Terasawa Mititaka、Honda Shin-ichi、Niibe Masahito、Hisakuni Tomohiko、Iwata Tadao、Higo Yuji、Hirai Takeshi、Shinmei Toru、Ohfuji Hiroaki、Irifune Tetsuo
    • Journal Title

      Journal of Applied Physics

      Volume: 123 Issue: 16 Pages: 161577-161577

    • DOI

      10.1063/1.5011209

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nano-polycrystalline diamond synthesized from neutron-irradiated highly oriented pyrolytic graphite (HOPG)2018

    • Author(s)
      Terasawa Mititaka、Honda Shin-ichi、Niwase Keisuke、Niibe Masahito、Hisakuni Tomohiko、Iwata Tadao、Higo Yuji、Shinmei Toru、Ohfuji Hiroaki、Irifune Tetsuo
    • Journal Title

      Diamond and Related Materials

      Volume: 82 Pages: 132-136

    • DOI

      10.1016/j.diamond.2018.01.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 衝撃圧縮されたC60フラーレンと中性子照射された黒鉛のアモルファスダイヤモンド変換の局所ゆらぎ2018

    • Author(s)
      庭瀬敬右, 中村一隆, 岩田忠夫
    • Organizer
      日本物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local fluctuations in the transformation to amorphous diamond from neutron-irradiated graphite and C60 fullerenes under shock-compression2017

    • Author(s)
      K. Niwase, K.G. Nakamura, T.Iwata
    • Organizer
      APS March Meeting 2017
    • Place of Presentation
      ニューオリンズ(アメリカ)
    • Year and Date
      2017-03-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Transformation from neutron-irradiated graphite to amorphous diamond by shock-compression2017

    • Author(s)
      K. Niwase, K.G. Nakamura, T.Iwata
    • Organizer
      SSSN-KANSAI
    • Place of Presentation
      京都
    • Year and Date
      2017-01-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 黒鉛のボールミリングによるアモルファス化の臨界条件2017

    • Author(s)
      庭瀬敬右,平岩佑介,石村英士
    • Organizer
      日本物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nano-polycrystalline diamond synthesized from neutron-irradiated highly oriented pyrolytic graphite2017

    • Author(s)
      M. Terasawa, S. Honda , K. Niwase, T. Hisakuni, M. Niibe, Y. Higo, H. Izumi, E. Taguchi, T. Iwata
    • Organizer
      DCM
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transformation to amorphous diamond from neutron-irradiated graphite and C60 fullerenes by shock-compression and local fluctuations in the defective structures2017

    • Author(s)
      K. Niwase, K.G. Nakamura, T.Iwata
    • Organizer
      ICDS-29
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 衝撃圧縮による黒鉛-ダイヤモンド変換のレーザー顕微鏡による観察2017

    • Author(s)
      庭瀬 敬右,中村 一隆,岩田 忠夫
    • Organizer
      日本顕微鏡学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local fluctuation of transformation to amorphous diamond from irradiated graphite and C60 fullerenes under shock-compression2016

    • Author(s)
      K. Niwase, K.G. Nakamura,T.Atou, T.Iwata
    • Organizer
      ICDCM-2016
    • Place of Presentation
      モンペリエ(フランス)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Amorphous diamond transformed from neutron-irradiated graphite by shock-compression2016

    • Author(s)
      K. Niwase, K.G. Nakamura, T. Atou, T. Iwata, Y. Sato, M. Terauchi
    • Organizer
      BIT's 1st Annual World Congress of Smart Materials-2015 (WCSM-2015)
    • Place of Presentation
      Singapore
    • Year and Date
      2016-03-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2015-10-21   Modified: 2019-03-29  

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