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Preparation and application of nitride phosphor-in-glass for high-power solid state laser lighting

Research Project

Project/Area Number 15K06448
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

XIE RONG-JUN  国立研究開発法人物質・材料研究機構, サイアロングループ, 主席研究員 (00370297)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywordsレーザー照明 / 蛍光体 / 窒化物 / ガラス / 発光ガラス / 発光セラミックス / 発光材料 / 輝度飽和 / 量子効率 / 熱伝導率 / 微構造 / 透光性 / 固体照明
Outline of Final Research Achievements

The blue laser-driven solid-state lighting is superior to white LEDs in super-high power density and super-high brightness, which attracts great attention in recent year. In this research, we attempted to develop luminescent phosphor-in-glass (PiG) and ceramic materials as color converters in laser lighting, and investigated the preparation of nitride PiG and ceramic materials and their photoluminescence properties under blue laser irradiations. The results showed that translucent PiG luminescent materials could be prepared at low temperatures, but they exhibited strong luminescence saturation under the high-power blue laser excitation. In addition, highly densified luminescent ceramics could be fabricated by using spark plasma sintering. These luminescent ceramics had relatively higher thermal conductivities, and thus showed less luminescence saturation than the PiG materials.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (33 results)

All 2017 2016 2015 Other

All Int'l Joint Research (4 results) Journal Article (18 results) (of which Int'l Joint Research: 16 results,  Peer Reviewed: 18 results,  Open Access: 11 results,  Acknowledgement Compliant: 11 results) Presentation (11 results) (of which Int'l Joint Research: 7 results,  Invited: 9 results)

  • [Int'l Joint Research] 中国計量大学/中国有色研究総院(中国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 中国計量大学/中国科学院上海セラミックス研究所/中国地質大学(中国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] 中国計量学院/中国科学技術大学/Appotronics Corporation(中国)

    • Related Report
      2015 Research-status Report
  • [Int'l Joint Research]

    • Related Report
      2015 Research-status Report
  • [Journal Article] New insights into the microstructure of translucent CaAlSiN3:Eu2+ phosphor ceramics for solid-state laser lighting2017

    • Author(s)
      Shuxing Li, Daiming Tang, Zifeng Tian, Xuejian Liu, Takashi Takeda, Naoto Hirosaki, Fangfang Xu,Zhengren Huang, Rong-Jun Xie
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 5 Issue: 5 Pages: 1042-1051

    • DOI

      10.1039/c6tc04987g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A robust red-emitting phosphor-in-glass (PiG) for use in white lighting sources pumped by blue laser diodes2017

    • Author(s)
      Qiang-Qiang Zhu, Xin Xu, Le Wang, Zi-Feng Tian, Yan-Zheng Xu, Naoto Hirosaki, Rong-Jun Xie
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 702 Pages: 193-198

    • DOI

      10.1016/j.jallcom.2017.01.256

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structural evolutions and significantly reduced thermal degradation of red-emitting Sr2Si5N8:Eu2+ via carbon doping2017

    • Author(s)
      Lihong Liu, Le Wang, Yuanqiang Li, Chenning Zhang, Yujin Cho, Siu Wing Or, Tianliang Zhou, Takashi Takeda, Naoto Hirosaki, Rong-Jun Xie
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 5 Issue: 35 Pages: 8927-8935

    • DOI

      10.1039/c7tc02908j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis and Photoluminescence Properties of a Blue-Emitting La3Si8N11O4:Eu2+ Phosphor2017

    • Author(s)
      Hui-Bing Xu, Wei-Dong Zhuang, Le Wang, Rong-Hui Liu, Yuan-Hong Liu, Li-Hong Liu, Yujin Cho, Naoto Hirosaki, Rong-Jun Xie
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 22 Pages: 14170-14177

    • DOI

      10.1021/acs.inorgchem.7b02310

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nitride phosphors as robust emissive materials in white flat field emission lamps2017

    • Author(s)
      Le Wang, Xiao-Jun Wang, Kohsei Takahashi, Takashi Takeda, Naoto Hirosaki, Rong-Jun Xie
    • Journal Title

      Optical Materials Express

      Volume: 7 Issue: 6 Pages: 1934-1941

    • DOI

      10.1364/ome.7.001934

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Phase formation of (Y,Ce)2BaAl4SiO12 yellow microcrystal-glass phosphor for blue LED pumped white lighting2017

    • Author(s)
      Haipeng Jia, Yujin Cho, Le Wang, Naoto Hirosaki, Maxim S. Molokeeve, Zhaohui Huang, Rong-Jun Xie
    • Journal Title

      Ceramics International

      Volume: 43 Issue: 8 Pages: 64256429-64256429

    • DOI

      10.1016/j.ceramint.2017.02.055

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A promising orange-yellow-emitting phosphor for high power warm-light white LEDs: Pure-phase synthesis and photoluminescence properties2017

    • Author(s)
      Zhenhua Chen, Qinghong Zhang, Yaogang Li, Hongzhi Wang , Rong-Jun Xie
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 715 Pages: 184-191

    • DOI

      10.1016/j.jallcom.2017.04.270

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] CaAlSiN3:Eu2+ translucent ceramic: a promising robust and efficienct red color converter for solid state laser displays and lighting2016

    • Author(s)
      S. Li, Q. Zhu, L. Wang, D. Tang, Y. Cho, X. Liu, N. Hirosaki, T. Nishimura, T. Sekiguchi, Z. Huang, and R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Pages: 8197-8205

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Al2O3-YAG:Ce composite phosphor ceramic: a thermally robust and efficient color converter for solid state lighting2016

    • Author(s)
      S. Li, Q. Zhu, D. Tang, X. Liu, G. Ouyang, L. Cao, N. Hirosaki, T. Nishimura, Z. Huang, and R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 37 Pages: 8648-8654

    • DOI

      10.1039/c6tc03215j

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] New Y2BaAl4SiO12:Ce3+ yellow microcrystal-glass powder phosphor with high thermal emission stability2016

    • Author(s)
      H. Ji, L. Wang, Y. Cho, N. Hirosaki, M.S. Molokeev, Z. Xia, Z. Huang, and R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 41 Pages: 9872-9878

    • DOI

      10.1039/c6tc03422e

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Structure and luminescence of a novel orange-yellow-emitting Ca1.62Eu0.38Si5O3N6 phosphor for warm white LEDs, discovered by a single-particle-diagnosis approach2016

    • Author(s)
      X.-J. Wang, S. Funahashi, T. Takeda, T. Suehiro, N. Hirosaki, and R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Pages: 9968-9975

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structure evolution and photoluminescence of Lu3(Al,Mg)2(Al,Si)3O12:Ce3+ phosphors: new yellow-color converters for blue LED-driven solidstate lighting2016

    • Author(s)
      H. Ji, L. Wang, M.S. Molokeev, N. Hirosaki, R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 28 Pages: 6855-6863

    • DOI

      10.1039/c6tc00966b

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Crystal structure, tunable emission and applications of Ca1xAl1xSi1+xN3xOx:RE (x = 0-0.22, RE = Ce3+, Eu2+) solid solution phosphors forwhite light-emitting diodes2016

    • Author(s)
      S. Li, L. Wang, Q.Q. Zhu, D. Tang, X. Liu, G. Cheng, L. Lu, T. Takeda, N. Hirosaki, Z. Huang and R.-J. Xie
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 47 Pages: 11219-11230

    • DOI

      10.1039/c6tc04057h

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Extra-Broad Band Orange-Emitting Ce3+-Doped Y3Si5N9O Phosphor for Solid-State Lighting: Electronic, Crystal Structures and Luminescence Properties2016

    • Author(s)
      Q.-Q. Zhu, L. Wang, N. Hirosaki, L.Y. Hao, X. Xu, and R.-J. Xie
    • Journal Title

      Chem. Mater.

      Volume: 28 Issue: 13 Pages: 4829-4839

    • DOI

      10.1021/acs.chemmater.6b02109

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Beta-sialon:Eu phosphor-in-glass: A robust green color converter for high power bllue laser lighting2015

    • Author(s)
      Q.Q. Zhu, X.J. Wang, L. Wang, N. Hiroskai, T. Nishimura, Z.F. Tian, Q. Li, Y.-Z. Xu, X. Xu, and R.-J. Xie
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 41 Pages: 10761-10766

    • DOI

      10.1039/c5tc02236c

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Reduced thermal degradation of the red-emitting Sr2Si5N8:Eu2+ phosphor via thermal treatment in nitrogen2015

    • Author(s)
      C. Zhang, T. Uchikoshi, R.=j. Xie, L. Liu, Y. Cho, Y. Sakka, N. Hirosaki, and T. Sekiguchi
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 29 Pages: 7642-7651

    • DOI

      10.1039/c5tc01575h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Blue-emitting St3Si8-xAlxO7+xN8-x:Eu2+ discovered by a single-particle-diagnosis approach: Crystal structure, luminescence, scale-up synthesis and its abnormal thermal quenching behavior2015

    • Author(s)
      X.J. Wang, L. Wang, T. Takeda, S. Funahashi, T. Suehiro, N. Hirosaki, and R.-J. Xie
    • Journal Title

      Chemistry of Materials

      Volume: 27 Issue: 22 Pages: 7689-7697

    • DOI

      10.1021/acs.chemmater.5b03252

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Highly efficient narrow-band green and red phosphors enabling wider color-gamut LED backlight for more brilliant displays2015

    • Author(s)
      L. Wang, X.J. Wang, T. Kohsei, K. Yoshimura, M. Izumi, N. Hirosaki, and R.-J. Xie
    • Journal Title

      Optics Express

      Volume: 23 Issue: 22 Pages: 28707-28717

    • DOI

      10.1364/oe.23.028707

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] YAG/Al2O3復合セラミックス発光材料の合成と発光特性2017

    • Author(s)
      解栄軍,李淑星,Yujin Cho,武田隆史,広崎尚登
    • Organizer
      日本応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] LUMINESCENT NITRIDE CERAMICS FOR SOLID STATE LASER LIGHTING2017

    • Author(s)
      Rong-Jun Xie, Shuxing Li, Xuejian Liu, Takashi Takeda, Naoto Hirosaki
    • Organizer
      9th International Symposium on Nitrides and Related Materials (ISNT2017) & 5th International Symposium on SiAlONs and Non-oxides (ISSNOX5)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Luminescent Ceramics for Solid State Laser Lighting2016

    • Author(s)
      解栄軍、武田隆史、広崎尚登
    • Organizer
      Intl. Symp. on Lumin, Spectro. and Appl. (Phosphor Safari 2016)
    • Place of Presentation
      Hong Kong Baptist University
    • Year and Date
      2016-11-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Transparent Phosphor-in-glass (PiG) Luminescent Materials for Solid State Laser Lighting2016

    • Author(s)
      解栄軍、武田隆史、広崎尚登
    • Organizer
      Materials Science & Technology 2016
    • Place of Presentation
      Salt Lack City, USA
    • Year and Date
      2016-10-23
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] CaAlSiN3:Eu2+発光セラミックスの作製2016

    • Author(s)
      解栄軍、李淑星、CHOYujin、武田隆史、広崎尚登
    • Organizer
      2016年第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ,,新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] New Nitride Luminescent Materials Discovered by the Single-Particle-Diagnosis Approach2016

    • Author(s)
      解栄軍、舟橋司朗、武田隆史、広崎尚登
    • Organizer
      4th Intl. Symp. on Rare Earth Resource Utilization
    • Place of Presentation
      中国科学院長春応用化学研究所
    • Year and Date
      2016-08-16
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Nitride phosphors for wide color-gamut white LED backlights2016

    • Author(s)
      解栄軍、高橋向星、広崎尚登
    • Organizer
      中国ナノ材料発光性質学術会議
    • Place of Presentation
      蘭州大学、中国
    • Year and Date
      2016-07-25
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Spectral Tuning and Application of Rare Earth-Doped Nitride Luminescent Materials2016

    • Author(s)
      解栄軍、広崎尚登
    • Organizer
      中国化学会第30回年会
    • Place of Presentation
      大連理工大学、中国
    • Year and Date
      2016-07-01
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Preparation of green-emitting beta-sialon-in-glass for laser lighting2015

    • Author(s)
      解栄軍、Qiangqiang Zhu、Xin Xu、広崎尚登
    • Organizer
      11th Laser Ceramics Symposium (LCS),
    • Place of Presentation
      New Century Grand Hotel Xuzhou,Xu Zhou,China
    • Year and Date
      2015-11-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal Degradation of Nitride Phosphors2015

    • Author(s)
      解栄軍、王春曇、武田隆史、ジョユージン、末廣隆之、 廣崎尚登
    • Organizer
      228th ECS Meeting,American Electrochemistry Society
    • Place of Presentation
      Phoenix Convention Center and the Hyatt Regency,Phoenix,アメリカ
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal degradation of nitride phosphors for solid state lighting2015

    • Author(s)
      解栄軍、武田隆史、末廣隆之、 廣崎尚登
    • Organizer
      11th Intl Conf. Ceram. Mater. Compt Energy and Environ Appl.
    • Place of Presentation
      Hyatt Regency Vancouver ,Vancouver,カナダ
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2015-04-16   Modified: 2019-03-29  

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