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Development of lead-free piezoelectric ceramics for high power applications by microstructure control

Research Project

Project/Area Number 15K06451
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research Institution防衛大学校(総合教育学群、人文社会科学群、応用科学群、電気情報学群及びシステム工学群)

Principal Investigator

Ishii Keisuke  防衛大学校(総合教育学群、人文社会科学群、応用科学群、電気情報学群及びシステム工学群), 電気情報学群, 教授 (30257208)

Co-Investigator(Kenkyū-buntansha) 江阪 久雄  防衛大学校(総合教育学群、人文社会科学群、応用科学群、電気情報学群及びシステム工学群), 電気情報学群, 教授 (40531992)
Co-Investigator(Renkei-kenkyūsha) TASHIRO SHINJIRO  防衛大学校, 電気情報学群, 教授 (00546062)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords圧電セラミックス / 非線形圧電性 / 非鉛 / 粒子配向制御 / 相境界 / テンプレート粒成長法 / 非鉛材料 / 板状結晶粒 / テンプレート / 一段階溶融塩法 / 圧延配向法 / 非鉛圧電材料 / BaTi2O5 / アルカリニオブ系セラミックス / 非線形圧電現象 / 電流跳躍現象
Outline of Final Research Achievements

The (K,Na)NbO3 system ceramics are typical lead-free piezoelectric ceramics. The effects of the grain orientation control, by which the crystal grains grow in the same direction, on nonlinear piezoelectricity was studied in these ceramics. The influence of Li substitution for Na and K on nonlinear piezoelectricity was also studied. In the oriented ceramics having the orientation factor of 97%, the nonlinear piezoelectric coefficient decreased to 1/6 compared with the random oriented ceramics. It was confirmed in the first time that nonlinear piezoelectricity can be reduced by the grain orientation control in (K,Na)NbO3 system piezoelectric ceramics. It was also found that the nonlinear piezoelectric coefficient decreased to 1/10 or less by the Li substitution.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (11 results)

All 2018 2017 2016 2015

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (7 results)

  • [Journal Article] 一段階溶融塩法による板状NaNbO3結晶粒の作製2018

    • Author(s)
      石井啓介
    • Journal Title

      防衛大学校理工学研究報告

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation between a Semi-Quantitative Concentration Index and the Actual Concentration of BaTi2O5 in the Mixed Phase with BaTiO3 and Ba6Ti17O402017

    • Author(s)
      S. Tashiro and K. Ishii
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 64 Pages: 104-106

    • NAID

      130005509439

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Orientation control of (K,Na)NbO3 ceramics using platelike NaNbO3 templates prepared by single-step molten salt synthesis with mixed salt2016

    • Author(s)
      K. Ishii and S. Tashiro
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nonlinear Piezoelectricity in Li-modified (K, Na)NbO3 System Ceramics2015

    • Author(s)
      K. Ishii and S. Tashiro
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54

    • NAID

      210000145802

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] (K,Na)NbO3系粒子配向セラミックス焼結へのBi添加効果2018

    • Author(s)
      石井啓介
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 混合塩から合成される板状NaNbO3テンプレート作製法の改良2017

    • Author(s)
      石井啓介、田代新二郎
    • Organizer
      第34回強誘電体応用会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超音波処理による板状NaNbO3結晶粒径の最適化2017

    • Author(s)
      石井啓介、田代新二郎
    • Organizer
      第33回強誘電体応用会議
    • Place of Presentation
      東京
    • Related Report
      2016 Research-status Report
  • [Presentation] 混合塩を用いた一段階溶融塩法による板状NaNbO3結晶粒の合成2016

    • Author(s)
      石井啓介、 田代新二郎
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 混合塩から合成された板状NaNbO3テンプレートを 用いた(K,Na)NbO3系セラミックスの配向制御2016

    • Author(s)
      石井啓介、田代新二郎
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      京都
    • Related Report
      2016 Research-status Report
  • [Presentation] Liを加えた(K,Na)NbO3系セラミックスの 非線形圧電性2015

    • Author(s)
      石井啓介、 田代新二郎
    • Organizer
      第32回強誘電体応用会議
    • Place of Presentation
      京都
    • Year and Date
      2015-05-20
    • Related Report
      2015 Research-status Report
  • [Presentation] BaTi2O5セラミックスの結晶相に及ぼす 作製条件2015

    • Author(s)
      田代新二郎、石井啓介
    • Organizer
      第32回強誘電体応用会議
    • Place of Presentation
      京都
    • Year and Date
      2015-05-20
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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