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Phase control and functional creation of nanocomposite particles by vapor quenching process

Research Project

Project/Area Number 15K06463
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionNagoya Institute of Technology

Principal Investigator

Hihara Takehiko  名古屋工業大学, 工学(系)研究科(研究院), 教授 (60324480)

Co-Investigator(Kenkyū-buntansha) 宮崎 怜雄奈  名古屋工業大学, 工学(系)研究科(研究院), 助教 (10756191)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsナノ粒子 / 燃料電池 / 触媒 / 磁性材料 / リチウム電池 / 負極材料 / 交換結合 / ナノコンポジット / 気相合成 / 固体電解質 / 固体高分子形燃料電池 / ナノコンポジット磁石
Outline of Final Research Achievements

By using the synthesis process of nanoparticles by vapor quenching (Plasma-gas-condensation method), we have studied (1) searching for novel fuel cell electrocatalysts using alloy nanoparticles, (2) research on exchange coupled magnets with soft / hard magnetic composite nanoparticles, (3) research on lithium battery negative electrode materials. The results of (1)are summarized below.
By elemental mapping of STEM, Ni and Pt are distributed more inside the particles in the prepared Ni-Zn-Pt alloy nanoparticles, and Zn is distributed more outside the particles. As for the Ni-Pt and Ni-Zn-Pt alloy nanoparticles, the maximum power density increases as the amount of Pt increases. In addition, the Ni-Zn-Pt alloy nanoparticles maintain high catalytic activity even on the low Pt composition side of about 10 at.% Pt as compared with the Ni-Pt alloy nanoparticles.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (38 results)

All 2018 2017 2016 2015

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Open Access: 9 results,  Acknowledgement Compliant: 3 results) Presentation (28 results) (of which Int'l Joint Research: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Li+ ion doping into KI-KBH4 solid solvent systems: The role of the BH4- anion2018

    • Author(s)
      Miyazaki Reona、Noda Yasuto、Miyazaki Hidetoshi、Soda Kazuo、Hihara Takehiko
    • Journal Title

      J. Alloys and Compounds

      Volume: 735 Pages: 1291-1296

    • DOI

      10.1016/j.jallcom.2017.11.244

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Tailoring of Morphology and Crystalline Structure of Nanoporous TiO2-TiO-TiN Composite Films for Enhanced Capacity as Anode Materials of Lithium-Ion Batteries2018

    • Author(s)
      Kure-Chu Song-Zhu、Sakuyama Haruki、Suzuki Ei-ichi、Yashiro Hitoshi、Sasaki Kuniaki、Segawa Hiroyo、Hihara Takehiko
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 165 Issue: 3 Pages: A477-A486

    • DOI

      10.1149/2.0251803jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] PEFC catalytic properties of Pt - Ni nanoparticles prepared by a plasma-gas-condensation2017

    • Author(s)
      M. Umezawa, R. Ishikawa, R.Miyazaki, T. Hihara
    • Journal Title

      Journal of Applied Physics

      Volume: 121 Pages: 0351021-6

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Post-anneal effect on the structural and Li+ conduction properties in NaI - LiBH4 system2017

    • Author(s)
      R. Miyazaki, D. Kurihara, D. Hayashi, S. Furughori, M. Shomura, T. Hihara
    • Journal Title

      MRS Advances

      Volume: 2 Pages: 389-394

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Li+ ionic conduction properties on NaI doped with a small amount of LiBH42016

    • Author(s)
      R. Miyazaki, D. Kurihara, T. Hihara
    • Journal Title

      Journal of Solid State Electrochemistry

      Volume: 20 Pages: 2759-2764

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electric and Magnetic Evolution in Sputter-Deposited FexSi1-x Alloy Films2016

    • Author(s)
      K. Sumiyama, M. Yamazaki, T. Yoneyama, K. Suzuki, K. Takemura, Y. Kurokawa, T. Hihara
    • Journal Title

      Materials Transactions

      Volume: 57 Pages: 907-912

    • NAID

      130005153136

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electric Evolution in Sputter-Deposited Sn-cSn Si1-cSn Alloy Films2016

    • Author(s)
      K. Sumiyama, Y. Kurokawa, H. Yamada, M. Yamazaki, T. Hihara
    • Journal Title

      Materials Transactions

      Volume: 57 Pages: 903-906

    • NAID

      130005153139

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electric Evolution in Sputter-Deposited Sn<sub><i>c</i><sub>Sn</sub></sub>Si<sub>1−<i>c</i><sub>Sn</sub></sub> Alloy Films2016

    • Author(s)
      K. Sumiyama, Y. Kurokawa, H. Yamada, M. Yamazaki, T. Hihara
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 57 Issue: 6 Pages: 903-906

    • DOI

      10.2320/matertrans.M2016029

    • NAID

      130005153139

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electric and Magnetic Evolution in Sputter-Deposited Fe<sub><i>x</i></sub>Si<sub>1−<i>x</i></sub> Alloy Films2016

    • Author(s)
      K. Sumiyama, M. Yamazaki, T. Yoneyama, K. Suzuki, K. Takemura, Y. Kurokawa, T. Hihara
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 57 Issue: 6 Pages: 907-912

    • DOI

      10.2320/matertrans.M2016046

    • NAID

      130005153136

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] PEFC catalytic properties of Pt alloy nanoparticles prepared by a Plasma-Gas-Condensation2017

    • Author(s)
      M. Umezawa, R. Ishikawa, S. Nonaka, R. Miyazaki, T. Hihara
    • Organizer
      ISPlasma2017
    • Place of Presentation
      中部大学
    • Year and Date
      2017-03-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 2源プラズマ・ガス凝縮法によるNd-Fe-Nナノ粒子の作製と評価2017

    • Author(s)
      西野柾志 日原岳彦 宮崎怜雄奈
    • Organizer
      日本金属学会2017秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2源プラズマ・ガス凝縮法によるFe-PtおよびCo-Ptナノ粒子の作製2017

    • Author(s)
      小松尚徹 宮崎怜雄奈 日原岳彦
    • Organizer
      日本金属学会2017秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] CuドープZnO薄膜の磁気特性評価2017

    • Author(s)
      寺田真穂 宮崎怜雄奈 日原岳彦
    • Organizer
      日本金属学会2017秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] スパッタリング法による高融点金属酸化物薄膜の作製と磁気特性の評価2017

    • Author(s)
      大橋京平 日原岳彦 宮崎怜雄奈
    • Organizer
      日本金属学会2017秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] プラズマ・ガス凝縮法によるPt-M(M = W, Ta, Mo, Nb)合金ナノ粒子の作製と燃料電池電極触媒特性の評価2017

    • Author(s)
      石河瞭一 野中慎也 宮崎怜雄奈 日原岳彦
    • Organizer
      日本金属学会2017秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] KI-KBH4-LiI系を固体電解質に用いた全固体Li電池の試作2017

    • Author(s)
      松尾知樹 宮崎怜雄奈 日原岳彦
    • Organizer
      日本金属学会・日本鉄鋼協会東海支部主催"第27回学生による材料フォーラム"
    • Related Report
      2017 Annual Research Report
  • [Presentation] Liフリー固体溶媒からの、Liイオン伝導体の合成2017

    • Author(s)
      栗原 大 宮崎 怜雄奈 日原 岳彦
    • Organizer
      日本金属学会・日本鉄鋼協会東海支部主催"第27回学生による材料フォーラム"
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体溶媒をベースとした新規Li+伝導体の開発2017

    • Author(s)
      宮崎 怜雄奈 野田 泰 宮崎 秀俊 曽田 一雄 坂口 勲 日原 岳彦
    • Organizer
      第43回固体イオニクス討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Li Doping Behavior in KI-KBH4 Solid Solvent and Its Li+ Ion Conduction Properties2017

    • Author(s)
      Reona Miyazaki, Yasuto Noda, Hidetoshi Miyazaki, Kazuo Soda, Takehiko Hihara
    • Organizer
      2017 MRS Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Liフリー固体溶媒へのLi塩ドープによる、新規固体電解質開発2017

    • Author(s)
      宮崎怜雄奈 野田泰斗 日原岳彦
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] LiBH4ドープNaIのLi+イオン伝導特性2016

    • Author(s)
      宮崎怜雄奈、栗原 大、野田泰斗、内林 渓、竹腰清乃理、日原岳彦
    • Organizer
      2016年第42回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 固体NMRによるNaI-LiBH4固溶体におけるLiイオン伝導機構の解析2016

    • Author(s)
      野田泰斗、内林 渓、宮崎怜雄奈、栗原 大、日原岳彦、竹腰清乃理
    • Organizer
      2016年第42回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Li+ Ion Conduction Properties of NaI Doped with Small Amount of Li Salts2016

    • Author(s)
      R. Miyazaki, Y. Noda, D. Kurihara, S. Furughori, K. Uchibayashi, K. Takegoshi, T. Hihara
    • Organizer
      2016 MRS Fall Meeting
    • Place of Presentation
      Boston
    • Year and Date
      2016-11-27
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Li 塩ドープNaI の合成とLi+伝導特性2016

    • Author(s)
      宮崎怜雄奈, 栗原大, 野田泰斗, 内林渓, 竹腰清乃理, 日原岳彦
    • Organizer
      日本金属学会第159回秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] プラズマ・ガス凝縮法で作製したNi-Zn-Pt合金ナノ粒子のPEFC触媒性能評価2016

    • Author(s)
      梅澤道久, 石川瞭一, 宮崎怜雄奈, 日原岳彦
    • Organizer
      日本金属学会第159回秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Solid-State NMR reveals Li-ion transport mechanism in 15NaI&middot;LiBH42016

    • Author(s)
      Y. Noda, K. Uchibayashi, R. Miyazaki, D. Kurihara, T. Hihara, K. Takegoshi
    • Organizer
      EUROMAR 2016
    • Place of Presentation
      Aarhus, Denmark
    • Year and Date
      2016-07-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Li希薄な15NaI・LiBH4のLi+伝導機構の固体NMRによる解析2016

    • Author(s)
      野田泰斗, 内林渓, 宮崎怜雄奈, 栗原大, 日原岳彦, 竹腰清乃理
    • Organizer
      低温物質科学研究センター講演会・研究交流会
    • Place of Presentation
      京都
    • Year and Date
      2016-02-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Ni-V複合ナノ粒子の作製とPEFC触媒性能評価2016

    • Author(s)
      吉田和矢, 宮崎怜雄奈, 日原岳彦
    • Organizer
      第26回学生による材料フォーラム
    • Place of Presentation
      名古屋大学
    • Related Report
      2016 Research-status Report
  • [Presentation] 反応性プラズマ・ガス凝縮法によるNd-Fe-Nナノ粒子の作製と磁気特性2016

    • Author(s)
      河端佑太, 宮崎怜雄奈, 日原岳彦
    • Organizer
      第26回学生による材料フォーラム
    • Place of Presentation
      名古屋大学
    • Related Report
      2016 Research-status Report
  • [Presentation] 2源プラズマ・ガス凝縮法によるCoPtナノ粒子の作製2016

    • Author(s)
      高橋伸幸, 宮崎怜雄奈, 日原岳彦
    • Organizer
      第26回学生による材料フォーラム
    • Place of Presentation
      名古屋大学
    • Related Report
      2016 Research-status Report
  • [Presentation] スパッタリング蒸着法で作製したMn-ZnO薄膜の磁気特性2016

    • Author(s)
      白木聡一, 宮崎怜雄奈, 日原岳彦
    • Organizer
      第26回学生による材料フォーラム
    • Place of Presentation
      名古屋大学
    • Related Report
      2016 Research-status Report
  • [Presentation] Ni-Zn-Pt合金ナノ粒子の作製とPEFC触媒性能評価2016

    • Author(s)
      梅澤道久, 宮崎怜雄奈, 日原岳彦
    • Organizer
      第26回学生による材料フォーラム
    • Place of Presentation
      名古屋大学
    • Related Report
      2016 Research-status Report
  • [Presentation] スパッタリング法で作製した酸化ハフニウム薄膜の磁気特性の評価2015

    • Author(s)
      加藤大祐,宮崎怜雄奈,日原岳彦
    • Organizer
      第25回学生による材料フォーラム
    • Place of Presentation
      豊橋
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズマ・ガス凝縮法によるFe-Pt複合ナノ粒子の作製と磁気特性評価2015

    • Author(s)
      羽場雅史,宮崎怜雄奈,日原岳彦
    • Organizer
      第25回学生による材料フォーラム
    • Place of Presentation
      豊橋
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズマガス凝縮法によるPt-Ni複合ナノ粒子の作製と燃料電池電極触媒特性の評価2015

    • Author(s)
      三ツ井正人,宮崎怜雄奈,日原岳彦
    • Organizer
      第25回学生による材料フォーラム
    • Place of Presentation
      豊橋
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] LiBH4添加NaIの合成とイオン伝導特性2015

    • Author(s)
      宮崎怜雄奈、日原岳彦
    • Organizer
      第26回東海地区光電気化学研究会・2015年東海地区ヤングエレクトロケミスト研究会合同講演会
    • Place of Presentation
      名古屋
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズマ・ガス凝縮法で作製したNi基ナノ合金粒子の電極触媒特性の評価2015

    • Author(s)
      梅澤道久,宮崎怜雄奈,日原岳彦
    • Organizer
      日本金属学会2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] Pt-Zn-Ni系コアシェル粒子2016

    • Inventor(s)
      宮崎怜雄奈、日原岳彦、梅澤道久、石河瞭一
    • Industrial Property Rights Holder
      宮崎怜雄奈、日原岳彦、梅澤道久、石河瞭一
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-064650
    • Filing Date
      2016-03-28
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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