NANO-SCALE SELF-ASSEMBLED POLYMER MEMBRANES WITH HYDROGEN SEPARATION CHANNELS

• Project/Area Number: 15K06493
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: Meiji University
• Principal Investigator: NAGAI KAZUKIYO 明治大学, 理工学部, 専任教授 (40350269)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
• Keywords: 自己組織化 / 水素社会 / 水素分離 / 分離チャンネル / 膜分離 / ポリイミド / ATRP / 薄膜 / マクロイニチエータ

Outline of Final Research Achievements

Nano-scale self-assembled polymer membranes with hydrogen separation channels were prepared for separation of an industrially important gas, hydrogen. Unlike common polymer membranes designed based on the solution-diffusion mechanism, hydrogen separation channels were produced using ABA-type triblock copolymers composed of polyimide and polymethylmethacrylate.

Research Products

• [Journal Article] Gas separation properties of amine crosslinked polyimide membranes modified by amine vapor (2017)
  • Author(s): T. Yoshioka, K. Kojima, R. Shindo, and K. Nagai
  • Journal Title: J. Appl. Polym. Sci. Volume: 134 Issue: 10 Pages: 1-9
  • DOI: 10.1002/app.44569
  • Peer Reviewed
• [Journal Article] Photoelectric properties of ABA-type triblock copolymers designed using fluorine-containing polyimide macroinitiators with polyhedral oligomeric silsesquioxane (2017)
  • Author(s): S. Sato, M. Ichikawa, E. Suzuki, H. Matsumoto, and K. Nagai
  • Journal Title: Polym. Eng. Sci. Volume: 57 Issue: 11 Pages: 1207-1213
  • DOI: 10.1002/pen.24498
  • Peer Reviewed
• [Journal Article] Permeability of dried gases and gases dissolved in water through polyimide membranes modified by immersing in amino compound solutions (2016)
  • Author(s): R. Shindo, N. Yamanaka, T. Wakamatsu, and K. Nagai
  • Journal Title: Polym. Eng. Sci. Volume: 56 Issue: 2 Pages: 178-186
  • DOI: 10.1002/pen.24241
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Phototransparency and water vapor sorption properties of ABA-type triblock copolymers derived from 6FDA-TeMPD and poly(2-methyl-2-adamantylmethacrylate) (2016)
  • Author(s): S. Ando, S. Konishi, A. Yoshida, and K. Nagai
  • Journal Title: J. Appl. Polym. Sci. Volume: 10 Issue: 32 Pages: 1-9
  • DOI: 10.1002/app.43795
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Preparation of porous membranes by selective decomposition of adamantane unit in ABA-type triblock copolymer (2016)
  • Author(s): S. Ando, A. Yoshida, and K. Nagai
  • Journal Title: Polym. Eng. Sci. Volume: 10 Issue: 10 Pages: 1-10
  • DOI: 10.1002/pen.24353
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and gas permeability of ABA-type triblock copolymers derived from fluorine-containing polyimide with polyhedral origomeric silsesquioxane (2015)
  • Author(s): T. Suzuki, A. Yoshida, S. Ando, and K. Nagai
  • Journal Title: Polym. Int. Volume: N/A Issue: 9 Pages: 1209-1218
  • DOI: 10.1002/pi.4897
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Effects of thermal treatment on the CO2 sorption of triblockcopolymers derived from polyimide and poly(methylmethacrylate) (2015)
  • Author(s): S. Ando, A. Yoshida, and K. Nagai
  • Journal Title: J. Appl. Polym. Sci. Volume: N/A Issue: 27 Pages: 1-12
  • DOI: 10.1002/app.42208
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] ポリイミド・メタクリル酸誘導体からなるABA型トリブロックコポリマーの合成と物性 (2017)
  • Author(s): 川底 航、笹子洋平、塩田龍之介、吉田明弘、安藤翔太、永井一清
  • Organizer: 第66回高分子学会年次大会
• [Presentation] ポリイミド・水酸基含有アダマンタン誘導体からなるABA型トリブロックコポリマーの合成と膜物性 (2017)
  • Author(s): 伊藤翼、塩田龍之介、谷口奈織美、吉田明弘、安藤翔太、永井一清
  • Organizer: 第66回高分子討論会
• [Presentation] ATRP法を用いたポリイミドからなるABA型トリブロックコポリマーの合成と水蒸気透過特性 (2016)
  • Author(s): 笹子洋平、塩田龍之介、鈴木翔、吉田明弘、安藤翔太、永井一清
  • Organizer: 第54回高分子と水に関する討論会
  • Place of Presentation: 東京工業大学
  • Year and Date: 2016-12-08
• [Presentation] Preparation of porous membranes by selective decomposition of adamantane unit in ABA-type triblock copolymer derived from polyimide and Adamantane derivative (2016)
  • Author(s): 安藤翔太、永井一清
  • Organizer: 252th American Chemical Society National Meeting & Exposition
  • Place of Presentation: Pennsylvania Convention Center, USA
  • Year and Date: 2016-08-23
  • Int'l Joint Research
• [Presentation] Gas Separation Polymer Membranes in Energy and Environmental Fields (2016)
  • Author(s): 永井一清
  • Organizer: XXV International Materials Research Congress 2016
  • Place of Presentation: Cancun, Mexico
  • Year and Date: 2016-08-15
  • Int'l Joint Research / Invited
• [Presentation] ポリイミドと親水性アダマンタンからなる新規複合材料の合成と溶存気体透過特性 (2016)
  • Author(s): 塩田龍之介、笹子洋平、鈴木翔、吉田明弘、安藤翔太、永井一清
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2016-05-27
• [Presentation] ポリイミド・HEMAからなるABA型トリブロックコポリマーの合成と物性 (2015)
  • Author(s): 笹子 洋平、塩田 龍之介、谷口 奈織美、 吉田 明弘、 安藤 翔太、 永井 一清
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学川内キャンパス
  • Year and Date: 2015-09-17
• [Presentation] ポリイミド・水酸基含有アダマンチルメタクリレートからなるABA型トリブロックコポリマーの合成と溶存気体透過特性 (2015)
  • Author(s): 塩田 龍之介、鈴木 翔、吉田 明弘、安藤 翔太、永井 一清
  • Organizer: 第64回高分子学会年次大会
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2015-05-28
• [Presentation] ポリイミドと水酸基を有するアダマンタンからなるABA型トリブロックコポリマーの合成と物性 (2015)
  • Author(s): 谷口 奈織美、鈴木 翔、市川 雅人、吉田 明弘、安藤 翔太、永井 一清
  • Organizer: 第64回高分子学会年次大会
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2015-05-28
• [Book] ポリイミドの機能向上技術と応用展開 (2017)
  • Author(s): 岩佐怜穂，風間伸吾，永井一清
  • Total Pages: 237
  • Publisher: シーエムシー出版
  • ISBN: 9784781312439
• [Remarks] 明治大学理工学部永井一清研究室ホームページ
  • URL: http://www.isc.meiji.ac.jp/~nagailab/