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High-efficient separation and recovery of harmful metal ions using magnetic electroactive ion exchange particles

Research Project

Project/Area Number 15K06532
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionHirosaki University

Principal Investigator

GUAN Guoqing  弘前大学, 北日本新エネルギー研究所, 教授 (90573618)

Co-Investigator(Kenkyū-buntansha) 阿布 里提  弘前大学, 理工学研究科, 教授 (70565374)
Co-Investigator(Renkei-kenkyūsha) KUSAKABE Katsuki  崇城大学, 工学部ナノサイエンス学科, 教授 (30153274)
Research Collaborator HAO Xiaogang  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords磁性電気活性粒子 / イオン分離 / 吸着 / 脱着 / 連続分離回収システム / 金属イオン / 電気化学特性 / 分離効率 / 分離回収システム / 電磁石制御 / 分離回収 / イオン交換 / 磁性粒子
Outline of Final Research Achievements

In this study, magnetic electroactive ion exchange particles with uniform sizes were synthesized and used for continuous separation and recovery of target metal ions such as cesium ions in a designed compacted electro-maganetic experimental equipment. The experimental conditions for continuous adsorption/ desorption of the target metal ions were optimized by investigating the effects of the initial concentration of target metal ions, the initial concentrations of coexisting ions, the amount of magnetic particles, the applied voltage and the electrode distance on the separation efficiency to the target cesium ion. In addition, the adsorption/desorption mechanism of magnetic electroactive particles for the target metal ions was clarified. Further, the recycle stability when repeatedly used was examined. Furthermore, a target metal ion continuous separation recovery system that can be put to the practical use was constructed theoretically.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (22 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (13 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 13 results,  Acknowledgement Compliant: 6 results) Presentation (5 results) Remarks (1 results)

  • [Int'l Joint Research] 太原理工大学(中国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 太原理工大学(中国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] 太原理工大学(中国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Potential-induced reversible uptake/release of perchlorate from wastewater by polypyrrole@CoNi-layered double hydroxide modified electrode with proton-ligand effect2018

    • Author(s)
      Yang Yanyan、Du Xiao、An Xiaowei、Ding Shengqi、Liu Feifan、Zhang Zhonglin、Ma Xuli、Hao Xiaogang、Guan Guoqing、Zhang Hui
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 523 Pages: 159-168

    • DOI

      10.1016/j.jcis.2018.03.098

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A smart potential-responsive ion exchange nanomaterial with superparamagnetism for cesium ion separation and recovery2017

    • Author(s)
      Wang Zhongde、Guo Shoujing、Wu Zhijun、Fan Huiling、Guan Guoqing、Hao Xiaogang
    • Journal Title

      Separation and Purification Technology

      Volume: 187 Pages: 199-206

    • DOI

      10.1016/j.seppur.2017.06.033

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An Electroactive and Regenerable Fe3O4@Polypyrrole Nanocomposite: Fabrication and Its Defluorination in an Electromagnetic Coupling System2017

    • Author(s)
      Wang Meijuan、Yan Wenjun、Kong Wei、Wu Zhijun、An Xiaowei、Wang Zhongde、Hao Xiaogang、Guan Guoqing
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 44 Pages: 12738-12744

    • DOI

      10.1021/acs.iecr.7b02601

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An electrochemically-switched BPEI-CQD/PPy/PSS membrane for selective separation of dilute copper ions from wastewater2017

    • Author(s)
      Gao Fengfeng、Du Xiao、Hao Xiaogang、Li Shasha、An Xiaowei、Liu Mimi、Han Nianchen、Wang Tonghua、Guan Guoqing
    • Journal Title

      Chemical Engineering Journal

      Volume: 328 Pages: 293-303

    • DOI

      10.1016/j.cej.2017.06.177

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Intelligent nanospheres with potential-triggered undamaged regeneration ability and superparamagnetism for selective separation of cesium ion2017

    • Author(s)
      Wu Zhijun、Wang Meijuan、An Xiaowei、Du Juan、Fan Huiling、Lin Naiming、Wang Zhongde、Hao Xiaogang、Guan Guoqing
    • Journal Title

      Chemical Engineering Journal

      Volume: 325 Pages: 229-238

    • DOI

      10.1016/j.cej.2017.05.006

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electrical double layer ion transport with cell voltage-pulse potential coupling circuit for separating dilute lead ions from wastewater2017

    • Author(s)
      Gao Fengfeng、Du Xiao、Hao Xiaogang、Li Shasha、Zheng Junlan、Yang Yanyan、Han Nianchen、Guan Guoqing
    • Journal Title

      Journal of Membrane Science

      Volume: 535 Pages: 20-27

    • DOI

      10.1016/j.memsci.2017.04.009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A novel electric-field-accelerated ion-sieve membrane system coupling potential-oscillation for alkali metal ions separation2017

    • Author(s)
      Du Xiao、Ma Xuli、Zhang Pengle、Zheng Junlan、Wang Zhongde、Gao Fengfeng、Hao Xiaogang、Liu Shibin、Guan Guoqing
    • Journal Title

      Electrochimica Acta

      Volume: 258 Pages: 718-726

    • DOI

      10.1016/j.electacta.2017.11.118

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A potential-controlled ion pump based on a three-dimensional PPy@GO membrane for separating dilute lead ions from wastewater2017

    • Author(s)
      Fengfeng Gao, Xiao Du, Xiaogang Hao, Shasha Li, Junlan Zheng, Yanyan Yang, Nianchen Han, Guoqing Guan
    • Journal Title

      Electrochimica Acta

      Volume: - Pages: 434-442

    • DOI

      10.1016/j.electacta.2017.03.187

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A Novel Electroactive λ-MnO2/PPy/PSS Core-Shell Nanorods Coated Electrode for Selective Recovery of Lithium Ions with Low Concentration2016

    • Author(s)
      Xiao Du, Guoqing Guan, Xiumin Li, Ajay D Jagadale, Xuli Ma, Zhongde Wang, Xiaogang Hao, Abuliti Abudula
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 4 Issue: 36 Pages: 13989-13996

    • DOI

      10.1039/c6ta05985f

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Controlled Self-Assembly of Oligomers-Grafted Fibrous Polyaniline/Single Zirconium Phosphate Nanosheet Hybrids with Potential-Responsive Ion Exchange Properties2016

    • Author(s)
      Xiao Du, Quan Zhang, Wenlei Qiao, Xiaolong Sun, Xuli Ma, Xiaogang Hao, Zhongde Wang, Abuliti Abudula, Guoqing Guan
    • Journal Title

      Chemical Engineering Journal

      Volume: 302 Pages: 516-525

    • DOI

      10.1016/j.cej.2016.05.066

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Reaction Kinetics Study of All cis-Polyaniline Nanotube Film Modified Electrode for Fast Ascorbic Acid Detecting2016

    • Author(s)
      Xuli Ma, Lianxi Si, Xiumin Li, Haiyan Du, Xiaogang Hao, Zhongde Wang, Abuliti Abudula, Guoqing Guan
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 49 Issue: 10 Pages: 937-942

    • DOI

      10.1252/jcej.15we314

    • NAID

      130005431641

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] An in Situ Potential-Enhanced Ion Transport System Based on FeHCF/PPy/PSS Membrane for the Removal of Ca2+ and Mg2+ from Dilute Aqueous Solution2016

    • Author(s)
      Pengle Zhang, Junlan Zheng, Zhongde Wang, Xiao Du, Fengfeng Gao, Xiaogang Hao, Guoqing Guan, Chuncheng Li, Shibin Liu
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 55 Issue: 21 Pages: 6198-6203

    • DOI

      10.1021/acs.iecr.6b00597

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electroactive Ion Exchange Materials: Current Status in Synthesis, Applications and Future Prospects2016

    • Author(s)
      Xiao Du, Xiaogang Hao,Zhongde Wang, Guoqing Guan
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 4 Issue: 17 Pages: 6236-6258

    • DOI

      10.1039/c6ta01385f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 電気活性イオン選択透過膜を用いた重金属イオンの分離2018

    • Author(s)
      官国清、吉田曉弘、阿布里提 、Xiaogang Hao、Xiao Du、 Fengfeng Gao
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Superparamagnetic Spherical Prussian Blue Particles for Effective Cesium Removal form Aqueous Solution2017

    • Author(s)
      Junlan Zheng, Xiumin Li, Xiaogang Hao, Abuliti Abudula and Guoqing Guan
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都江東区)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 磁性電気活性粒子を用いたセシウムイオンの選択的な分離2017

    • Author(s)
      官国清、鄭君蘭、吉田曉弘、阿布里提、Zhijun Wu、Zhongde Wang、Xiaogang Hao
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁性電活性イオン交換粒子を用いた水中有害イオンの除去2016

    • Author(s)
      官国清、鄭君蘭、王忠徳、Xiaogang Hao、阿布里提
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Research-status Report
  • [Presentation] One-step unipolar pulse electrodeposition of HMn2O4/ PPy/PSS hybrid film with high selectivity for recovery of lithium from seawater2015

    • Author(s)
      Xiao Du、Xuli Ma、Jagadale Ajay、Xiaogang Hao、官国清、阿布里提
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Remarks]

    • URL

      https://sites.google.com/site/energyconversionengineering/home/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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