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Development of temperature-responsive magnetic adsorbent -Control of pore entrance size and dispersion/aggregation state by temperature-

Research Project

Project/Area Number 15K06536
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionAkita University

Principal Investigator

Murakami Kenji  秋田大学, 理工学研究科, 教授 (10272030)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords温度応答性吸着剤 / 磁性吸着剤 / 感温性高分子 / 分子ふるい / 有機無機複合体 / マグネタイト
Outline of Final Research Achievements

A mesoporous silica (MS) adsorbent with temperature sensitivity and magnetism was synthesized. At first, hematite was precipitated on the MS surface, and then a MS coated with magnetite (MMS) was produced by reduction. Furthermore, this MMS was coated with PNIPAM (Amino-PMMS). Results of thermogravimetry showed the amount of PNIPAM in the Amino-PMMS was around 2.4 wt%. Also, the Amino-PMMS was well attracted by a magnet. The Amino-PMMS adsorbed around 0.19 mmol/g of methyl orange (MO) at room temperature, whereas it adsorbed only around 0.08 mmol / g of MO at 42°C (above the lower critical solution temperature of PNIPAM). This indicates that the synthesized Amino-PMMS is a temperature-responsive adsorbent.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (16 results)

All 2018 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (13 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] メソポーラマグネタイトの合成と染料吸着性能の評価2018

    • Author(s)
      安野恵理,菅原諒祐,中村彩乃,村上賢治
    • Journal Title

      化学工学論文集(印刷中)

      Volume: -

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Thermo-Responsive Separation Membrane and Evaluation of Its Separation Properties2016

    • Author(s)
      澤田峻一,木村瑠璃子,村上賢治
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 42 Issue: 3 Pages: 107-112

    • DOI

      10.1252/kakoronbunshu.42.107

    • NAID

      130005152192

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 磁性メソポーラス酸化鉄の合成と吸着剤への応用2017

    • Author(s)
      安野恵理,今井あゆみ,菅原諒祐,中村彩乃,村上賢治
    • Organizer
      化学工学会東北支部第19回先端研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of Magnetic Mesoporous Iron Oxide (MMIO) and Evalution of Its Adosorption Property2017

    • Author(s)
      安野恵理,今井あゆみ,菅原諒祐,中村彩乃,村上賢治
    • Organizer
      平成29年度化学系学協会東北大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁性メソポーラス酸化鉄の合成条件の検討及び染料吸着性能の評価2017

    • Author(s)
      安野恵理,菅原諒祐,中村彩乃,村上賢治
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 感温性高分子/無機化合物複合体の合成とその応用2017

    • Author(s)
      村上賢治
    • Organizer
      元素機能科学プロジェクトセミナー
    • Place of Presentation
      群馬大学(群馬県桐生市)
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Separating magnetite loaded adsorbent from water by High-Gradient Magnetic Separation method2016

    • Author(s)
      Ayano Nakamura, Kohei Sugawara, Syunsuke Nakajima, Kenji Murakami
    • Organizer
      6th International Conference on Sustainable Energy and Environment (SEE2016)
    • Place of Presentation
      Dusit Thani Bangkok(タイ,バンコク)
    • Year and Date
      2016-11-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 懸濁液中土壌粒子の磁気分離用凝集剤の開発2016

    • Author(s)
      村上賢治,菅原浩平,山川武尊,中村彩乃,中島春介
    • Organizer
      化学工学会福島大会2016
    • Place of Presentation
      コラッセ福島(福島県福島市)
    • Year and Date
      2016-11-25
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of Temperature-Responsive Polymer on Flocculating Soil Particles2016

    • Author(s)
      中村彩乃,菅原浩平,グェン トゥイ ガー,中島春介,村上賢治
    • Organizer
      平成28年度化学系学協会東北大会
    • Place of Presentation
      いわき明星大学(福島県いわき市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Research-status Report
  • [Presentation] ,“Reduction of sediment volume of soil particles in suspension by adding temperature-responsive polymer2016

    • Author(s)
      グェン トゥイ ガー,中村彩乃,中島春介,村上賢治
    • Organizer
      平成28年度化学系学協会東北大会
    • Place of Presentation
      いわき明星大学(福島県いわき市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Research-status Report
  • [Presentation] Synthesis and Characterization of Magnetic Mesoporous Iron Oxide by Soft-templating Method2016

    • Author(s)
      安野恵理,阿仁屋拓道,中村彩乃,村上賢治
    • Organizer
      平成28年度化学系学協会東北大会
    • Place of Presentation
      いわき明星大学(福島県いわき市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Research-status Report
  • [Presentation] 土壌粒子の凝集挙動に及ぼす温度応答性高分子添加の影響2016

    • Author(s)
      中村彩乃,グェン トゥイ ガー,中島春介,村上賢治
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 感温性高分子の添加による懸濁液中土壌粒子の磁気分離効率の向上2016

    • Author(s)
      菅原浩平,玉置友宏,中島春介,中村彩乃,村上賢治
    • Organizer
      化学工学会第48回春季大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Synthesis of magnetic mesoporous materials2015

    • Author(s)
      渡辺英樹,阿仁屋拓道,村上賢治
    • Organizer
      平成27年度化学系学協会東北大会
    • Place of Presentation
      弘前大学文京キャンパス
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] Evaluation of Cs adsorption and desorption properties of zeolite and application to magnetic separation2015

    • Author(s)
      菅原浩平,雄鹿高弘,村上賢治
    • Organizer
      平成27年度化学系学協会東北大会
    • Place of Presentation
      弘前大学文京キャンパス
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Remarks] 秋田大学 村上研究室 ホームページ

    • URL

      http://www.gipc.akita-u.ac.jp/~physchem/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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