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Laser assisted nano material synthesis and morphological control by controling physical property of supercritical fluid

Research Project

Project/Area Number 15K06540
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKanazawa University

Principal Investigator

HIGASHI Hidenori  金沢大学, 自然システム学系, 准教授 (40294889)

Co-Investigator(Kenkyū-buntansha) 瀬戸 章文  金沢大学, 自然システム学系, 教授 (40344155)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords超臨界二酸化炭素 / レーザーアブレーション / プルーム / ナノカーボン / ダイヤモンド / グラファイト / アモルファス / 形態制御 / プルームサイズ / 可視化セル / 観察 / 結晶性 / ナノダイヤモンド
Outline of Final Research Achievements

We performed generation of nanocarbon by irradiating the graphite target with laser light in supercritical carbon dioxide. The density of supercritical carbon dioxide was adjusted by changing the pressure. As a result of morphological observation and particle size distribution measurement of the obtained nanocarbon, most of the nanoparticles were aggregates of amorphous carbon having low crystallinity under low pressure and high pressure conditions. On the other hand, a lot of isolated spherical particles were observed in the nanoparticles generated under the condition of the critical density (approximately 8 MPa). It is indicated that particularly fine particles will have high crystallinity and show a diamond structure based on the distance between crystal lattices by the results of high resolution TEM image and restricted field electron beam diffraction image.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (6 results)

All 2017 2016 2015

All Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] Synthesis of Nanocarbon by Pulsed Laser Ablation of Graphite in Supercritical Carbon Dioxide2017

    • Author(s)
      Kazuki Maejima, Hidenori Higashi, Toru Yoshikawa, Mikio Kumita, Takafumi Seto and Yoshio Otani
    • Organizer
      The 6th International Symposium on Micro and Nano Technology
    • Place of Presentation
      九州大学医学部百年講堂
    • Year and Date
      2017-03-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 超臨界二酸化炭素中でのレーザーアブレーションによるナノカーボン生成に及ぼすプルームサイズの影響2017

    • Author(s)
      前島 一輝,東 秀憲,汲田 幹夫,瀬戸 章文,大谷 吉生
    • Organizer
      化学工学会 関西支部・中国四国支部合同 金沢大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of Surrounding Fluid Properties on Morphology of Carbon Nanoparticles Generated by Pulsed Laser Ablation in Carbon Dioxide2017

    • Author(s)
      Kazuki Maejima, Hidenori Higashi, Mikio Kumita, Takafumi Seto, Yoshio Otani
    • Organizer
      10th International Conference on Supercritical Fluids (Supergreen2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] レーザーアブレーション法により生成する炭素ナノ粒子の形態に及ぼす雰囲気流体の影響2016

    • Author(s)
      東秀憲,吉川徹,汲田幹夫,瀬戸章文,大谷吉生
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Fabrication of Nanocarbon by Irradiating Pulse Laser in Supercritical Carbon Dioxide2015

    • Author(s)
      Toru Yoshikawa, Hidenori Higashi, Mikio Kumita , Takafumi Seto and Yoshio Otani
    • Organizer
      7th International Symposium on Molecular Thermodynamics and Molecular Simulation (MTMS'15)
    • Place of Presentation
      福岡大学
    • Year and Date
      2015-08-04
    • Related Report
      2015 Research-status Report
  • [Presentation] 超臨界流体中のレーザーアブレーションによるナノカーボンの合成2015

    • Author(s)
      吉川徹,東秀憲, 汲田幹夫,瀬戸章文,大谷吉生
    • Organizer
      2015年度粉体工学会春期研究発表会
    • Place of Presentation
      連合会館
    • Year and Date
      2015-05-19
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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