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Development of microporous ceramic-organic composite phase membranes for gas separation by utilizing chelating ligands

Research Project

Project/Area Number 15K06545
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKobe University (2016-2017)
Hiroshima University (2015)

Principal Investigator

Yoshioka Tomohisa  神戸大学, 科学技術イノベーション研究科, 教授 (50284162)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords二酸化炭素分離 / ナノろ過 / セラミック / キレート / チタニア / ジルコニア / 分子シミュレーション
Outline of Final Research Achievements

Organic chelating ligands could be remained in a ceramic membrane when it was calcined at 350 dgree C in nitrogen atmosphere. TiO2-ZrO2-Dopaine sol coated membranes on alumina support showed a CO2/N2 permeation ratio of 20 at 35 degree C, which indicated that TiO2-ZrO2-based gas separation membranes could be prepared. On the other hand, TiO2-ZrO2 membranes, prepared by removing organic chelate ligand as a template for forming porous structures, had fractionation performance of molecular weight cut-off around 2,000. This type of membrane is promising for a nanofiltration membrane. From the results of non-equilibrium molecular dynamics permeation simulations under a pressure gradient condition, molecular permeation flux would depend on interaction of permeating molecules with pore surface.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results) Presentation (18 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] Water transport and ion rejection investigation for application of cyclic peptide nanotubes to forward osmosis process: A simulation study2017

    • Author(s)
      H. Wu, T. Yoshioka, K. Nakagawa, T. Shintani, T. Tsuru, D. Saeki, Y. Chen, K Tung, H. Matsuyama
    • Journal Title

      Desalination

      Volume: 424 Pages: 85-94

    • DOI

      10.1016/j.desal.2017.09.008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 日本における膜分離法によるCO2 分離回収技術2017

    • Author(s)
      神尾英治,吉岡朋久
    • Journal Title

      膜(MEMBRANE)

      Volume: 42 Pages: 2-10

    • NAID

      130005403840

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] キレート配位子を鋳型とするナノ多孔性TiO2-ZrO2複合膜の作製と特性評価2018

    • Author(s)
      貞佑樹, 吉岡朋久, 中川敬三, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] TiO2-ZrO2-有機キレート配位子複合ガス分離膜の作製とCO2透過特性の評価2018

    • Author(s)
      平井翔一, 吉岡朋久, 中川敬三, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] TiO2-ZrO2-有機キレート複合材料の特性評価とCO2分離膜への応用2017

    • Author(s)
      平井翔一,吉岡朋久,中川敬三,新谷卓司,神尾英治,松山秀人
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学,東京
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機キレートをテンプレートとする多孔性TiO2-ZrO2複合膜の特性評価2017

    • Author(s)
      貞佑樹, 吉岡朋久, 中川敬三, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      日本膜学会第39年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 日本における膜分離法によるCO2分離回収技術2017

    • Author(s)
      吉岡朋久, 神尾英治
    • Organizer
      日本膜学会第39年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Characterization of porous titania-zirconia composite membrane materials prepared by using organic chelating ligands2017

    • Author(s)
      T. Yoshioka, Y. Sada, K. Nakagawa, T. Shintani, E. Kamio, H. Matsuyama
    • Organizer
      11th International Congress on Membranes and Membrane Processes (ICOM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of gas molecular properties on characterization of microporous membrane structures based on the modified GT model: molecular dynamics study2017

    • Author(s)
      T. Yoshioka, K. Tamaoki, H. Nagasawa, M. Kanezashi, T. Tsuru
    • Organizer
      11th International Congress on Membranes and Membrane Processes (ICOM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多孔性TiO2-ZrO2複合膜材料のナノ細孔構造に及ぼす有機キレート配位子の影響2017

    • Author(s)
      貞佑樹, 吉岡朋久, 中川敬三, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      分離技術会年会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] TiO2ナノ細孔内水透過シミュレーションと透過モデルによる解析2017

    • Author(s)
      鈴木悠太, 吉岡朋久, 中川敬三, 新谷卓司, 三野泰志, 神尾英治, 松山秀人
    • Organizer
      分離技術会年会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Characterization of nanoporous titania-zirconia composite membranes2017

    • Author(s)
      Y. Sasda, T. Yoshioka, K. Nakagawa, T. Shintani, E. Kamio, H. Matsuyama
    • Organizer
      The 11th International Conference on Separation Science and Technology (ICSST17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Non-equilibrium molecular dynamics simulation of water transport2017

    • Author(s)
      Y. Suzuki, T. Yoshioka, K. Nakagawa, T. Shintani, Y. Mino, E. Kamio, H. Matsuyama
    • Organizer
      The 11th International Conference on Separation Science and Technology (ICSST17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TiO2-ZrO2-有機キレート複合材料を用いたCO2分離膜の作製と特性評価2017

    • Author(s)
      平井翔一, 吉岡朋久, 中川敬三, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      膜シンポジウム2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機キレートを用いた多孔性TiO2-ZrO2複合膜の作製と構造評価2017

    • Author(s)
      貞佑樹,吉岡朋久,中川敬三,新谷卓司,神尾英治,松山秀人
    • Organizer
      第19回化学工学会学生発表会
    • Place of Presentation
      大阪大学,大阪
    • Related Report
      2016 Research-status Report
  • [Presentation] CO2 permeation and CO2/N2 separation characteristics of sol-gel derived microporous amino-silica membranes2016

    • Author(s)
      T. Yoshioka1, Y. Nagao, H. Nagasawa, M. Kanezashi, T. Tsuru
    • Organizer
      THE 5TH ASIAN CONFERENCE ON INNOVATIVE ENERGY & ENVIRONMENTAL CHEMICAL ENGINEERING (ASCON-IEEChE 2016)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-11-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation and gas permeation characteristics of microporous amorphous TiO2-ZrO2-Dopamine membranes2016

    • Author(s)
      T. Yoshioka, Y. Ushio, H. Nagasawa, M. Kanezashi, T. Tsuru
    • Organizer
      The 10th Conference of Aseanian Membrane Society (AMS10)
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-07-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子動力学法による有効透過分子径評価と分子形状が気体透過特性に及ぼす影響2015

    • Author(s)
      玉沖和也,吉岡朋久,長澤寛規,金指正言,都留稔了
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学
    • Year and Date
      2015-11-25
    • Related Report
      2015 Research-status Report
  • [Presentation] 多孔性アミノシリカ膜のCO2透過特性に及ぼすCsドープおよび製膜条件の影響2015

    • Author(s)
      永尾享春,吉岡朋久,長澤寛規,金指正言,都留稔了
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 分子動力学法を用いたOH基を有するオルガノシリカ膜の分子透過性評価2015

    • Author(s)
      成清慎太朗,吉岡朋久,長澤寛規,金指正言,都留稔了
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Book] Current Trends and Future Developments on (Bio-) Membranes Silica Membranes: Preparation, Modelling, Application, and Commercialization, Chapter 5: Molecular dynamic (MD) simulation of silica membranes2017

    • Author(s)
      Tomohisa Yoshioka
    • Total Pages
      378
    • Publisher
      Elsevier
    • ISBN
      9780444638663
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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