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Study on the formation of single-layered nano-catalytic particle films with large area under extremely thin-layer surface plasma

Research Project

Project/Area Number 15K06573
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionNational Institutes for Quantum and Radiological Science and Technology (2016-2017)
Japan Atomic Energy Agency (2015)

Principal Investigator

Hakoda Teruyuki  国立研究開発法人量子科学技術研究開発機構, 量子ビーム科学研究部門, 研究企画室長(定常) (70354933)

Co-Investigator(Kenkyū-buntansha) 山本 春也  国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 上席研究員(定常) (70354941)
Co-Investigator(Renkei-kenkyūsha) SHIMOYAMA Iwao  独立行政法人日本原子力研究開発機構, 原子力科学研究部門・原子力科学研究部門・物質科学研究センター, 研究主幹 (10425572)
ARITANI Hirofumi  埼玉工業大学, 工学部, 准教授 (40303929)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords触媒・化学プロセス / 触媒調製化学 / ナノ粒子
Outline of Final Research Achievements

For the purpose of the formation of single-layered nano-catalytic particle films with large area under extremely thin-layer surface plasma, aqueous solutions containing single or multiple components of noble metal ions in the presence of 0.5-20v% alcohol (2-propanol or ethanol) were irradiated with a few tens keV electron beams (EBs). Thin films with large area were produced on the surface of the irradiated solution at low concentrations of alcohol. The formation mechanism of nanoparticles and the films was clarified based on their structural and chemical analysis. Furthermore, the films were observed to be catalytic activity. These results opened up the possibility of the new catalytic production method using extremely thin-layer surface plasma.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (4 results)

All 2017 2016 2015

All Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Presentation] 水溶液表面でのナノ粒子薄膜の生成2017

    • Author(s)
      毒島梨那, 廣瀨尚之, 箱田照幸, 山本春也, 有谷博文
    • Organizer
      日本化学会関東支部群馬地区研究交流発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Orientational control of CeO2 films on sapphire substrates grown by magnetron sputtering2016

    • Author(s)
      S. Yamamoto, M. Sugimoto, H. Koshikawa, T. Hakoda, T. Yamaki
    • Organizer
      18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] γ線照射したPt及びPdエピタキシャル膜のRBS/channeling解析2015

    • Author(s)
      山本春也, 島田明彦, 宮下敦巳, 箱田照幸
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      産業貿易センタービル(神奈川県横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Research-status Report
  • [Presentation] 電子線誘起極表層プラズマ反応場を利用した金ナノ粒子膜の生成2015

    • Author(s)
      箱田照幸, 高橋絢香, 島田明彦, 山本春也, 有谷博文, 八巻徹也
    • Organizer
      第39 回静電気学会全国大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス(東京都八王子)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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