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Influence of charge delocalization in nanofabrication induced by ionizing radiations

Research Project

Project/Area Number 15K06662
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear engineering
Research InstitutionHokkaido University

Principal Investigator

Okamoto Kazumasa  北海道大学, 工学研究院, 助教 (10437353)

Co-Investigator(Renkei-kenkyūsha) KOZAWA Takahiro  大阪大学, 産業科学研究所, 教授 (20251374)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords放射線化学 / レジスト / パルスラジオリシス / 電子線 / 極端紫外線(EUV) / 半導体超微細化 / ラジカルイオン / 放射線、X線、粒子線 / 芳香族分子 / EUVリソグラフィ / ΠーΠ相互作用 / 放射線、X線、粒子線
Outline of Final Research Achievements

Extreme-ultraviolet (EUV) lithography has attracted attention as the most up-to-date semiconductor mass production technology using an ionizing radiation. In the resist material, the radiation chemical reaction is induced by ionization after the exposure and then the solubility in the developer is changed. Although the dynamics of charges in the resist after ionization is important for nanolithography, details have been not yet clarified. In this study, we tried to clarify the behavior of excess charges in the aromatic molecule which is the main component of the resist by using the electron beam pulse radiolysis method etc. We also proposed a new method to improve resist performance.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (17 results)

All 2018 2017 2016 2015 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 6 results) Remarks (1 results)

  • [Journal Article] Sensitivity enhancement of chemically amplified EUV resists by adding acid-generating promoters2017

    • Author(s)
      Shinya Fujii, Kazumasa Okamoto, Hiroki Yamamoto, Takahiro Kozawa, Toshiro Itani
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 6S1 Pages: 06GD01-06GD01

    • DOI

      10.7567/jjap.56.06gd01

    • NAID

      210000147863

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dynamics of Radical Ions of Hydroxyhexafluoroisopropyl-Substituted Benzenes2017

    • Author(s)
      K. Okamoto, N. Nomura, R. Fujiyoshi, K. Umegaki, H. Yamamoto, K. Kobayashi, and T. Kozawa
    • Journal Title

      J. Phys. Chem. A

      Volume: 121 Issue: 49 Pages: 9458-9465

    • DOI

      10.1021/acs.jpca.7b09842

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of radical cations of poly(4-hydroxystyrene) in the presence and absence of triphenylsulfonium triflate as determined by pulse radiolysis of its highly concentrated solution2016

    • Author(s)
      K. Okamoto, T. Ishida, H. Yamamoto, T. Kozawa, R. Fujiyoshi, and K. Umegaki
    • Journal Title

      Chem. Phys. Lett.

      Volume: 657 Pages: 44-48

    • DOI

      10.1016/j.cplett.2016.05.058

    • NAID

      120006488393

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dynamics of radical ions of fluorinated polymer for Extreme Ultraviolet (EUV) lithography2015

    • Author(s)
      N. Nomura, K. Okamoto, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Journal Title

      Proc. SPIE

      Volume: 9658 Pages: 96581C-96581C

    • DOI

      10.1117/12.2193060

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] パルスラジオリシスによるフェニルスルホン化合物の放射線化学反応2018

    • Author(s)
      岡本一将, 河合俊平, 山本洋揮, 古澤孝弘
    • Organizer
      日本原子力学会2018年春の大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 化学増幅型レジストへのスルホン化合物の添加効果2017

    • Author(s)
      岡本 一将, 藤井 槙哉, 山本 洋揮, 古澤 孝弘, 井谷 俊郎
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] ポリスチレンのフェニルトリメトキシシラン溶液のパルスラジオリシス2017

    • Author(s)
      堀 成生, 岡本一将, 山本洋揮, 古澤孝弘, 藤吉亮子, 梅垣菊男
    • Organizer
      第60回放射線化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Sensitivity enhancement of chemically amplified EUV by adding acid generation promoters2016

    • Author(s)
      Shinya Fujii, Kazumasa Okamoto, Hiroki Yamamoto, Takahiro Kozawa, Toshiro Itani
    • Organizer
      29th International Microprocesses and Nanotechnology Conference (MNC2016)
    • Place of Presentation
      ANA Crowne Plaza Kyoto (京都府・京都市)
    • Year and Date
      2016-11-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ヒドロキシヘキサフルオロイソプロピルベンゼンのラジカルイオンのダ イナミクス2016

    • Author(s)
      岡本一将、野村直矢、山本洋揮、藤吉亮子、梅垣菊男
    • Organizer
      第59回放射線化学討論会
    • Place of Presentation
      量子科学技術研究開発機構 高崎量子応用研究所(群馬県・高崎市)
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] 添加剤を用いた酸生成促進によるEUV 用化学増幅型レジストの感度向上2016

    • Author(s)
      藤井槙哉、岡本一将、山本洋揮、古澤孝弘、井谷俊郎
    • Organizer
      第59回放射線化学討論会
    • Place of Presentation
      量子科学技術研究開発機構 高崎量子応用研究所(群馬県・高崎市)
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
  • [Presentation] Radiation-induced reaction of fluorinated polymers and related compounds for extreme-ultraviolet lithography2015

    • Author(s)
      N. Nomura, K. Okamoto, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawii Convention Center(Honolulu, Hawaii, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Pulse radiolysis study of resist polymers with and without photoacid generator2015

    • Author(s)
      K. Okamoto, T. Ishida, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawii Convention Center(Honolulu, Hawaii, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Radiation chemistry of fluorinated polymers for Extreme-ultraviolet resist2015

    • Author(s)
      N. Nomura, K. Okamoto, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Organizer
      28th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      富山国際会議場(富山県富山市)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Pulse radiolysis in concentrated poly(4-hydroxystyrene) solution: Acid generation dynamics in EUV and electron-beam chemically amplified resist2015

    • Author(s)
      K. Okamoto, T. Ishida, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Organizer
      28th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      富山国際会議場(富山県富山市)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] パルスラジオリシス法によるフッ素樹脂の放射線化学反応の解明2015

    • Author(s)
      野村直矢、岡本一将、藤吉亮子、梅垣菊男、山本洋揮、古澤孝弘
    • Organizer
      日本原子力学会2015年秋の大会
    • Place of Presentation
      静岡大学静岡キャンパス(静岡県静岡市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] Dynamics of radical ions of fluorinated polymer for Extreme Ultraviolet (EUV) lithography2015

    • Author(s)
      N. Nomura, K. Okamoto, H. Yamamoto, T. Kozawa, R. Fujiyoshi, K. Umegaki
    • Organizer
      Photomask Japan 2015
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2015-04-20
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 量子ビーム応用医工学研究室ホームページ

    • URL

      http://labs.eng.hokudai.ac.jp/labo/qsre/QSciEngjp/

    • Related Report
      2016 Research-status Report 2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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