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Development of high performance porous solid supported chemical heat storage material and chemical heat pump using that material

Research Project

Project/Area Number 15K06692
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionAichi Institute of Technology

Principal Investigator

WATANABE Fjio  愛知工業大学, 総合技術研究所, 教授 (70109312)

Co-Investigator(Kenkyū-buntansha) 架谷 昌信  愛知工業大学, 工学部, 教授 (50021788)
小林 敬幸  名古屋大学, 工学研究科, 准教授 (90242883)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords化学蓄熱 / 化学ヒートポンプ / 多孔体担持型蓄熱材 / 酸化カルシウム / カーボン多孔体 / 金属多孔体 / 多孔体 / 蓄熱 / 回転型蓄熱器
Outline of Final Research Achievements

The most important issues in the development of chemical heat pumps using a gas-solid chemical reaction are: reduction in reaction rate due to repeated dehydration reaction and hydration reaction, and the increase in heat transfer resistance due to changes in volume. In this research, two types of porous solid supported chemical heat storage materials are proposed: (1) a carbonaceous porous solid supported CaO, and (2) a porous metal supported Ca(OH)2. The effectiveness of these heat storage materials was evaluated. The following findings were obtained as a result.
Based on (1), it was shown that: with a sample having CaO content of 50 wt% or less, volume expansion due to hydration occurs only in the pores of the porous solid; the hydration reaction ratio is 85% or higher. Based on (2), the carrier ratio for Ca(OH)2 of 40 vol% was obtained. In addition, it was found that for the 10 repeated hydration/dehydration reactions, the hydration reaction ratio was about 80%.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (3 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (2 results)

  • [Journal Article] Long-Term Durability and Reactivation of Thermochemical Heat Storage Driven by the CaO/Ca (OH) 2 Reversible Reaction2017

    • Author(s)
      K Kuwata, T Esaki, N Kobayashi, at al.
    • Journal Title

      JURNAL OF MATERIALS SCIENCE AND cHEMICAL ENGINEERING

      Volume: 5 Pages: 23-32

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 化学ヒートポンプ用回転型蓄熱器の伝熱性評価2016

    • Author(s)
      渡辺藤雄,伊藤聖也,市木大博,架谷昌信,小林敬幸
    • Organizer
      2016年度日本冷凍空調学会年次大会
    • Place of Presentation
      兵庫県神戸市
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] CaO/H2O/Ca(OH)2化学ヒートポンプを対象とする回転型蓄熱器の熱出力特性評価2015

    • Author(s)
      渡辺藤雄,塩見仁郎,鈴木智久,坪内修,架谷昌信
    • Organizer
      化学工学第47回秋季大会
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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