| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
In this research, we achieved the design of novel highly active catalysts based on detailed mechanistic studies and their application to the synthesis of asymmetric tetrasubstituted carbon stereocenters, resulted in the construction of a new chemical library of amino acid derivatives with tetrasubstituted carbon stereocenters.
In addition, we succeeded in developing environmentally friendly new catalytic asymmetric tetrasubstituted carbon synthesis using unprotected imines and paved the new way for the synthesis of unprotected amines.
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