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Use of gas chromatography-mass spectrometry-olfactometry to identify and characterize compounds responsible for off-flavor of drinking water

Research Project

Project/Area Number 15K12250
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental risk control and evaluation
Research InstitutionHokkaido University

Principal Investigator

Matsushita Taku  北海道大学, 工学研究院, 准教授 (30283401)

Co-Investigator(Kenkyū-buntansha) 白崎 伸隆  北海道大学, 工学研究院, 助教 (60604692)
Research Collaborator SAKUMA Miki  
HATASE Taiki  
IKEKAME Shohei  
TAZAWA Shiori  
ISAKA Masahito  
AKI Tomoko  
MATSUI Yoshihiko  
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords環境保全学 / 環境リスク制御・評価 / カルキ臭
Outline of Final Research Achievements

The off-flavor of drinking water is caused by transformation products (TPs) generated from organic compounds such as amino acids during the chlorination process. However, the contributions of many of these TPs to the off-flavor have not been quantitatively investigated, mainly because sensory evaluations using conventional flask tests could not be conducted due to the lack of appropriate chemical standards. In the present study, we used gas chromatography GC-MS-O analysis to identify the cause of the off-flavor, and proposed a sensory evaluation procedure for quantitatively determining the contributions of TPs to this off-flavor, regardless of the availability of the TPs. As a case study, we used a solution containing phenylalanine that had been chlorinated for our evaluations. The GC-MS-O analysis revealed that two TPs, N-chlorophenylacetaldimine and 2-chloro-2-phenylacetaldehyde, for which chemical standards are not commercially available, were responsible for the off-flavor.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (7 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Trichloramine removal with activated carbon is governed by two reductive reactions: a theoretical approach with diffusion-reaction models2017

    • Author(s)
      Matsushita, T., Matsui, Y., Ikekame, S., Sakuma M. and Shirasaki, N.
    • Journal Title

      Environmental Science & Technology

      Volume: 印刷中 Issue: 8 Pages: 4541-4548

    • DOI

      10.1021/acs.est.6b05461

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 微粉炭による浄水プロセスでのかび臭原因物質とカルキ臭原因物質の除去2017

    • Author(s)
      松井佳彦, 松下拓
    • Journal Title

      水環境学会誌

      Volume: 40(2) Pages: 50-53

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Mechanisms of trichloramine removal with activated carbon: Stoichiometric analysis with isotopically labelled trichloramine and theoretical analysis with a diffusion-reaction model2015

    • Author(s)
      Sakuma, M., *Matsushita, T., Matsui, Y., Aki, A., Isaka, M. and Shirasaki, N.
    • Journal Title

      Water Research

      Volume: 68 Pages: 839-848

    • DOI

      10.1016/j.watres.2014.10.051

    • NAID

      120005553678

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 浄水カルキ臭の制御に向けたGC-Olfactometryによる臭気評価法の確立:フェニルアラニン塩素処理由来の臭気を用いた検討2017

    • Author(s)
      畑瀬大樹, 佐久間美紀, 松下拓, 田澤しおり, 松井佳彦, 白崎伸隆
    • Organizer
      第51回日本水環境学会年会
    • Place of Presentation
      熊本大学(熊本市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Investigating mechanism underlying removal of trichloramine with super-powdered activated carbon2016

    • Author(s)
      Sakuma, M., Matsushita, T., Matsui, Y., Aki, T., Isaka, M., Hatase, T. and Shirasaki, N.
    • Organizer
      IWA World Water Congress 2016
    • Place of Presentation
      Brisbane (Australia)
    • Year and Date
      2016-10-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] どのような活性炭がトリクロラミン分解に有効か?: 拡散-反応モデルによる分解の数値化と活性炭の物理化学的特性との間の相関分析2016

    • Author(s)
      池亀翔平, 松井佳彦, 松下拓, 白崎伸隆
    • Organizer
      第50回日本水環境学会年会
    • Place of Presentation
      アスティとくしま(徳島県徳島市)
    • Year and Date
      2016-03-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 浄水カルキ臭の全体像の把握と制御2015

    • Author(s)
      松下拓, 松井佳彦, 白崎伸隆, 佐久間美紀, 安藝朋子, 井阪雅仁, 田澤しおり, 池亀翔平, 畑瀬大樹
    • Organizer
      第23回衛生工学シンポジウム
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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