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Dispersion Control of Organic Molecules in Extremely Limited Small Space: Cluster to Nanocrystals

Research Project

Project/Area Number 15K13262
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanostructural chemistry
Research InstitutionTohoku University

Principal Investigator

OIKAWA Hidetoshi  東北大学, 多元物質科学研究所, 教授 (60134061)

Co-Investigator(Kenkyū-buntansha) 小野寺 恒信  東北大学, 多元物質科学研究所, 助教 (10533466)
Co-Investigator(Renkei-kenkyūsha) MITSUI TADASHI  物質・材料研究機構, 先端的共通技術部門, 主任研究員 (90343863)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsナノ材料 / 相分離・結晶化過程 / クラスター・ナノ粒子 / 乳化重合 / 高分子微粒子 / ペリレン / 有機ナノ結晶 / 蛍光発光 / ポリスチレン
Outline of Final Research Achievements

Aiming at investigating the structural correlations for physical properties of organic molecular clusters, some dispersion states, for example, molecule state, cluster, and organic nanocrystals, could be experimentally controlled suitably by finely optimizing the rates of phase separation, segregation, and crystallization of organic molecules embedded polymer microspheres that is a so-called extremely limited small space. “Phase separation in polymerization field and subsequent nanocrystallization process” has been developed successfully in perylene and polystyrene (PS) system. Actually, the state of perylene dispersed in polymer microspheres was analyzed and evaluated by the measurements with the conventional fluorescence spectroscopy, near-field scanning optical microscopy, and positron annihilation method. As a result, the intermediate dispersion state would be strongly suggested for the first time in the case of perylene embedded in PS microshperes.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (9 results)

All 2017 2016 2015 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Dispersion Control of Perylene Fluorophores in a Polymer Microsphere2016

    • Author(s)
      K. Yoshioka, T. Onodera, H. Kasai, S. Okada, H. Oikawa
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 629 Issue: 1 Pages: 239-242

    • DOI

      10.1080/15421406.2015.1096445

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] ホリマーマトリクス中における発光性色素の挙動2017

    • Author(s)
      吉岡甲子郎、小野寺恒信、笠井 均、岡田修司、及川 英俊
    • Organizer
      東北大学大学院理学研究科・生命科学研究科 合同シンポジウム2017
    • Place of Presentation
      東北大学(青葉山北キャンパス)(仙台市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fluorescent Properties of Perylene Dispersed in Polymer Microsphere2016

    • Author(s)
      Koshiro Yoshioka, Tsunenobu Onodera, Tadashi Mitsui, Hitoshi Kasai, Shuji Okada, Hidetoshi Oikawa
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics (KJF-ICOMEP 2016)
    • Place of Presentation
      アクロス福岡(福岡市)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fluorescent Properties of Perylene Embedded in Poly(St-co-MMA) Microspheres: Approach to “Intermediate state”2016

    • Author(s)
      Koshiro Yoshioka, Tsunenobu Onodera, Tadashi Mitsui, Hitoshi Kasai, Hidetoshi Oikawa
    • Organizer
      The 7th Tohoku University’s Chemistry Summer School 2016
    • Place of Presentation
      東北大学(青葉山北キャンパス)(仙台市)
    • Year and Date
      2016-08-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] コポリマー微小球に内包されたペリレンの発光特性2016

    • Author(s)
      吉岡甲子郎、小野寺恒信、笠井 均、岡田修司、及川 英俊
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Dispersion Control of Fluorescent Molecules in a Polymer Microsphere Matrix2015

    • Author(s)
      Koshiro Yoshioka, Tsunenobu Onodera, Hitoshi Kasai, Shuji Okada, and Hidetoshi Oikawa
    • Organizer
      IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME2015)
    • Place of Presentation
      PACIFIC YOKOHAMA (Yokohama City)
    • Year and Date
      2015-10-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 蛍光分子を内包したポリマーマイクロスフィアの光学特性評価2015

    • Author(s)
      吉岡甲子郎、小野寺恒信、笠井 均、岡田修司、及川英俊
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 高分子マトリクス中における蛍光分子の分散状態の解析2015

    • Author(s)
      吉岡甲子郎、小野寺恒信、笠井 均、岡田修司、及川英俊
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Remarks] 及川研究室ホームページ

    • URL

      http://www2.tagen.tohoku.ac.jp/lab/oikawa/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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