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Development of single-molecular light-emitting transistor

Research Project

Project/Area Number 15K13293
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionMeiji University

Principal Investigator

Noguchi Yutaka  明治大学, 理工学部, 専任准教授 (20399538)

Co-Investigator(Renkei-kenkyūsha) MAJIMA Yutaka  東京工業大学, 科学技術創成院, 教授 (40293071)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords単一分子発光 / ナノギャップ電極 / 電気化学発光セル / 変位電流評価法 / 発光トランジスタ / 発光性ポリマー
Outline of Final Research Achievements

We proposed a new type of single-molecular light-emitting device fabricated in a nanogap electrode, where the light emission is obtained through an energy transfer from host to guest molecules. The efficient ambipolar charge injection from similar electrodes (gold) was realized by using a blend film of a light-emitting semiconducting polymer and ionic liquid, that is, a light-emitting electrochemical cell (LEC). In addition, due to the appropriate surface treatment for the SiO2 substrate, the active layer was successfully formed only on the electrodes and nanogap. Therefore the light emission is expected to occur at the nanogap. Finally, a current driven light emission from the nanogap LEC was successfully obtained.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (30 results)

All 2018 2017 2016 2015 Other

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (19 results) (of which Int'l Joint Research: 9 results,  Invited: 5 results) Book (1 results) Remarks (4 results)

  • [Journal Article] Molecular Floating-gate Single-electron Transistor2017

    • Author(s)
      M. Yamamoto, Y. Azyma, M. Sakamoto, T. Teranishi, H. Ishii, Y. Majima, Y. Noguchi
    • Journal Title

      Sci. Rep.

      Volume: in press Issue: 1 Pages: 1589-1589

    • DOI

      10.1038/s41598-017-01578-7

    • NAID

      120006366775

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Observation of charge transport through CdSe/ZnS quantum dots in a single-electron transistor structure2016

    • Author(s)
      Masanori Kobo, Makoto Yamamoto, Hisao Ishii, Yutaka Noguchi
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 16

    • DOI

      10.1063/1.4966175

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Significant relaxation of residual negative carrier in polar Alq3 film directly detected by high-sensitivity photoemission2016

    • Author(s)
      Hiroumi Kinjo, Hyunsoo Lim, Tomoya Sato, Yutaka Noguchi, Yasuo Nakayama, and Hisao Ishii
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 2 Pages: 021601-021601

    • DOI

      10.7567/apex.9.021601

    • NAID

      210000137771

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Observation of ambipolar switching in a silver nanoparticle single-electron transistor with multiple molecular floating gates2016

    • Author(s)
      Makoto Yamamoto, Shuhei Shinohara, Kaoru Tamada, Hisao Ishii, and Yutaka Noguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 3S2 Pages: 03DC02-03DC02

    • DOI

      10.7567/jjap.55.03dc02

    • NAID

      210000146177

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Analyzing Degradation Effects of Organic Light-Emitting Diodes via Transient Optical and Electrical Measurements2015

    • Author(s)
      Tobias D. Schmidt, Lars Jaeger, Yutaka Noguchi, Hisao Ishii, and Wolfgang Bruetting
    • Journal Title

      Journal of Applied Physics

      Volume: 117 Issue: 21 Pages: 215502-215502

    • DOI

      10.1063/1.4921829

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of Interface Electronic Structures on Transition Voltage Spectroscopy of Alkanethiol Molecular Junctions2015

    • Author(s)
      Daisuke Nose, Kouki Dote, Tomoya Sato, Makoto Yamamoto, Hisao Ishii, Yutaka Noguchi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 未定 Issue: 22 Pages: 12765-12771

    • DOI

      10.1021/acs.jpcc.5b03296

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 有機ELデバイスの動作機構解析2018

    • Author(s)
      野口 裕
    • Organizer
      応用物理学会関西支部セミナー「光機能の新展開~有機ELデバイスの新展開~」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 変位電流と発光強度の同時測定による電気化学発光セルの過渡特性解析2017

    • Author(s)
      野口 裕、日下田 哲也、米川 文広
    • Organizer
      第64応用物理学会学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] イオン液体の混合比に依存した電気化学発光セルの動作特性と局所的膜構造2017

    • Author(s)
      日下田 哲也、加藤 勇一郎、米川 文広、野口 裕
    • Organizer
      有機EL討論会 第25回例会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 変位電流測定による有機発光素子の動作機構解析2017

    • Author(s)
      野口 裕、石井 久夫
    • Organizer
      学振第142委員会 第76回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Single-molecules as a floating gate of metal nanoparticle single-electron transistors2017

    • Author(s)
      Yutaka Noguchi, Makoto Yamamoto, Yasuo Azuma, Hisao Ishii, Yutaka Majima
    • Organizer
      14th European Conference on Molecular Electronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoresponsive charge transport through CdSe/ZnS quantum dots in nanogap electrodes2017

    • Author(s)
      Ryuji Yamashita, Makoto Yamamoto, Yutaka Noguchi
    • Organizer
      9th International Conference on Molecular Electronics and Bioelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transient properties of light-emitting electrochemical cells studied by displacement current measurement2017

    • Author(s)
      Yutaka Noguchi, Tetsuya Higeta, Fumihiro Yonekawa
    • Organizer
      9th International Conference on Molecular Electronics and Bioelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Displacement current measurement for analyzing transient behaviors of light-emitting electrochemical cells2017

    • Author(s)
      Yutaka Noguchi
    • Organizer
      2017 KPS spring meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 変位電流評価法による電気化学発光セルの動作機構解析2016

    • Author(s)
      野口 裕、日下田 哲也
    • Organizer
      有機EL討論会 第23回例会
    • Place of Presentation
      富山市民プラザ(富山)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 変位電流測定の基礎と有機発光素子の動作機構解析2016

    • Author(s)
      野口 裕、石井 久夫
    • Organizer
      高分子学会 有機エレクトロニクス研究会
    • Place of Presentation
      東京工業大学田町キャンパスCIC国際会議室(東京)
    • Year and Date
      2016-10-13
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Asymmetric formation of p-i-n junction in a light-emitting electrochemical cell studied by displacement current measurement2016

    • Author(s)
      Yutaka Noguchi, Tetsuya Higeta
    • Organizer
      8th International Conference on Molecular Electronics (ElecMol2016)
    • Place of Presentation
      Paris, France
    • Year and Date
      2016-08-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 変位電流評価法を用いた電気化学発光セルの動作機構解析2016

    • Author(s)
      野口 裕、佐野早紀
    • Organizer
      第63回応用物理学会学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 銅フタロシアニン誘導体を添加した金ナノ粒子単電子トランジスタにおける光応答解析2016

    • Author(s)
      山本 真人、東 康男、真島 豊、坂本 雅典、寺西 利治、石井 久夫、野口 裕
    • Organizer
      第63回応用物理学会学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 積層型有機薄膜素子における電荷注入・蓄積および劣化特性2015

    • Author(s)
      野口 裕
    • Organizer
      ナノプローブテクノロジー第167委員会 第80回研究会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-10-20
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 有機蒸着膜の配向分極と有機EL素子の界面特性2015

    • Author(s)
      野口 裕、石井久夫
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Contribution of interface electronic structures to transition voltage spectroscopy of alkanethiol molecular junctions2015

    • Author(s)
      Yutaka Noguchi, Daisuke Nose, Koki Dote, Tomoya Sato, Makoto Yamamoto, Hisao Ishii
    • Organizer
      European Conference on Molecular Electronics (ECME2015)
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Observation of Photo-Induced Multiple-States in Copper Phthalocyanine Derivative Doped Silver Nanoparticles Single-Electron Transisor2015

    • Author(s)
      Makoto Yamamoto, Shuhei Shinohara, Kaoru Tamada, Rieko Ueda, Toshifumi Terui, Hisao Ishii, Yutaka Noguchi
    • Organizer
      European Conference on Molecular Electronics (ECME2015)
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] The Roles of Interface Charge in Organic Light-Emitting Diodes Doped by a Thermally Activated Delayed Fluorescence Emitter2015

    • Author(s)
      Yutaka Noguchi, Hyung Jun Kim, Ryuta Ishino, Kenichi Goushi, Chihaya Adachi, Yasuo Nakayama, Hisao Ishii
    • Organizer
      Eighth International Conference on Molecular Electronics and Bioelectronics (M&BE8)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-06-24
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Observation of Molecular Floating Gate Effects in Silver Nanoparticles Single-Electron Transistors with Copper Phthalocyanine Derivatice2015

    • Author(s)
      Makoto Yamamoto, Shuhei Shinohara, Kaoru Tamada, Rieko Ueda, Toshifumi Terui, Hisao Ishii, Yutaka Noguchi
    • Organizer
      Eighth International Conference on Molecular Electronics and Bioelectronics (M&BE8)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-06-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] 先端 有機半導体デバイスー基礎からデバイス物性までー2015

    • Author(s)
      野口 裕、中山泰生、石井久夫
    • Total Pages
      526
    • Publisher
      オーム社
    • Related Report
      2015 Research-status Report
  • [Remarks] 有機分子エレクトロニクス研究室

    • URL

      http://www.isc.meiji.ac.jp/~molele/paper.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 明治大学 教員データベース

    • URL

      http://gyoseki1.mind.meiji.ac.jp/mjuhp/KgApp?kojinId=140070

    • Related Report
      2017 Annual Research Report
  • [Remarks] 有機分子エレクトロニクス研究室

    • URL

      http://www.isc.meiji.ac.jp/~molele/index.html

    • Related Report
      2016 Research-status Report
  • [Remarks] 明治大学 教員データベース

    • URL

      http://gyoseki1.mind.meiji.ac.jp/mjuhp/KgApp?kojinId=140070

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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