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Composition patterning and functionalization on glass surface using electrical nanoimprint

Research Project

Project/Area Number 15K13297
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionHokkaido University

Principal Investigator

Nishii Junji  北海道大学, 電子科学研究所, 教授 (60357697)

Co-Investigator(Kenkyū-buntansha) 海住 英生  北海道大学, 電子科学研究所, 准教授 (70396323)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsナノインプリント / 微細周期構造 / コロナ放電 / ガラス / アルカリイオン / 酸化物ガラス / 微細構造 / 応力腐食
Outline of Final Research Achievements

One-dimensional structure of 700-nm period were imprinted on a sodaaluminosilicate
glass using a platinum-coated silica mold with application of DC voltage. The migration of network modifier cations below the anode side surface to the cathode side is a necessary condition for grating formation. Glass surfaces were chemically etched using a 55% KOH solution at 70 degC. The top area of the NAS grating ridge, where the non-contacted area of the mold is located, was etched preferentially. Finally, the reverse concavo-convex grating appeared by etching. Localized stress corrosion in the grating ridge is expected to be an origin of the anisotropic etching and the grating pattern formation. This study was published in OPTICAL MATERIALS EXPRESS (doi.org/10.1364/OME.7.001438).

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2017 2016 2015

All Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Int'l Joint Research: 7 results,  Invited: 7 results)

  • [Journal Article] Nano-imprinting of surface relief gratings on soda-aluminosilicate and soda-lime silicate glasses2017

    • Author(s)
      N. Kubo, N. Ikutame, M. Takei, B. Weibai, S. Ikeda, K. Yamamoto, K. Uraji, T. Misawa, M. Fujioka, H. Kaiju, G. Zhao, J. Nishii
    • Journal Title

      Optical Materials Express

      Volume: 7 Issue: 5 Pages: 1438-1445

    • DOI

      10.1364/ome.7.001438

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Migration behavior of alkali and alkaline-earth cations in soda-lime silicate glass surface by electrical nanoimprint2016

    • Author(s)
      S. Ikeda, K. Uraji, T. Suzuki, K. Yamamoto and J. Nishii
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 453 Pages: 103-107

    • DOI

      10.1016/j.jnoncrysol.2016.09.030

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Migration behavior of network-modifier cations at glass surface during electrical poling2016

    • Author(s)
      T. Suzuki, J. Anzai, Y. Takimoto, K. Uraji, K. Yamamoto and J. Nishii
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 452 Pages: 125-129

    • DOI

      10.1016/j.jnoncrysol.2016.08.037

    • NAID

      40021349381

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Deposition of SiO2 on Ion Confuctive Area of Soda-lime Glass Surface2016

    • Author(s)
      D. Sakai, K. Harada, Y. Hara, H. Ikeda, S. Funatsu, K. Uraji, T. Suzuki, Y. Yamamoto, K. Yamamoto, N. Ikutame, K. Kawaguchi, H. Kaiju and J. Nishii
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 1-7

    • DOI

      10.1038/srep27767

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fluorescence microscopy imaging of cells with a plasmonic dish integrally molded2016

    • Author(s)
      K. Tawa, C. Sasakawa, T. Fujita, K. Kiyosue, C. Hosokawa, J. Nishii, M. Oike and N. Kakinuma
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 3S2 Pages: 03DF12-03DF12

    • DOI

      10.7567/jjap.55.03df12

    • NAID

      210000146215

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phase separation and crystallization in sodium lanthanum phosphate glasses induced by electrochemical substitution of sodium ions with protons2015

    • Author(s)
      K. Kawaguchi, T. Yamaguchi, T. Omata, T. Yamashita, H. Kawazoe and J. Nishii
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 17 Issue: 35 Pages: 22855-22861

    • DOI

      10.1039/c5cp04132e

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improving thermal stability and its effects on proton mobility in proton-conducting phosphate glasses prepared by the electrochemical substitution of sodium ions with protons2015

    • Author(s)
      T. Yamaguchi, T. Ishiyama, K. Sakuragi, J. Nishii, T. Yamashita, H. Kawazoe and T. Omata
    • Journal Title

      Solid State Ionics

      Volume: 275 Pages: 62-65

    • DOI

      10.1016/j.ssi.2015.03.003

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural change of NaO1/2-WO3-NbO5/2-LaO3/2-PO5/2 glass induced by electrochemical substitution of sodium ions with protons2015

    • Author(s)
      T. Ishiyama, T. Yamaguchi, J. Nishii, T. Yamashita, H. Kawazoe, N. Kuwata, J. Kawamura and T. Omata
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Issue: 20 Pages: 13640-13646

    • DOI

      10.1039/c4cp05999a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Fabrication of Microstructure on Soda-lime Silicate Glass Using Corona Discharge2016

    • Author(s)
      D. Sakai, M. Abe, K. Harada, T. Omatsu, I. Yoshida, T. Nishiura, T. Takemori, J. Nishii and H. Shibata
    • Organizer
      The Sixth Japan-Korea Workshop on Digital Holography and Information Photonics
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of a New NASICON-structured KxNa3-x-yHyV2(PO4)3 Using a Novel Ion Substitution Method2016

    • Author(s)
      N. Kubo, W. Chuanbao, M. Fujioka, H. Kaiju and J. Nishii
    • Organizer
      The 17th RIES-Hokudai International Symposium
    • Place of Presentation
      シャトレーゼガトーキングダムサッポロ(北海道札幌市)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical Nanoimprint2016

    • Author(s)
      J. Nishii
    • Organizer
      The 33rd International Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Daejeon(Korea)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Behavior of alkali and alkaline-earth ions silicate glasses under DC voltage application2016

    • Author(s)
      J. Nishii
    • Organizer
      CerSJ-GOMD Joint Symposium on Glass Science and Technologies co-located with The 57th Meeting on Glass and Photonic Materials & The 12th Symposium of Glass Industry Conferences of Japan
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電圧印加ガラスインプリントによる特異な微細構造形成2016

    • Author(s)
      久保 直紀、三澤 貴浩、藤岡 正弥、海住 英生、西井 準治
    • Organizer
      平成28年度日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrical Nanoimprint on Soda-lime Silicate Glass2016

    • Author(s)
      J. Nishii, T. Misawa, M. Fujioka and H. Kaiju
    • Organizer
      The 7th Japan-China-Korea Joint Conference on MEMS/NEMS 2016
    • Place of Presentation
      札幌市教育文化会館(北海道札幌市)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fine pattern formation on silicate glasses under DC voltage application2016

    • Author(s)
      J. Nishii, T. Misawa, M. Takei, S. Ikeda, T. Suzuki, K. Uraji and K. Yamamoto
    • Organizer
      International Congress on Glass
    • Place of Presentation
      Shanghai(China)
    • Year and Date
      2016-04-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrical imprint for fine patterning of silicate glasses2016

    • Author(s)
      J. Nishii
    • Organizer
      The 3rd Glass Summit and Atomistic Simulations Workshop
    • Place of Presentation
      Wuhan(China)
    • Year and Date
      2016-04-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アルカリ-プロトン置換したリン酸塩ガラスの伝導特性と熱的特性2016

    • Author(s)
      木下 拓也、宮崎 篤、藤岡 正弥、海住 英生、西井 準治、山口 拓哉、小俣 孝久
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学(東京都 新宿区)
    • Year and Date
      2016-03-16
    • Related Report
      2015 Research-status Report
  • [Presentation] ガラスナノインプリント技術(微細化の限界)2016

    • Author(s)
      西井 準治
    • Organizer
      2016年第1回極限ナノ造形・構造物性研究会 講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都 目黒区、東京都)
    • Year and Date
      2016-01-27
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ランタノイド含有リン酸塩ガラスのアルカリ-プロトン置換による中温域プロトン伝導体の作製2016

    • Author(s)
      宮崎 篤、山口 拓哉、海住 英生、小俣 孝久、西井 準治
    • Organizer
      化学系学協会北海道支部2016年冬季研究発表会
    • Place of Presentation
      北海道大学(北海道 札幌市)
    • Year and Date
      2016-01-20
    • Related Report
      2015 Research-status Report
  • [Presentation] Recent progress of intermediate temperature fuel cell2015

    • Author(s)
      J. NIshii
    • Organizer
      CUH/Hokkaido University Joint Workshop “Advanced Materials and Characterization”
    • Place of Presentation
      City University of Hong Kong(香港 九龍)
    • Year and Date
      2015-12-10
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Proton conductivity of alkali-proton substituted phosphate glass using corona discharge treatment2015

    • Author(s)
      J. Nishii
    • Organizer
      2015 RIES-CIS Symposium
    • Place of Presentation
      国立交通大学(台湾 新竹)
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
    • Invited

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Published: 2015-04-16   Modified: 2018-03-22  

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