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Exploration of ballistic conduction on the femtosecond scale in organic semiconductors

Research Project

Project/Area Number 15K13334
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Applied materials
Research InstitutionNagaoka University of Technology

Principal Investigator

Unuma Takeya  長岡技術科学大学, 工学研究科, 准教授 (20456693)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords共役ポリマー / テラヘルツ放射 / フェムト秒 / 超高速現象 / 高電場効果 / テラヘルツ
Outline of Final Research Achievements

We investigated the ultrafast motion of electrons and holes under bias electric field in conjugated polymers, which are major organic semiconductors, on the basis of emitted terahertz waveforms. When several conjugated polymer films with different main chains were excited by femtosecond laser pulses, the obtained terahertz signals were found to have the same order of magnitude and quite similar shapes. This means that the ultrafast motion is common to the conjugated polymers. A detailed analysis of terahertz waveforms revealed that the polarization relevant to terahertz emission is created by electron-hole pairs and quenched on the time scale of less than 350 fs.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (3 results)

All 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (1 results)

  • [Journal Article] Terahertz emission from biased conjugated polymers excited by femtosecond laser pulses2016

    • Author(s)
      Takeya Unuma, Naruki Yamada, Hideo Kishida
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 12 Pages: 121601-121601

    • DOI

      10.7567/apex.9.121601

    • NAID

      210000138113

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Segmentation of conducting domains in PEDOT:PSS films induced by an additive for conductivity enhancement2016

    • Author(s)
      Takeya Unuma, Muneki Yoshikawa, Arao Nakamura, Hideo Kishida
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 5 Pages: 051601-051601

    • DOI

      10.7567/apex.9.051601

    • NAID

      210000137874

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] テラヘルツ放射分光における因果律に基づく時間原点決定法の拡張2017

    • Author(s)
      南海舟,鵜沼毅也
    • Organizer
      平成29年度応用物理学会北陸・信越支部学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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