• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Synthesis of photocatalitic semiconducting composite powder

Research Project

Project/Area Number 15K13343
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Applied materials
Research InstitutionKanagawa Institute of Industrial Sclence and Technology

Principal Investigator

Akiyama Kensuke  地方独立行政法人神奈川県立産業技術総合研究所, 化学技術部, 主任研究員 (70426360)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords水素 / 新エネルギー / 結晶工学 / 水素生成 / 光触媒効果 / 鉄シリサイド
Outline of Final Research Achievements

Photocatalytic water-splitting is an ideal method for solar energy harvesting. Some photocatalysts that can split water under UV light have been discovered. However, development of visible-light sensitive photocatalysts is indispensable due to the effective utilization of incoming solar energy. On the other hand, semiconducting iron disilicide (β-FeSi2) has a band gap of approximately 0.80 eV and a very large optical absorption coefficient over 1E5 /cm at 1 eV.
In this report, we report on the novel fabrication method of β-FeSi2/3C-SiC composite powder by using metal-organic chemical vapor deposition (MOCVD) method which is general in semiconductor process technology. This β-FeSi2/SiC composite powder could evolve hydrogen (H2) from methyl-alcohol aqueous solution under irradiation of visible light with wavelengths of 420-650 nm.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (40 results)

All 2018 2017 2016 2015 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 7 results,  Acknowledgement Compliant: 7 results) Presentation (26 results) (of which Int'l Joint Research: 7 results) Remarks (2 results)

  • [Journal Article] Room temperature photoluminescence spectrum from β-FeSi2 films2018

    • Author(s)
      Kensuke Akiyama, Yoshihisa Matsumoto and Hiroshi Funakubo
    • Journal Title

      Proceedings of SPIE

      Volume: 10554

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of p- and n-type Conduction in Thermoelectric Non-doped Mg2Si Thin Films Prepared by Sputtering Method2018

    • Author(s)
      Kurokawa Mao、Shimizu Takao、Uehara Mutsuo、Katagiri Atsuo、Akiyama Kensuke、Matsushima Masaaki、Uchida Hiroshi、Kimura Yoshisato、Funakubo Hiroshi
    • Journal Title

      MRS Advances

      Volume: なし Issue: 24 Pages: 1-5

    • DOI

      10.1557/adv.2018.150

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111)-oriented epitaxial magnesium silicide (Mg2Si) films on (001) Al2O3 substrates by RF magnetron sputtering and their properties2018

    • Author(s)
      Atsuo Katagiri, Shota Ogawa, Mutsuo Uehara, P. S. Sankara Rama Krishnan, Mao Kurokawa, Masaaki Matsushima, Takao Shimizu, Kensuke Akiyama and Hiroshi Funakubo
    • Journal Title

      Journal of Material Science

      Volume: 53 Issue: 7 Pages: 5151-5158

    • DOI

      10.1007/s10853-017-1902-z

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-plane orientation and composition dependences of crystal structure and electrical properties of {100}-oriented Pb(Zr, Ti)O3 films grown on (100) Si substrates by metal organic chemical vapor deposition2017

    • Author(s)
      Shoji Okamoto、P. S. Sankara Rama Krishnan、Satoshi Okamoto、Shintaro Yokoyama、Kensuke Akiyama、Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 10S Pages: 10PF12-10PF12

    • DOI

      10.7567/jjap.56.10pf12

    • NAID

      210000148389

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of photoluminescence from iron disilicide on Si(111) substrates with Au layers by controlling microstructures2017

    • Author(s)
      Kensuke Akiyama, Yoshihisa Matsumoto and Hiroshi Funakubo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 6S2 Pages: 06HE03-06HE03

    • DOI

      10.7567/jjap.56.06he03

    • NAID

      210000147966

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis and Photocatalytic Properties of Iron Disilicide/SiC Composite Powder2017

    • Author(s)
      Kensuke Akiyama, Yuu Motoizumi, Tetsuya Okuda, Hiroshi Funakubo, Hiroshi Irie and Yoshihisa Matsumoto
    • Journal Title

      MRS Advances

      Volume: 2 Issue: 8 Pages: 471-476

    • DOI

      10.1557/adv.2017.221

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of microstructures on electrical conduction properties of β-FeSi2 epitaxial films2017

    • Author(s)
      Kensuke Akiyama, Teiko Kadowaki, Yasuo Hirabayashi and Hiroshi Funakubo
    • Journal Title

      Journal of Crystal Growth

      Volume: 印刷中 Pages: 744-748

    • DOI

      10.1016/j.jcrysgro.2016.12.032

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Preparation of preferentially (111)-oriented Mg2Si thin films on (001)Al2O3 and (100)CaF2 substrates and their thermoelectric properties2017

    • Author(s)
      Mao Kurokawa, Mutsuo Uehara, Daichi Ichinose, Takao Shimizu, Kensuke Akiyama, Masaaki Matsushima, Hiroshi Uchida, Yoshisato Kimura, and Hiroshi Funakubo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 5S1 Pages: 05DC02-05DC02

    • DOI

      10.7567/jjap.56.05dc02

    • NAID

      210000147762

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Preparation of Ca-Si Films on (001) Al2O3 Substrates by an RF Magnetron Sputtering Method and Their Electrical Properties2016

    • Author(s)
      Mutsuo Uehara, Kensuke Akiyama, Takao Shimizu, Masaaki Matsushima, Hiroshi Uchida, Yoshisato Kimura, and Hiroshi Funakubo
    • Journal Title

      J. Elector. Mater.

      Volume: - Issue: 6 Pages: 3121-3126

    • DOI

      10.1007/s11664-016-4404-x

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Epitaxial Growth and Photoluminescence Properties of β-FeSi2 Grains Using Liquid Phase Obtained by Au-Si Eutectic Reaction2016

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Journal Title

      Proceedings of International Society for Optics and Photonics

      Volume: 9768 Pages: 97681Q-97681Q

    • DOI

      10.1117/12.2212057

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Composition dependences of crystal structure and electrical properties of epitaxial Pb(Zr,Ti)O3 films grown on Si and SrTiO3 substrates2016

    • Author(s)
      Shoji Okamoto, Satoshi Okamoto, Shintaro Yokoyama, Kensuke Akiyama and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 55 Issue: 10S Pages: 10TA08-10TA08

    • DOI

      10.7567/jjap.55.10ta08

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Metal-organic chemical vapor deposition growth of β-FeSi2/Si composite powder via vapor-liquid-solid method and its photocatalytic properties2016

    • Author(s)
      Kensuke Akiyama, Yuu Motoizumi, Hiroshi Funakubo, Hiroshi Irie and Yoshihisa Matsumoto
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 6S2 Pages: 06HC02-06HC02

    • DOI

      10.7567/jjap.55.06hc02

    • NAID

      210000146711

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Room temperature photoluminescence spectrum from β-FeSi2 films2018

    • Author(s)
      Kensuke Akiyama, Yoshihisa Matsumoto and Hiroshi Funakubo
    • Organizer
      SPIE Phtonics West
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 窒素(N)ドーピングした鉄シリサイドのPL発光特性2018

    • Author(s)
      秋山賢輔, 高橋亮, 松本佳久, 舟窪浩
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] β-FeSi2薄膜のPL発光特性に及ぼす成長温度の影響2017

    • Author(s)
      秋山 賢輔,松本 佳久,舟窪 浩
    • Organizer
      第64回応用物理学会・春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] β-FeSi2 薄膜のPL発光特性に及ぼす成長温度の影響2017

    • Author(s)
      秋山 賢輔,松本佳久,舟窪浩
    • Organizer
      第64回応用物理学会 春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PL発光強度増大化へのSi(111)基板上β-FeSi2 成長の低温度化検討2017

    • Author(s)
      秋山 賢輔,松本佳久,舟窪浩
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] MOCVD法でSi基板上に作製した面内配向制御して作製したPZT薄膜における電気特性の組成依存性2017

    • Author(s)
      岡本庄司, 岡本 賢, 横山慎太郎, 秋山賢輔, 舟窪浩
    • Organizer
      第34回強誘電体応用会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of p-type and n-type conduction in thermoelectric Mg2Si thin films prepared by sputtering method2017

    • Author(s)
      Mao Kurokawa, Mutsuo Uehara, Daichi Ichinose, Takao Shimizu, Kensuke Akiyama, Masaaki Matsushima, Hiroshi Uchida, Yoshisato Kimura and Hiroshi Funakubo
    • Organizer
      MRS Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄シリサイド/炭化ケイ素複合構造の創生と光触媒特性2016

    • Author(s)
      秋山賢輔、高橋亮、本泉佑、奥田徹也、舟窪浩、入江寛、松本佳久
    • Organizer
      第23回光触媒シンポジウム
    • Place of Presentation
      東京理科大学・葛飾キャンパス
    • Year and Date
      2016-12-02
    • Related Report
      2016 Research-status Report
  • [Presentation] Synthesis and Photocatalytic Properties of Iron Disilicide/SiC Composite Powder2016

    • Author(s)
      Kensuke Akiyama, Yu Motoizumi, Tetsuya Okuda and Yoshihisa Matsumoto, Hiroshi Funakubo, Hiroshi Irie
    • Organizer
      Materials Research Society Symposium 2016-fall meeting
    • Place of Presentation
      ボストン、 ハイネス・コンベンション・センター
    • Year and Date
      2016-11-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] MOCVD growth of photoluminescent iron disilicide via vapor-liquid-solid method using Au-Si liquids phase2016

    • Author(s)
      Kensuke Akiyama, Yoshihisa Matsumoto and Hiroshi Funakubo
    • Organizer
      38th International Symposium on Dry Process
    • Place of Presentation
      北海道大学・会議場
    • Year and Date
      2016-11-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 熱処理がMg2Si薄膜の伝導型に与える影響2016

    • Author(s)
      黒川 満央、上原睦雄、清水荘雄、松島正明、木村 好里、秋山賢輔、内田 寛、舟窪浩
    • Organizer
      第77回応用物理学会・秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-15
    • Related Report
      2016 Research-status Report
  • [Presentation] β-FeSi2/SiC複合粒子の作製と光触媒効果による水からの水素生成2016

    • Author(s)
      秋山賢輔、本泉佑、奥田徹也、舟窪浩、入江寛、松本佳久
    • Organizer
      第77回応用物理学会・秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] β-FeSi2薄膜の低温でのフォトルミネッセンス発光2016

    • Author(s)
      秋山賢輔、松本佳久、舟窪浩
    • Organizer
      第77回応用物理学会・秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Epitaxial Growth of Iron Disilicide Thin Film on 4H-SiC2016

    • Author(s)
      Kensuke Akiyama, Teiko Kadowaki, Yasuo Hirabayashi Yoshihisa Matsumoto and Hiroshi Funakubo
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-08-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of Mg2Si Thin Films on Various Kinds of Substrates and their Thermoelectric Properties2016

    • Author(s)
      Mao Kurokawa, Mutsuo Uehara, Daichi Ichinose, Takao Shimizu, Kensuke Akiyama, Masaaki Matsushima, Hiroshi Uchida, Yoshisato Kimura, and Hiroshi Funakubo
    • Organizer
      Asia-Pacific Conference on Semiconducting Silicides and Related Materials 2016
    • Place of Presentation
      九州大学
    • Year and Date
      2016-07-16
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] β-FeSi2/SiC複合粒子の作製と光触媒効果による水からの水素生成2016

    • Author(s)
      秋山賢輔、本泉佑、高橋亮、舟窪浩、入江寛、松本佳久
    • Organizer
      第35回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京工業大学・蔵前会館くらまえホール
    • Year and Date
      2016-06-10
    • Related Report
      2016 Research-status Report
  • [Presentation] Si基板およびSrTiO3基板上エピタキシャルPZT薄膜の電気特性および結晶構造の組成依存性2016

    • Author(s)
      岡本庄司、秋山賢輔、岡本 賢、横山慎太郎、舟窪浩
    • Organizer
      強誘電体応用会議
    • Place of Presentation
      コープイン京都
    • Year and Date
      2016-05-26
    • Related Report
      2016 Research-status Report
  • [Presentation] β-FeSi2/SiC複合構造粒子の作製と光触媒効果による水素生成2016

    • Author(s)
      秋山賢輔, 本泉佑, 高橋亮, 舟窪浩, 入江寛, 松本佳久
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Si(001)上の3C-SiCエピ膜形成および積層欠陥生成過程の断面TEM解析2016

    • Author(s)
      山崎順, 石田篤志, 秋山賢輔, 平林康男
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Eu ドープNiO エピタキシャル薄膜の室温作製と特性評価2016

    • Author(s)
      高野詩織, 塩尻大士, 秋山賢輔, 金子智, 松田晃史, 吉本 護
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 鉄シリサイド薄膜のPL発光特性に及ぼすアニール処理の影響2016

    • Author(s)
      秋山賢輔, 松本佳久, 木口賢紀, 舟窪浩
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 収差補正電子顕微鏡を用いたSi(001)基板上エピタキシャル3C-SiC膜の形成過程と積層欠陥生成過程の研究2015

    • Author(s)
      山崎順, 玉置央和, 野村優貴, 石田篤志, 秋山賢輔, 平林康男
    • Organizer
      先進パワー半導体分科会
    • Place of Presentation
      大阪国際交流センター(大阪府)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Research-status Report
  • [Presentation] MOCVD growth of β-FeSi2 on Si via vapor-liquid-solid method using Au-Si liquids phase2015

    • Author(s)
      Kensuke Akiyama and Hiroshi Funakubo
    • Organizer
      37th International Symposium on Dry Process
    • Place of Presentation
      Awaji Yumebutai International Conference Center (Awaji Island, Japan)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリコン上への金属層導入による鉄シリサイド半導体の微細構造制御と光触媒特性2015

    • Author(s)
      秋山賢輔 舟窪浩
    • Organizer
      材料シンポジウムワークショップ
    • Place of Presentation
      京都テルサ(京都府)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 透過顕微鏡を用いたSi(001)上の3C-SiC膜形成及び積層欠陥生成過程の研究2015

    • Author(s)
      山崎順, 石田篤志, 秋山賢輔, 平林康男
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 窒素(N)ドーピングした鉄シリサイドのPL発光特性2015

    • Author(s)
      秋山賢輔, 高橋亮, 松本佳久, 舟窪浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Remarks] 神奈川県立産業技術総合研究所 論文情報

    • URL

      https://www.kanagawa-iri.jp/collaboration/info_gather/theses/kitc_paper_info/

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
  • [Remarks] 神奈川県産業技術センター

    • URL

      http://www.kanagawa-iri.jp/researchresults.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi