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Simulation of Plasma-Liquid-Interface Processing

Research Project

Project/Area Number 15K13391
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Plasma electronics
Research InstitutionOsaka City University

Principal Investigator

SHIRAFUJI Tatsuru  大阪市立大学, 大学院工学研究科, 教授 (10235757)

Research Collaborator GOTO Motonobu  名古屋大学, 大学院工学研究科, 教授 (80170471)
TACHIBANA Akira  大阪市立大学, 大学院工学研究科, 准教授 (80305614)
TANAKA Kenji  大阪市立大学, 大学院工学研究科, 助教 (20254386)
IMAI Shin'ichi  パナソニック株式会社, 全社CTO室技術戦略部, 主幹
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsプラズマ / 液体 / 計測 / モデル化 / シミュレーション / 色素分解 / 活性酸素窒素種 / ガス引き込み効果 / 液相診断 / 気相診断 / 気相反応 / 液相反応 / 時間分解発光分光 / 時間空間分解発光分光
Outline of Final Research Achievements

As an example of the plasma-liquid-interface processing, we have first focused on the degradation of methylene blue molecules in aqueous solution by plasma. We have clarified the degradation mechanism by mass spectrometric measurement of the species in liquid, and by modeling and simulating of the degradation process. In addition, we have measured reactive-oxygen-nitrogen species in the water treated with air plasma by using various detection methods, and made a model to explain the experimental results. We have clarified that hydroxyl radicals are not generated directly from plasma but indirectly from peroxynitrites in the case of long-term plasma processing of water. Furthermore, we have performed numerical simulations of an atmospheric pressure plasma jet involving oxygen in contact with a flowing medium. We have clarified that the gas-drag effect significantly reduces oxygen radical flux on the surface, and that it can be suppressed by replacing the ambient gas to an inert gas.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 10 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Reaction mechanisms of methylene-blue degradation in three-dimensionally integrated micro-solution plasma2017

    • Author(s)
      T. Shirafuji, Y. Ishida, A. Nomura, Y. Hayashi, and M. Goto
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 6S2 Pages: 06HF02

    • DOI

      10.7567/jjap.56.06hf02

    • NAID

      120006474982

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019924

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Acquisition of cell-adhesion capability of the surface of crosslinked albumin films irradiated with atmospheric-pressure plasma jets2016

    • Author(s)
      T. Shirafuji, M. Iwamura, R. Taga, Y. Kashiwagi, K. Nakajima, Y. Ogata, K. Tanaka, A. Tachibana, and T. Tanabe
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 7S2 Pages: 07LG03

    • DOI

      10.7567/jjap.55.07lg03

    • NAID

      120006367172

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019923

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] プラズマと液体との相互作用2016

    • Author(s)
      白藤 立, 竹内 希
    • Journal Title

      プラズマ・核融合学会誌

      Volume: 92 Pages: 693-699

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Matrix-assisted laser desorption ionization time-of-flight mass spectrometric analysis of degradation products after treatment of methylene blue aqueous solution with three-dimensinonally integrated microsolution plasma2016

    • Author(s)
      T. Shirafuji, A. Nomura, Y. Hayashi, K. Tanaka, and M. Goto
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 1S Pages: 01AH02-01AH02

    • DOI

      10.7567/jjap.55.01ah02

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 同軸型DBDによるプラズマ処理水中のペルオキシ亜硝酸の検出2017

    • Author(s)
      白藤 立, 西本 健太郎, 宮本 翔馬, 今井 伸一
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜,神奈川県横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Gas-gap dependence of the quenching rate of OH(A) observed in DBD on water2017

    • Author(s)
      S. Kito and T. Shirafuji
    • Organizer
      The 9th International Symposium on Advanced Plasma Science and its Application for Nitrides and Nanomaterials / The 10th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      中部大学,愛知県春日井市
    • Year and Date
      2017-03-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Time evolution of mass spectra of MB aqueous solution treated with three dimensionally integrated micro solution plasma2017

    • Author(s)
      Y. Ishida, T. Shirafuji, K. Tanaka, Y. Hayashi, and M. Goto
    • Organizer
      The 9th International Symposium on Advanced Plasma Science and its Application for Nitrides and Nanomaterials / The 10th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      中部大学,愛知県春日井市
    • Year and Date
      2017-03-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solution-plasma synthesis of a free-standing and Au-nanoparticle-containing polymer membrane on aqueous solution2017

    • Author(s)
      Y. Nakamura, T. Shirafuji, and T. Isshiki
    • Organizer
      The 9th International Symposium on Advanced Plasma Science and its Application for Nitrides and Nanomaterials / The 10th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      中部大学,愛知県春日井市
    • Year and Date
      2017-03-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristics of APPJ on a flowing medium2017

    • Author(s)
      T. Shirafuji
    • Organizer
      The 9th International Symposium on Advanced Plasma Science and its Application for Nitrides and Nanomaterials / The 10th International Conference on Plasma-Nano Technology & Science
    • Place of Presentation
      中部大学,愛知県春日井市
    • Year and Date
      2017-03-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気圧プラズマと液体の相互作用2017

    • Author(s)
      白藤 立
    • Organizer
      日本学術振興会プラズマ材料科学第153委員会 プラズマ材料科学スクール 大気圧プラズマの基礎:プラズマ生成,気相反応から表面相互作用まで
    • Place of Presentation
      弘済会館,東京都千代田区
    • Year and Date
      2017-02-23
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Diagnostics of air-plasma-treated water using fluorescent reagents2017

    • Author(s)
      K. Nishimoto, S. Imai, and T. Shirafuji
    • Organizer
      第34回プラズマプロセシング研究会/第29回プラズマ材料科学シンポジウム
    • Place of Presentation
      北海道大学,北海道札幌市
    • Year and Date
      2017-01-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effects of ambient gases on atomic oxygen flux from an atmospheric pressure plasma jet on a flowing medium2017

    • Author(s)
      T. Shirafuji
    • Organizer
      第34回プラズマプロセシング研究会/第29回プラズマ材料科学シンポジウム
    • Place of Presentation
      北海道大学,北海道札幌市
    • Year and Date
      2017-01-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of polymer thin films containing Au nanoparticles by plasma in contact with aqueous solution2016

    • Author(s)
      T. Shirafuji and Y. Nakamura
    • Organizer
      The 25th Annual Meeting of MRS-Japan 2015
    • Place of Presentation
      横浜開港記念館,神奈川県横浜市
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Reaction mechanisms of methylene-blue degradation in three-dimensionally integrated micro solution plasma2016

    • Author(s)
      T. Shirafuji, Y. Ishida, A. Nomura, Y. Hayashi, and M. Goto
    • Organizer
      The 38th International Symposium on Dry Process
    • Place of Presentation
      北海道大学,北海道札幌市
    • Year and Date
      2016-11-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] O2/N2大気圧プラズマジェットの数値シミュレーション2016

    • Author(s)
      白藤 立
    • Organizer
      電気学会プラズマ・パルスパワー・放電合同研究会
    • Place of Presentation
      佐賀大学,佐賀県佐賀市
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] Time- and space-resolved OES on plasma in contact with water2016

    • Author(s)
      T. Shirafuji, K. Obana, and S. Kito
    • Organizer
      The 4th International Workshop and The 3rd International Mini Workshop on Solution Plasma and Molecular Technologies
    • Place of Presentation
      West Bohemia University, Plzen, Czech Republic
    • Year and Date
      2016-06-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A semi-analytical model for static sheath including presheath2015

    • Author(s)
      T. Shirafuji and K. Denpoh
    • Organizer
      The 9th Asia-Pacific International Symposium on the Basics and Applications of Plasma Technology / The 28th Symposium on Plasma Science for Materials
    • Place of Presentation
      Nagasaki University, Nagasaki, Japan
    • Year and Date
      2015-12-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水が関与するマイクロプラズマの集積化とその材料プロセスへの応用2015

    • Author(s)
      白藤 立
    • Organizer
      東京理科大学総合研究院第1回ウォーターフロンティアサイエンスシンポジウム
    • Place of Presentation
      東京理科大学森戸記念館,東京新宿区
    • Year and Date
      2015-12-05
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Time-resolved OES on Argon DBD with a water electrode - Experimental results and numerical simulation2015

    • Author(s)
      T. Shirafuji, K. Obana, and K. Tanaka
    • Organizer
      The 37th International Symposium on Dry Process
    • Place of Presentation
      Awaji Yumebutai International Conference Center, Awaji, Japan
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mechanisms of methylene blue degradation in three-dimensionally integrated micro-solution plasma2015

    • Author(s)
      A. Nomura, Y. Hayashi, K. Tanaka, T. Shirafuji, and M. Goto
    • Organizer
      The 9th International Conference on Reactive Plasmas / The 68th Gaseous Electronics Conference / The 33rd Symposium on Plasma Processing
    • Place of Presentation
      Hawaii Convention Center, Honolulu, USA
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Time-resolved optical emission spectroscopy on DBD of Ar gas in contact with water2015

    • Author(s)
      K. Obana, K. Tanaka, and T. Shirafuji
    • Organizer
      The 9th International Conference on Reactive Plasmas / The 68th Gaseous Electronics Conference / The 33rd Symposium on Plasma Processing
    • Place of Presentation
      Hawaii Convention Center, Honolulu, USA
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水電極を有するArガスDBD中のOH(A)の挙動~時間分解OESと計算機シミュレーションによる検討~2015

    • Author(s)
      白藤 立,尾花 和彦,田中 健司
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 水面上Arガス誘電体バリア放電中のOH(A)の挙動2015

    • Author(s)
      白藤 立,尾花 和彦,田中 健司
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      広島大学,広島東広島市
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
  • [Remarks] 研究室の広報Web

    • URL

      http://t-shirafuji.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 研究室広報Web

    • URL

      http://t-shirafuji.jp/

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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