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Indium implantations onto porous zeolites for the development of novel catalysts

Research Project

Project/Area Number 15K13406
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Quantum beam science
Research InstitutionOsaka University

Principal Investigator

Yoshimura Satoru  大阪大学, 工学研究科, 准教授 (40294029)

Co-Investigator(Kenkyū-buntansha) 木内 正人  国立研究開発法人産業技術総合研究所, その他部局等, 研究員 (50356862)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Keywordsインジウム / ゼオライト / 触媒 / イオンビーム / プラズマ
Outline of Final Research Achievements

In previous papers, it has been reported that chemical substances that contain both indium (In) and silicon (Si) in close proximity catalyze certain organic chemical reactions. In this study, the implantation of In onto zeolite was carried out by an ion beam injection process or by an arc plasma process for the possible development of novel catalysts. In the ion beam experiment, In ions were generated by sputtering of In2O3 target with Ar ions in an ion source. In ions were extracted under high voltages to form mono-energic In ions with the peak energy of 500 eV. Then, the zeolite substrates were irradiated with the In ion beam. XRD and XPS of samples reveals that In was successfully implanted. However, we failed to detect the catalytic effects. On the other hand, In nanoparticles were deposited on zeolite using a pulse arc plasma system. We have found that the resulting materials were capable of catalyzing an organic chemical reaction, i.e., Friedel-Craft alkylation.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 4 results,  Acknowledgement Compliant: 4 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Deposition of indium nanoparticles on powdered material by pulse arc plasma to synthesize catalysts for Friedel-Crafts alkylation2018

    • Author(s)
      S. Yoshimura, Y. Nishimoto, S. Sugimoto, M. Kiuchi, M. Yasuda
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 16

    • NAID

      130006727036

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalytic property of an indium-deposited powder-type material containing silicon and its dependence on the dose of indium nano-particles irradiated by a pulse arc plasma process2017

    • Author(s)
      S. Yoshimura, Y. NIshimoto, M. Kiuchi, Y. Agawa, H. Tanaka, M. Yasuda
    • Journal Title

      AIP Advances

      Volume: 7 Issue: 6

    • DOI

      10.1063/1.4990517

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low-energy mass-selected ion beam production of fragments produced from hexamethyldisiloxane for the formation of silicon oxide film2017

    • Author(s)
      S. Yoshimura, S. Sugimoto, K. Murai, M. Kiuchi
    • Journal Title

      Surface and Coatings Technology

      Volume: 313 Pages: 402-406

    • DOI

      10.1016/j.surfcoat.2017.02.009

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Low-energy SiC2H6+ and SiC3H9+ ion beam productions by the mass-selection of fragments produced form hexamethyldisilane for SiC film formations2016

    • Author(s)
      S. Yoshimura, S. Sugimoto, K. Murai, M. Kiuchi
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 12

    • DOI

      10.1063/1.4972206

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 新規反応触媒開発を目指したゼオライトへのインジウム担持の試み2015

    • Author(s)
      吉村智, 木内正人, 西本能弘, 安田誠, 馬場章夫, 杢野由明, 杉本敏司, 浜口智志
    • Journal Title

      スマートプロセス学会誌

      Volume: 4 Pages: 228-233

    • NAID

      130005263569

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Indium implantation onto zeolite by pulse arc plasma process for the development of novel catalysts2015

    • Author(s)
      S. Yoshimura, Y. Nishimoto, M. Kiuchi, M. Yasuda
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 10 Pages: 1292-1294

    • DOI

      10.1246/cl.150499

    • NAID

      130005101464

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ヘキサメチルジシランの解離フラグメントの低エネルギーイオンビーム生成とシリコンカーバイド成膜2017

    • Author(s)
      吉村智, 杉本敏司, 木内正人
    • Organizer
      第44回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Indium nano-particles deposition to zeolite powder by a pulse arc plasma processs for synthesizing catalysts2017

    • Author(s)
      S. Yoshimura, Y. Nishimoto, S. Sugimoto, M. Kiuchi, M. Yasuda
    • Organizer
      The 8th International Symposium on Surface Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] インジウム担持ゼオライト触媒活性のインジウムドース依存性2016

    • Author(s)
      吉村智, 西本能弘, 木内正人, 安田誠
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟朱鷺メッセ(新潟県・新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] ゼオライトへのインジウム担持とその触媒活性2015

    • Author(s)
      吉村智, 西本能弘, 木内正人, 安田誠
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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