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Development of single-shot spectroscopy for vibrational optical activity

Research Project

Project/Area Number 15K13502
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Condensed matter physics I
Research InstitutionOsaka University

Principal Investigator

Nakamura Ryosuke  大阪大学, 産学連携本部, 特任講師 (70379147)

Co-Investigator(Kenkyū-buntansha) 梅村 信弘  千歳科学技術大学, 理工学部, 准教授 (40580098)
神村 共住  大阪工業大学, 工学部, 准教授 (40353338)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords赤外吸収 / レーザー分光 / 光学活性 / タンパク質
Outline of Final Research Achievements

We develop the spectroscopic system to detect vibrational optical activity with high sensitivity and high spectral resolution by using chirped pulse upconversion, where mid-infrared probe pulses are mixed with chirped pulses and converted into the visible region. It is shown that LiGaS2 is the best candidate for our purpose. The performance of the spectroscopic system is as follows: Spectral resolution of 2.8 cm, time resolutions of 0.2 ps, and noise level of 10-4. We also demonstrated that the mid-infrared spectroscopy using narrowband pump pulses with tunable frequency and polarization is sensitive to molecular structures.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (19 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Int'l Joint Research: 9 results)

  • [Journal Article] Simultaneous mid-infrared pulse generation and shaping in engineered quasi-phase-matched nonlinear crystals2017

    • Author(s)
      R. Nakamura
    • Journal Title

      Optics Communications

      Volume: 383 Pages: 545-550

    • DOI

      10.1016/j.optcom.2016.09.050

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Wide-bandgap nonlinear crystal LiGaS2 for femtosecond mid-infrared spectroscopy with chirped pulse upconversion2016

    • Author(s)
      R. Nakamura, Y. Inagaki, H. Hata, N. Hamada, N. Umemura, T. Kamimura
    • Journal Title

      Applied Optics

      Volume: 55 Issue: 33 Pages: 9365-9369

    • DOI

      10.1364/ao.55.009365

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Removal Technology of Poly-Vinyl Phenol Using Laser Irradiation2016

    • Author(s)
      T. Kamimura, K. Nuno, Y. Kuroki, T. Yamashiro, S. Tsujimoto, R. Nakamura, S. Takagi, T. Nishiyama, H. Horibe
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 29 Issue: 4 Pages: 633-637

    • DOI

      10.2494/photopolymer.29.633

    • NAID

      130005284455

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2016 Annual Research Report
  • [Presentation] Damage resistance of wide-bandgap nonlinear crystals for femtosecond mid-infrared spectrometer using chirped-pulse upconversion2016

    • Author(s)
      M. Akimoto, Y. Inagaki, H. Hata, N. Hamada, R. Nakamura, N. Umemura, M. Yoshimura, and T. Kamimura
    • Organizer
      48th Annual Symposium on Optical Materials for High-Power Lasers
    • Place of Presentation
      Boulder, CO, USA
    • Year and Date
      2016-09-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Laser removal of PVP without causing laser-induced surface damage2016

    • Author(s)
      K. Nuno, T. Yamashiro, S. Tuzimoto, R. Nakamura, S. Takagi, T. Nishiyama, H. Horibe, and T. Kamimura
    • Organizer
      48th Annual Symposium on Optical Materials for High-Power Lasers
    • Place of Presentation
      Boulder, CO, USA
    • Year and Date
      2016-09-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 和周波混合を用いた周波数領域2次元赤外分光法の開発II2016

    • Author(s)
      稲垣嘉清, 畑秀文, 神村共住, 梅村信弘, 濱田格雄, 中村亮介
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] リアルタイム時系列光子計測によるタンパク質のミリ秒構造追跡2016

    • Author(s)
      北林和樹, 神村共住, 濱田格雄, 中村亮介
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Femtosecond Mid-Infrared Spectrometer Using Chirped-Pulse Upconversion in a Wide-Bandgap Nonlinear Crystal2016

    • Author(s)
      Y. Inagaki, H. Hata, T. Kamimura, N. Umemura, N. Hamada, and R. Nakamura
    • Organizer
      5th Advanced Lasers and Photon Sources
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Monitoring Microsecond Conformational Dynamics of Biomolecules Based on Realtime Detection of Fluorescence Photon Sequence2016

    • Author(s)
      K. Kitabayashi, T. Kamimura, N. Hamada, and R. Nakamura
    • Organizer
      5th Advanced Lasers and Photon Sources
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Improvement of resist stripping efficiency without causing laser-induced surface damage2016

    • Author(s)
      K. Nuno, Y. Kuroki, S. Takagi, T. Yamashiro, S. Tsujimoto, R. Nakamura, T. Nishiyama, T. Kamimura, and H. Horibe
    • Organizer
      5th Pacific-rim Laser Damage Conference
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Substrate material dependence of the thin film stress and its controle2016

    • Author(s)
      H. Omatsu, M. Akimoto, T. Murakami, R. Nakamura, T. Kamimura, S. Tujimoto, and T. Ymasiro
    • Organizer
      5th Pacific-rim Laser Damage Conference
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 和周波混合を用いた周波数領域二次元赤外分光法の開発2016

    • Author(s)
      稲垣嘉清, 畑秀文, 中村亮介, 梅村信弘, 神村共住
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 金属錯体の光かい離過程における中赤外フェムト秒時間分解分光2016

    • Author(s)
      中村亮介, 畑秀文, 稲垣嘉清, 濱田格雄, 神村共住
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 中赤外フェムト秒時間分解分光のための和周波混合結晶の評価2015

    • Author(s)
      稲垣嘉清, 畑秀文, 中村亮介, 神村共住, 梅村信弘
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] チャープパルスアップコンバージョンを用いたタンパク質の中赤外フェムト秒時間分解分光2015

    • Author(s)
      畑秀文, 中村亮介, 濱田格雄, 神村共住
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 中赤外光励起によるタンパク質の振動エネルギーフロー解析2015

    • Author(s)
      中村亮介, 濱田格雄
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Vibrational energy flow in photoactive yellow protein studied by infrared pump and visible probe spectroscopy2015

    • Author(s)
      R. Nakamura and N. Hamada
    • Organizer
      17th International Conference on Time-Resolved Vibrational Spectroscopy
    • Place of Presentation
      Madison, WI, USA
    • Year and Date
      2015-06-21
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Transient IR Pump-Probe Spectroscopy of Photoactive Molecules using Chirped Pulse Upconversion2015

    • Author(s)
      H. Hata, R. Nakamura. N. Hamada, and T. Kamimura
    • Organizer
      3rd International Conference on Ultrafast Structural Dynamics
    • Place of Presentation
      Zurich, Switzerland
    • Year and Date
      2015-06-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Vibrational Energy Flow of Chromophore in Protein Probed by IR Pump and Visible Probe Spectroscopy2015

    • Author(s)
      R. Nakamura and N. Hamada
    • Organizer
      3rd International Conference on Ultrafast Structural Dynamics
    • Place of Presentation
      Zurich, Switzerland
    • Year and Date
      2015-06-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2020-05-15  

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