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Measurements of rovibrational constants of CaH+ for studying possible time variation of electron-proton mass ratio

Research Project

Project/Area Number 15K13545
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Atomic/Molecular/Quantum electronics
Research InstitutionSophia University

Principal Investigator

Okada Kunihiro  上智大学, 理工学部, 教授 (90311993)

Co-Investigator(Kenkyū-buntansha) 梶田 雅稔  国立研究開発法人情報通信研究機構, 電磁波研究所時空標準研究室, 主任研究員 (50359030)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsイオントラップ / クーロン結晶 / 分子イオン / 陽子-電子質量比 / CaH+ / レーザー冷却 / 光解離 / 回転温度 / 分子イオン分光 / 陽子ー電子質量比
Outline of Final Research Achievements

The purpose of the present work is determination of rovibrational constants of CaH+, which is one of the best candidates for studying possible time variation of the proton-electron mass ratio by ultraprecise vibrational spectroscopy. In order to measure the rovibrational constants, we have constructed a cryogenic linear Paul trap for rotational cooling of Coulomb crystallized CaH+ ions and laser spectroscopy system consisting of a mid-infrared laser and a violet semiconductor laser. We also performed a photodissociation experiment in order to determine the rovibrational constants. We successfully observed the photodissociation reaction CaH+ + hν → Ca+ + H. The lower limit of the photodissociation cross section was determined by the measurement of the photodissociation rate. This experimental progress paved the way to measure the rovibrational constant of CaH+ through LIF measurements.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015 Other

All Journal Article (13 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 13 results,  Open Access: 1 results,  Acknowledgement Compliant: 7 results) Presentation (18 results) (of which Int'l Joint Research: 8 results,  Invited: 4 results) Remarks (2 results)

  • [Journal Article] Photodissociation of sympathetically crystallized CaH+2017

    • Author(s)
      Naoki Kimura, Masatoshi Kajita, Kunihiro Okada
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 875 Pages: 022042-022042

    • DOI

      10.1088/1742-6596/875/3/022042

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Phase-coherent transfer and retrieval of terahertz frequency standard over 20 km optical fiber with 4 x 10-18 accuracy2017

    • Author(s)
      S. Nagano, M. Kumagai, H. Ito, M. Kajita, Y. Hanado
    • Journal Title

      Applied Physics Express

      Volume: 10 Pages: 012502-012502

    • DOI

      10.1109/irmmw-thz.2017.8067220

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-step pulse observation to improve resonance contrast for coherent population trapping atomic clock2017

    • Author(s)
      Yuichiro Yano Email author , Shigeyoshi Goka, Masatoshi Kajita
    • Journal Title

      Appl. Phys. B

      Volume: 123 Issue: 3 Pages: 671-8

    • DOI

      10.1007/s00340-017-6650-x

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Accuracy estimation of the 16O2+ transition frequencies targeting the search for the variation in the proton-electron mass ratio2017

    • Author(s)
      Masatoshi Kajita
    • Journal Title

      Phys. Rev. A

      Volume: 95 Issue: 2 Pages: 0234181-6

    • DOI

      10.1103/physreva.95.023418

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Search for the Variation in (mp/me) Using Two Vibrational Transition Frequencies of Molecular Ions2017

    • Author(s)
      Kajita Masatoshi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 86 Issue: 12 Pages: 123301-123301

    • DOI

      10.7566/jpsj.86.123301

    • NAID

      210000134597

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase-coherent transfer and retrieval of terahertz frequency standard over 20 km optical fiber with 4 x 10-18 accuracy2017

    • Author(s)
      Shigeo Nagano, Motohiro Kumagai, Hiroyuki Ito, Masatoshi Kajita and Yuko Hanado
    • Journal Title

      Appl. Phys. Express

      Volume: 10 Issue: 1 Pages: 0125021-4

    • DOI

      10.7567/apex.10.012502

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Accuracy estimation of the 16O2+ transition frequencies targeting the search for the variation in the proton-electron mass ratio2017

    • Author(s)
      Masatoshi Kajita
    • Journal Title

      Physical Review A

      Volume: 122 Pages: 2031-5

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaluation of variation in (mp/me) from the frequency difference between the 15N2+ and 87Sr transitions2016

    • Author(s)
      Masatoshi Kajita
    • Journal Title

      Appl. Phys. B

      Volume: 122 Issue: 7 Pages: 2031-5

    • DOI

      10.1007/s00340-016-6479-8

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Prospect of molecular clocks2016

    • Author(s)
      Masatoshi Kajita
    • Journal Title

      Asian Journal of Physics

      Volume: 25 Pages: 1051-1059

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quasi-equilibrium characterization of mixed ion Coulomb crystals2015

    • Author(s)
      Kunihiro Okada, Masanari Ichikawa, Michiharu Wada, and Hans A. Schuessler
    • Journal Title

      Physical Review Applied

      Volume: 4 Issue: 5

    • DOI

      10.1103/physrevapplied.4.054009

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Toward laser spectroscopy of rotationally cooled CaH+ ions trapped in a cryogenic linear Paul trap2015

    • Author(s)
      Kunihiro Okada and Masatoshi Kajita
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 635 Issue: 3 Pages: 032060-032060

    • DOI

      10.1088/1742-6596/635/3/032060

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of ion Coulomb crystals for fundamental sciences2015

    • Author(s)
      Kunihiro Okada, Masanari Ichikawa, MichiharuWada
    • Journal Title

      Hyperfine Interactions

      Volume: 236 Issue: 1-3 Pages: 87-94

    • DOI

      10.1007/s10751-015-1188-y

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] N2+ quadrupole transitions with small Zeeman shift2015

    • Author(s)
      Masatoshi Kajita
    • Journal Title

      Physical Review A

      Volume: 90 Issue: 4 Pages: 0434231-6

    • DOI

      10.1103/physreva.92.043423

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Search of the variation in the proton-to-electron mass ratio using two vibrational transition frequencies of molecular ions2018

    • Author(s)
      M. Kajita
    • Organizer
      10th International Workshop on Fundamental Physics Using Atoms (FPUA2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 多価イオン共同冷却実験に向けたイオン生成と捕捉II2018

    • Author(s)
      木村直樹, 和田道治, 岡田邦宏, 加藤英俊,中村信行, 大前宣昭, 香取秀俊
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photdissociation of sympathetically crystallized CaH+2017

    • Author(s)
      N. Kimura, M. Kajita, K. Okada
    • Organizer
      XXX International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A laboratory study of interstellar ion-polar molecule reactions2017

    • Author(s)
      K. Okada
    • Organizer
      1st North American Conference on Trapped Ions (NACTI 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of cryogenic linear combined ion trap for cold Highly Charged Ion generation2017

    • Author(s)
      N. Kimura, M. Wada, K. Okada, N. Nakamura, N. Ohmae, H. Katori
    • Organizer
      9th International Workshop on Fundamental Physics Using Atoms (FPUA2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 冷却多価イオン生成に向けたイオントラップ装置の開発とその機能試験2017

    • Author(s)
      木村直樹, 和田道治, 岡田邦宏, 加藤英俊, 中村信行, 大前宣昭, 香取秀俊
    • Organizer
      原子衝突学会第42回年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 多価イオン共同冷却実験に向けたイオン生成と捕捉2017

    • Author(s)
      木村直樹, 和田道治, 岡田邦宏, 加藤英俊, 中村信行, 大前宣昭, 香取秀俊
    • Organizer
      日本物理学会2017年度秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 基礎物理定数の時間依存性検証に向けた冷却多価イオン生成装置の開発構想と現状2017

    • Author(s)
      木村直樹, 和田道治, 岡田邦宏, 加藤英俊, 中村信行, 大前宣昭, 香取秀俊
    • Organizer
      第5回超精密周波数計測とその比較技術による回路技術調査専門委員
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Precise measurement of N2+ vibrational transition frequency toward the test of variation in mp/me2017

    • Author(s)
      梶田雅稔
    • Organizer
      International Conference on "Fundamental Physics Using Atoms"
    • Place of Presentation
      京都大学桂キャンパス(京都府・京都市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 陽子ー電子質量比変化の観測を目指したO2+遷移周波数の確度見積もり2017

    • Author(s)
      梶田雅稔
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 15N2+と87Srの遷移周波数差による陽子-電子質量比変化の高感度検出2016

    • Author(s)
      梶田雅稔
    • Organizer
      日本物理学会
    • Place of Presentation
      金沢大学角間キャンパス(石川県・金沢市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] クーロン結晶化した極低温分子イオンCaX+ ( X = O, H) の光解離2016

    • Author(s)
      岡田邦宏,梶田雅稔
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      宮城県仙台市,東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 窒素分子イオン四重極遷移周波数の精密計測2016

    • Author(s)
      梶田雅稔
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      宮城県仙台市,東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Prospect of molecular clocks2016

    • Author(s)
      梶田雅稔
    • Organizer
      Workshop “Current Trend and Future Directions in Relativistic Many Electron Theories”
    • Place of Presentation
      東京工業大学(東京都・目黒区)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Precise measurement of N2+ vibrational transition frequencies2016

    • Author(s)
      梶田雅稔
    • Organizer
      European Conference on Trapped Ions
    • Place of Presentation
      Waldhotel National(Arosa, スイス)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 周波数精密計測が現代物理に与える役割2016

    • Author(s)
      梶田雅稔
    • Organizer
      電子回路委員会
    • Place of Presentation
      情報通信研究機構(東京都・小金井市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Precise measurement of N2+ vibrational transition frequency - toward the test of variation in mp/me2015

    • Author(s)
      梶田雅稔
    • Organizer
      International Conference on "Fundamental Physics Using Atoms"
    • Place of Presentation
      東京都和光市,理化学研究所
    • Year and Date
      2015-12-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Toward laser spectroscopy of rotationally cooled CaH+ ions trapped in a cryogenic linear Paul trap2015

    • Author(s)
      Kunihiro Okada and Masatoshi Kajita
    • Organizer
      XXIX International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC2015)
    • Place of Presentation
      Toledo, Spain, Toledo Congress Centre
    • Year and Date
      2015-07-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 上智大学理工学部・原子物理研究室

    • URL

      http://www.ph.sophia.ac.jp/~ttak-ken/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 上智大学理工学部・原子物理研究室

    • URL

      http://www.ph.sophia.ac.jp/~ttak-ken/index.html

    • Related Report
      2016 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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