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Nitrogen geochemistry: Speciation of nitrogen in the deep earth from high pressure and high temperature experiments

Research Project

Project/Area Number 15K13600
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Geochemistry/Cosmochemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Kagi Hiroyuki  東京大学, 大学院理学系研究科(理学部), 教授 (70233666)

Co-Investigator(Kenkyū-buntansha) 篠崎 彩子  名古屋大学, 環境学研究科, 学振特別研究員(PD) (80570506)
岡田 卓  東京大学, 大学院理学系研究科(理学部), 特任助教 (90343938)
佐野 有司  東京大学, 大気海洋研究所, 教授 (50162524)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords窒素 / 高温高圧実験 / マントル / 下部マントル / 窒化物 / 地球深部
Outline of Final Research Achievements

Nitrogen is a major element in the atmosphere and one of the very important elements for life. However, the budget ant behavior in the deep earth is unclear. In this research project, we synthesized mantle minerals using a multi anvil high-pressure apparatus and investigated concentrations of nitrogen. We found that the lower mantle can be an important nitrogen reservoir.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (20 results)

All 2018 2017 2016 2015

All Journal Article (13 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 13 results,  Open Access: 7 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] High-Pressure - High-Temperature Study of Benzene: Refined Crystal Structure and New Phase Diagram up to 8 GPa and 923 K2018

    • Author(s)
      Chanyshev Artem D.、Litasov Konstantin D.、Rashchenko Sergey V.、Sano-Furukawa Asami、Kagi Hiroyuki、Hattori Takanori、Shatskiy Anton F.、Dymshits Anna M.、Sharygin Igor S.、Higo Yuji
    • Journal Title

      Crystal Growth & Design

      Volume: 印刷中 Issue: 5 Pages: 3016-3026

    • DOI

      10.1021/acs.cgd.8b00125

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Behavior of intermolecular interactions in α-glycine under high pressure2018

    • Author(s)
      Shinozaki, Ayako Komatsu, Kazuki Kagi, Hiroyuki Fujimoto, Chikako Machida, Shinichi Sano-Furukawa, Asami Hattori, Takanori
    • Journal Title

      The Journal of Chemical Physics

      Volume: 148 Issue: 4 Pages: 044507-044507

    • DOI

      10.1063/1.5009980

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Fluorenylidene-Acridane That Becomes Dark in Color upon Grinding _ Ground State Mechanochromism by Conformational Change2018

    • Author(s)
      Tsuyoshi Suzuki, Hiroshi Okada, Takafumi Nakagawa, Kazuki Komatsu, Chikako Fujimoto, Hiroyuki Kagi, Yutaka Matsuo
    • Journal Title

      Chem. Sci.

      Volume: 9 Issue: 2 Pages: 475-482

    • DOI

      10.1039/c7sc03567e

    • NAID

      120006708961

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Raman spectroscopic determination of Sr/Ca ratios of calcite samples2017

    • Author(s)
      Shibano Y., Takahata K., Kawano J., Watanabe T., Enomoto D., Kagi H., Kamiya N. and Yamamoto J.
    • Journal Title

      Journal of Raman Spectroscopy

      Volume: 48 Issue: 12 Pages: 1755-1761

    • DOI

      10.1002/jrs.5235

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Trace element composition and U-Pb age of zircons from Estherville: Constraints on the timing of the metal-silicate mixing event on the mesosiderite parent body2017

    • Author(s)
      Haba Makiko K.、Yamaguchi Akira、Kagi Hiroyuki、Nagao Keisuke、Hidaka Hiroshi
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 215 Pages: 76-91

    • DOI

      10.1016/j.gca.2017.07.028

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Bulk moduli and equations of state of ice VII and ice VIII2017

    • Author(s)
      Klotz, S., Komatsu, K., Kagi, H., Kunc, K., Sano-Furukawa, A., Machida, S. and Hattori, T
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 17 Pages: 174111-174111

    • DOI

      10.1103/physrevb.95.174111

    • NAID

      120006502074

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Note: Development of a new Bridgman-type high pressure cell for accurate dielectric measurements2017

    • Author(s)
      Yamane, R. Komatsu, K. Kagi, H.
    • Journal Title

      Review of Scientific Instruments

      Volume: 88 Issue: 4 Pages: 046104-046104

    • DOI

      10.1063/1.4980154

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced phase transition of vaterite, a metastable phase of CaCO3.2017

    • Author(s)
      Maruyama K., Kagi H., Komatsu K., Yoshino T. and Nakano S.
    • Journal Title

      Journal of Raman Spectroscopy

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Detection of increased heating and estimation of coseismic shear stress from Raman spectra of carbonaceous material in pseudotachylytes2017

    • Author(s)
      Ito, K., K. Ujiie, and H. Kagi
    • Journal Title

      Geophysical Research Letters

      Volume: 44 Issue: 4 Pages: 1749-1757

    • DOI

      10.1002/2016gl072457

    • NAID

      120007134982

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] The mineralogy of Ca-rich inclusions in sublithospheric diamonds2016

    • Author(s)
      D.A. Zedgenizov, A.L. Ragozin, V.V. Kalinina, H. Kagi
    • Journal Title

      Geochemistry International

      Volume: 54 Issue: 10 Pages: 890-900

    • DOI

      10.1134/s0016702916100116

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Micro- and nano-inclusions in a superdeep diamond from Sao Luiz, Brazil2016

    • Author(s)
      H. Kagi, D.A. Zedgenizov, H. Ohfuji, and H. Ishibashi
    • Journal Title

      Geochemistry International

      Volume: 54 Issue: 10 Pages: 834-838

    • DOI

      10.1134/s0016702916100062

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] The features of Ca-mineralogy of inclusions in sublithospheric diamonds.2016

    • Author(s)
      Zedgenizov D.A., Ragozin A.L., Kalinina V.V., and Kagi H.
    • Journal Title

      Geochemistry International

      Volume: 印刷中

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preferential dissolution of SiO2 from enstatite to H2 fluid under high pressure and temperature.2015

    • Author(s)
      Shinozaki A., Kagi H., Hirai H., Ohfuji H., Okada T., Nakano S. and Yagi T.
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 43 Issue: 4 Pages: 277-285

    • DOI

      10.1007/s00269-015-0792-3

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Incorporation of nitrogen into the lower-mantle minerals under high pressure and high temperature2018

    • Author(s)
      Hiroyuki Kagi
    • Organizer
      FY2017 General Meeting / International Symposium, Interaction and Coevolution of the Core and Mantle
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高温高圧実験からみたマントル鉱物への窒素取り込み2017

    • Author(s)
      鍵 裕之, 福山 鴻, 井上 徹, 柿澤 翔, 新名 亨, 高畑 直人, 佐野 有司
    • Organizer
      日本地球化学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高温高圧下における下部マントル鉱物への窒素の固溶2017

    • Author(s)
      鍵 裕之, 福山 鴻, 井上 徹, 柿澤 翔, 新名 亨, 高畑 直人, 佐野 有司
    • Organizer
      日本鉱物科学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高温高圧下における窒素・アンモニア流体とケイ酸塩鉱物の反応2016

    • Author(s)
      星野 由紀子、岡田 卓、鍵 裕之、八木 健彦、篠崎 彩 子、中野 智志
    • Organizer
      高圧討論会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Research-status Report
  • [Presentation] Reaction between olivine and nitrogen at high pressure and high temperature2016

    • Author(s)
      Hiroyuki Kagi, Toshinori Kubo, Taku Okada, Takehiko Yagi, Ayako Shinozaki, Hiroaki Ohfuji, Satoshi Nakano, Aiko Nakao
    • Organizer
      International Symposium Advances in High Pressure Research III: Towards Geodynamic Implications-2016
    • Place of Presentation
      Novosibirsk (Russia)
    • Year and Date
      2016-08-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Pressure-induced reactions in organic materials: a new insight for evolution of bio-related molecules2015

    • Author(s)
      Hiroyuki Kagi
    • Organizer
      International Seminar “High-Pressure Mineralogy: Theory and Experiment”
    • Place of Presentation
      モスクワ(ロシア)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高温高圧下における窒素流体中でのカンラン石の挙動2015

    • Author(s)
      久保 俊智, 鍵 裕之, 篠崎 彩子, 岡田 卓, 中野 智志, 中尾 愛子
    • Organizer
      日本地球化学会第62回年会
    • Place of Presentation
      横浜国立大学(神奈川県・横浜市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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