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Visualization of ion diffusion process at interface by sequential measurement method of electrostatic potential.

Research Project

Project/Area Number 15K13622
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

Oshima Yoshifumi  北陸先端科学技術大学院大学, 先端科学技術研究科, 准教授 (80272699)

Research Collaborator ZHANG Xiaobin  北陸先端科学技術大学院大学, ナノマテリアルテクノロジーセンター, 研究員 (40647111)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords透過型電子顕微鏡 / 位相情報 / 静電ポテンシャル / イオン拡散 / ナノギャップ
Outline of Final Research Achievements

In order to clarify the visualization of the electrostatic potential distribution at the interfaces of two different phases and find the local ion diffusion at the interface, intensity transport equations was applied to the transmission electron microscope (TEM) images. We succeeded in obtaining the electrostatic potential at the a-Ge film / vacuum interface from the three TEM images of under focus, in focus and over focus. Actually, we solved the problem that the low frequency component of white noise is emphasized in the TIE phase map by narrower region of interest, and also solved the problem that the intensity transport equation could not be applied to the image not satisfying the periodic boundary condition such as TEM image of two phase interface by mirroring method.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015

All Journal Article (9 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 9 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results)

  • [Journal Article] Fabrication of hydrazine sensor based on silica-coated Fe2O3 magnetic nanoparticles prepared by a rapid microwave irradiation method2017

    • Author(s)
      H. Akhter, J. Murshed, Md. A. Rashed, Y. Oshima, Y. Nagao, M. M. Rahman, A. M. Asiri, M.A. Hasnat, Md. N. Uddin, and I. A. Siddiquey
    • Journal Title

      J. Alloys and Compounds

      Volume: 698 Pages: 921-929

    • DOI

      10.1016/j.jallcom.2016.12.266

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Three-dimensional characterization of Guinier-Preston zones in an Al-Cu alloy using depth-sectioning technique2017

    • Author(s)
      T. Hamaoka, C.-Y. Jao, X. Zhang, Y. Oshima, and Masaki Takeguchi
    • Journal Title

      Microscopy

      Volume: 66 Pages: 78-88

    • DOI

      10.1093/jmicro/dfw104

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction study of nitrogen ion beam with silicon2017

    • Author(s)
      M. E. Schmidt, X. Zhang, Y. Oshima, L. T. Anh A. Yasaka, T. Kanzaki, M. Muruganathan, M. Akabori, T. Shimoda and H. Mizuta
    • Journal Title

      J. Vac. Sci.& Tech. B

      Volume: 35 Issue: 3

    • DOI

      10.1116/1.4977566

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Detection of large thermal vibration for Cu atoms in tetrahedrite by high-angle annular dark-field imaging2017

    • Author(s)
      T. P. Mishra, M. Koyano and Y. Oshima
    • Journal Title

      Appl. Phys. Express

      Volume: 10 Issue: 4 Pages: 045601-045601

    • DOI

      10.7567/apex.10.045601

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A stable lithium-rich surface structure for lithium-rich layered cathode materials2016

    • Author(s)
      S. Kim, W. Cho, X. Zhang, Y. Oshima and J. Wook Choi
    • Journal Title

      Nature Communications

      Volume: 7 Issue: 1 Pages: 13598-13598

    • DOI

      10.1038/ncomms13598

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] In situ Scanning Electron Microscope Observation of Silicon Anode Reactions in Lithium-Ion Battery during Charge-Discharge Processes2016

    • Author(s)
      Chen, C.-Y.; Sano, T.; Tsuda, T.; Ui, K.; Oshima, Y.; Yamagata, M.; Ishikawa, M.; Haruta, M.; Doi, T.; Inaba, M.; Kuwabata, S.
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 36153-36153

    • DOI

      10.1038/srep36153

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] On the Mechanism of Crystal Water Insertion during Anomalous Spinel-to-Birnessite Phase Transition2016

    • Author(s)
      S. Kim, S. Lee, K. W. Nam, J. Shin, S. Y. Lim, W. Cho, K. Suzuki, Y. Oshima, M. Hirayama, R. Kanno and J. W. Choi
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 15 Pages: 5488-5494

    • DOI

      10.1021/acs.chemmater.6b02083

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic resolved Phase Map of monolayer MoS2 retrieved by Spherical Aberration-Corrected Transport of Intensity Equation2016

    • Author(s)
      X. Zhang and Y. Oshima
    • Journal Title

      Microscopy

      Volume: 65 Issue: 5 Pages: 422-428

    • DOI

      10.1093/jmicro/dfw026

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental Evaluation of Spatial Resolution in Phase Maps Retrieved by Transport of Intensity Equation2015

    • Author(s)
      Xiaobin Zhang, Yoshifumi Oshima
    • Journal Title

      Microscopy

      Volume: 64 Issue: 6 Pages: 395-400

    • DOI

      10.1093/jmicro/dfv045

    • NAID

      120006725401

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] アトミックカーボンチェン形成過程のその場TEM観察2017

    • Author(s)
      (40)張暁賓,水谷加奈子,マレクシュッミット,ムルガナタンマノハラン,水田博,大島義文
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Operando TEM observation of lithium ion bettery2016

    • Author(s)
      Y. Oshima, S. Lee and K. Takayanagi
    • Organizer
      20th International Vacuum Congress
    • Place of Presentation
      Busan (Korea)
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a TEM holder for electronic conductance measurement of suspended graphene nanoribbons2016

    • Author(s)
      X. Zhang, S. Iwashiwa, M. Schmidt, M. Muruganathan, H. Mizuta and Y. Oshima
    • Organizer
      20th International Vacuum Congress
    • Place of Presentation
      Busan (Korea)
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Operand Transmission Electron Microscope Observation of Lithium Ion Battery -What happened during the Operation2016

    • Author(s)
      Y. Oshima
    • Organizer
      The 11th Asia-Pacific Microscopy Conference
    • Place of Presentation
      Phuket (Thailand)
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Operando TEM Observation of Lithium Ion Battery2016

    • Author(s)
      Y. Oshima
    • Organizer
      The 5th International Symposium on Advanced Microscopy and Theoretical Calculations
    • Place of Presentation
      ウインクあいち(愛知県名古屋市)
    • Year and Date
      2016-05-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Phase Map of a Single MoS2 Sheet Retrieved by Aberration Corrected Transport of Intensity Equation2015

    • Author(s)
      Xiaobin Zhang, Yoshifumi Oshima
    • Organizer
      2nd East-Asia Microscopy Conference
    • Place of Presentation
      姫路商工会議所(兵庫県姫路市)
    • Year and Date
      2015-11-24
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] In-Situ TEM Observation of Electrochemical Process2015

    • Author(s)
      Yoshifumi Oshima
    • Organizer
      2nd East-Asia Microscopy Conference
    • Place of Presentation
      姫路商工会議所(兵庫県姫路市)
    • Year and Date
      2015-11-24
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Atomic Resolved phase Map of MoS2 Monolayer Sheet Retrieved by Spherical Aberration Corrected Transport of Intensity Equation2015

    • Author(s)
      Xiaobin Zhang, Yoshifumi Oshima
    • Organizer
      Microscopy and Microanalysis 2016
    • Place of Presentation
      Portland コンベンションセンター(米国)
    • Year and Date
      2015-08-03
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 収差補正TIE法を用いた2硫化モリブデンシートの原子分解能位相像2015

    • Author(s)
      張 暁賓,大島 義文
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都国際会議場(京都府京都市)
    • Year and Date
      2015-05-12
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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