multidimensional obervation of orientational vector correlation and the resonance on the scattering partial wave in the cold radical reaction

• Project/Area Number: 15K13624
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Physical chemistry
• Research Institution: Osaka University
• Principal Investigator: Ohoyama Hiroshi 大阪大学, 理学研究科, 准教授 (60192522)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: 極低温 / 散乱部分波 / 分子偏向器 / 偏向装置 / 極低温ラジカル反応 / 配向ベクトル相関 / 散乱部分波共鳴

Outline of Final Research Achievements

We developed　an experiment apparatus for the study on the orientational vector correlation in the radical-radical reaction at the extremely low collision energy region without lowering the molecular beam velocity. For this purpose, we developed a molecular beam deflector for the merging beam technique. A curved quadrupole molecular deflector was developed and its performance was evaluated. In this study, ｗe clarified the effectiveness of this technique and it's practical problems.

Research Products

• [Journal Article] Initial dissolution of D2O at the gas liquid interface of the ionic liquid [C4min][NTf2] associated with hydrogen-bond network formation (2016)
  • Author(s): H. Ohoyama, T. Teramoto
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 18 Issue: 40 Pages: 28061-28068
  • DOI: 10.1039/c6cp03448a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Intra-grain conduction of self-doped polyaniline (2016)
  • Author(s): Yuki Usami, Kentaro Imamura, Tomoki Akai, Dock-Chil Che, Hiroshi Ohoyama, Hikaru Kobayashi, Takuya Matsumoto
  • Journal Title: J. Appl. Phys. Volume: VOL.120 Issue: 8 Pages: 084308-084308
  • DOI: 10.1063/1.4961610
  • Peer Reviewed
• [Journal Article] Atomic Alignment Effect on Reactivity and on Product Alignment in the Energy-Transfer Reaction of Oriented Ar (3P2, 4s [3/2]2, MJ = 2) + Kr (4p6,1S0) → Ar (3p6, 1S0) + Kr (5p [3/2]2) (2015)
  • Author(s): H. Ohoyama
  • Journal Title: J. Phys. Chem. A Volume: 119 Issue: 10 Pages: 1820-1829
  • DOI: 10.1021/jp509989x
  • Peer Reviewed
• [Presentation] Study on gas dissolution dynamics at the gas-liquid interface by usin an ionic liquid beam (2016)
  • Author(s): Matsuura Y., Teramoto T., Ohoyama H.
  • Organizer: 32th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 大宮ソニックシティホール
• [Presentation] イオン液体分子線を用いた気―液界面でのガス溶解過程の研究 (2016)
  • Author(s): 松浦裕介、寺本高啓、大山浩
  • Organizer: 第１０回分子科学討論会
  • Place of Presentation: 神戸ファッションマート
• [Presentation] イオン液体分子線を用いた気-液界面溶解ダイナミクスの研究 (2015)
  • Author(s): 松浦 裕介,寺本 高啓,大山 浩
  • Organizer: 第９回分子科学討論会
  • Place of Presentation: 東京工業大学 大岡山キャンパス(東京都）
  • Year and Date: 2015-09-16
• [Presentation] Study on collision dynamics at the gas-liquid interface by using an ionic liquid beam (2015)
  • Author(s): MATSUURA, Yusuke; TERAMOTO, Takahiro; OHOYAMA, Hiroshi
  • Organizer: 第31回化学反応討論会
  • Place of Presentation: 北海道大学工学部フロンティア応用科学研究棟（北海道札幌市）
  • Year and Date: 2015-06-03