• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Thermodynamic study of liquid droplets in a vacuum and their application to bio-molecular analysis

Research Project

Project/Area Number 15K13627
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionKyushu University

Principal Investigator

TERASAKI Akira  九州大学, 理学研究院, 教授 (60222147)

Co-Investigator(Renkei-kenkyūsha) ARAKAWA Masashi  九州大学, 理学研究院, 助教 (10610264)
Research Collaborator ANDO Kota  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords液滴 / 真空 / 水 / エチレングリコール / 熱力学 / 蒸発冷却 / 輻射加熱 / 凍結核生成 / 過冷却液体
Outline of Final Research Achievements

Liquid droplets of water and ethylene glycol (EG) were investigated by developing a technique to generate and trap a micrometer-sized liquid droplet in a vacuum. In general, it is anticipated that the droplet would freeze immediately due to rapid cooling via fast evaporation of liquid exposed to a vacuum. We evaluated temperature-dependent homogeneous nucleation rate of supercooled water by observing water droplets for about 10 ms until freezing. On the other hand, an aqueous solution of inorganic salt was found to evaporate more slowly than pure water. In contrast, EG, which exhibits vapor pressure much lower than water, was found to survive as liquid for more than tens of seconds because evaporative cooling and room-temperature radiative heating compensate for each other to keep the droplet's temperature constant above freezing point. These findings provide us with novel knowledge useful for exploiting liquid in a vacuum.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016 2015 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Evaporation processes of a liquid droplet of ethylene glycol in a vacuum2016

    • Author(s)
      K. Ando, M. Arakawa, and A. Terasaki
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 8 Pages: 961-963

    • DOI

      10.1246/cl.160381

    • NAID

      130005254527

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Freezing process of a water droplet evaporatively cooled in a vacuum2017

    • Author(s)
      Kota Ando, Masashi Arakawa, and Akira Terasaki
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 真空中で蒸発冷却された水液滴の凍結時間のサイズ依存性2017

    • Author(s)
      安東航太、荒川 雅、寺嵜 亨
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 真空中で蒸発冷却された液滴の温度測定2016

    • Author(s)
      安東航太、荒川 雅、寺嵜 亨
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Liquid droplets in a vacuum for wet chemistry of gas-phase clusters2016

    • Author(s)
      Kota Ando, Masashi Arakawa, and Akira Terasaki
    • Organizer
      Eighteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 18)
    • Place of Presentation
      Jyvaskyla;, Finland
    • Year and Date
      2016-08-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characterization of liquid micro-droplets in a vacuum: evaporative cooling and freezing2016

    • Author(s)
      A. Terasaki, K. Ando, and M. Arakawa
    • Organizer
      The 13th Trombay Symposium on Radiation & Photochemsitry
    • Place of Presentation
      Mumbai, India
    • Year and Date
      2016-01-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Trapping a liquid micro-droplet in a vacuum toward wet chemistry of gas-phase clusters2015

    • Author(s)
      K. Ando, M. Arakawa, and A. Terasaki
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 真空中で発生・捕捉した液滴の蒸発速度・凍結時間の測定2015

    • Author(s)
      安東航太、荒川 雅、寺嵜 亨
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Book] Evaporation and freezing processes of liquid droplets in a vacuum2018

    • Author(s)
      Kota Ando
    • Total Pages
      64
    • Publisher
      九州大学大学院理学府(博士論文)
    • Related Report
      2017 Annual Research Report
  • [Remarks] 量子化学研究室ホームページ

    • URL

      http://www.scc.kyushu-u.ac.jp/quantum/index_j.php

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi