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Preparation of cold ions and detection of nuclear polarization for gas-phase NMR spectroscopy

Research Project

Project/Area Number 15K13630
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionToyota Physical and Chemical Research Institute (2017)
Institute for Molecular Science (2015-2016)

Principal Investigator

Fuke Kiyokazu  公益財団法人豊田理化学研究所, フェロー事業部門, フェロー (00111766)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords核磁気共鳴 / 気相イオン / 極低温冷却 / 核スピン分極 / 質量分析 / RF磁場励起
Outline of Final Research Achievements

We are constructing a gas-phase NMR apparatus of molecular ions based on a Stern-Gerlach type detection technique using a Penning trap (NMR cell). In this method, ultracold molecular ions are introduced in the cell and its magnetic resonance is probed by observing the modulation of their TOFs induced by the RF magnetic excitation at both ends of the cell. Thus, the preparation and manipulation of cold ions under the strong magnetic field are the basic techniques of this method. We present new experimental techniques and the results on cold trimethylamine ions with translational temperature of less than 1 mK, which are prepared through deceleration, slicing, and bunching of the ions generated by the photoionization of supersonically cooled trimethylamine. We also developed a RF magnetic excitation system for the NMR detection. Using these techniques, we are conducting a proof of principle experiment of new NMR method for gas-phase ions.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (4 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results)

  • [Journal Article] Preparation of cold ions in strong magnetic field and its application to gas-phase NMR spectroscopy2015

    • Author(s)
      K. Fuke, Y. Ohshima, M. Tona
    • Journal Title

      Hyperfine Interactions

      Volume: 236 Issue: 1-3 Pages: 9-18

    • DOI

      10.1007/s10751-015-1189-x

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 気相イオンの極低温冷却と気相NMR分光法への応用2017

    • Author(s)
      冨宅喜代一
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 気相イオンの極低温冷却法の開発と気相NMR分光法への応用2016

    • Author(s)
      冨宅喜代一
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 気相イオンの極低温冷却法と気相NMR分光法への応用2015

    • Author(s)
      冨宅喜代一、大島康裕
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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