Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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Outline of Final Research Achievements |
We have attempted to control the redox property of antiaromatic norcorrole derivatives by introducing a variety of substituents. Introduction of two electron-donating aryl groups or electron-withdrawing aryl groups significantly destabilized norcorroles. However, installation of both electron-donating and electron-withdrawing aryl groups allowed isolation of novel norcorrole derivatives as stable compounds. We have also elucidated redox properties of norcorrole derivatives, which were substantially influenced by the introduced substituents.
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