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Exploitation of porphyrinoids for secondary batteries

Research Project

Project/Area Number 15K13639
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionNagoya University

Principal Investigator

SHINOKUBO Hiroshi  名古屋大学, 工学研究科, 教授 (50281100)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsポルフィリン / 二次電子 / 蓄電池 / 酸化還元 / 反芳香族 / 活物質 / π電子化合物 / 二次電池 / 反芳香族性 / π拡張
Outline of Final Research Achievements

We have attempted to control the redox property of antiaromatic norcorrole derivatives by introducing a variety of substituents. Introduction of two electron-donating aryl groups or electron-withdrawing aryl groups significantly destabilized norcorroles. However, installation of both electron-donating and electron-withdrawing aryl groups allowed isolation of novel norcorrole derivatives as stable compounds. We have also elucidated redox properties of norcorrole derivatives, which were substantially influenced by the introduced substituents.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (19 results)

All 2017 2016 2015 Other

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 6 results,  Invited: 7 results) Remarks (2 results)

  • [Journal Article] Enhancing the low-energy absorption band and charge mobility of antiaromatic Ni(II) norcorroles by their substituent effects2017

    • Author(s)
      T. Yoshida
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 6 Pages: 1112-1115

    • DOI

      10.1039/c6cc09444a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin2015

    • Author(s)
      Y. Tanaka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 37 Pages: 10908-10911

    • DOI

      10.1002/anie.201505130

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Indolylindolinone: Easily Accessible, Tunable, and Wide-Range Absorbing Dyes2015

    • Author(s)
      A. Shiegno
    • Journal Title

      Chem. Lett.

      Volume: 44 Issue: 12 Pages: 1703-1705

    • DOI

      10.1246/cl.150815

    • NAID

      130005112551

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis and Properties of 10-Heterocorroles2017

    • Author(s)
      H. Shinokubo
    • Organizer
      231th ECS Meeting
    • Place of Presentation
      New Orleans
    • Year and Date
      2017-05-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A facile synthesis of novel expanded porphyrinoids: BisNi(II) complexes of dicyanovinylene-di(meso-aryl)dipyrromethene2017

    • Author(s)
      Nathan Faialaga
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 反芳香族ノルコロールの新規周辺官能基化反応の開発2016

    • Author(s)
      川島 弘之
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] 置換基効果を利用した反芳香族ノルコロールの物性発現2016

    • Author(s)
      吉田 拓矢
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] Studies of Substituent Effects on Antiaromatic Norcorroles2016

    • Author(s)
      吉田 拓矢
    • Organizer
      IGER 2015年度年次報告会
    • Place of Presentation
      名古屋
    • Year and Date
      2016-01-08
    • Related Report
      2015 Research-status Report
  • [Presentation] A study on organic batteries using porphyrinoid electrodes2016

    • Author(s)
      Ji-Young SHIN
    • Organizer
      Pre-ICMM2016
    • Place of Presentation
      Nagoya
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Properties of Antiaromatic Porphyrins2016

    • Author(s)
      H. Shinokubo
    • Organizer
      229th ECS Meeting
    • Place of Presentation
      San Diego
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 反芳香族ポルフィリンの合成と物性2016

    • Author(s)
      忍久保 洋
    • Organizer
      京都大学大学院理学研究科講演会
    • Place of Presentation
      京都
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 合成化学から生活を豊かにする機能性マテリアル創出へ!2016

    • Author(s)
      忍久保 洋
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Antiaromatic Norcorrol Batteries2015

    • Author(s)
      J.-Y. Shin
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Honolul
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 反芳香族ノルコロールの新規周辺官能基化反応の開発2015

    • Author(s)
      川島 弘之
    • Organizer
      第46回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      津
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
  • [Presentation] テトラアザポルフィリン五価リン錯体の一電子還元による安定19πポルフィリノイドの生成2015

    • Author(s)
      吉田 拓矢
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      松山
    • Year and Date
      2015-09-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Syntheses and Properties of Novel Porphyrinoids from Dipyrrins2015

    • Author(s)
      H. Shinokubo
    • Organizer
      The 7th East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka
    • Year and Date
      2015-09-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis, Property, and Application of Antiaromatic Porphyrins2015

    • Author(s)
      H. Shinokubo
    • Organizer
      ICMAT 2015
    • Place of Presentation
      Singapore
    • Year and Date
      2015-06-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] Shinokubo group

    • URL

      http://www.apchem.nagoya-u.ac.jp/hshino/top.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 忍久保研究室

    • URL

      http://www.apchem.nagoya-u.ac.jp/hshino/top.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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