Exploitation of porphyrinoids for secondary batteries
| Project/Area Number |
15K13639
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | ポルフィリン / 二次電子 / 蓄電池 / 酸化還元 / 反芳香族 / 活物質 / π電子化合物 / 二次電池 / 反芳香族性 / π拡張 |
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| Outline of Final Research Achievements |
We have attempted to control the redox property of antiaromatic norcorrole derivatives by introducing a variety of substituents. Introduction of two electron-donating aryl groups or electron-withdrawing aryl groups significantly destabilized norcorroles. However, installation of both electron-donating and electron-withdrawing aryl groups allowed isolation of novel norcorrole derivatives as stable compounds. We have also elucidated redox properties of norcorrole derivatives, which were substantially influenced by the introduced substituents.
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Report
(3 results)
Research Products
(19 results)
