Synthesis of high-quality pi-coordination nanosheet using gaseous interface
| Project/Area Number |
15K13654
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
Nishihara Hiroshi 東京大学, 大学院理学系研究科(理学部), 教授 (70156090)
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| Co-Investigator(Renkei-kenkyūsha) |
Sakamoto Ryota 東京大学, 大学院理学系研究科, 助教 (80453843)
Kusamoto Tetsuro 東京大学, 大学院理学系研究科, 助教 (90585192)
Nakazato Kazuo 名古屋大学, 大学院工学研究科, 教授 (90377804)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 気相合成 / 気固界面 / 配位ナノシート / STM / 金属錯体 / 二次元物質 / 金属錯体ナノシート / 電気伝導性 / キャパシタ材料 / 水素発生反応 / 電極触媒 / 界面合成 / ナノシート / CONASH / ジチオレン / πナノシート / 界面反応 / 錯体 |
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| Outline of Final Research Achievements |
In a ultrahigh vacuum chamber, hexakis(benzylthio)benzene and nickel(0) were co-deposited on a graphite surface and observed its structure using STM. The co-deposition formed a three-dimensional clusters, and sheet-like products were not observed. In the next experiment, Cu(111) surface, which is supposed to interact more strongly with molecules, was employed for the deposition of hexakis(benzylthio)benzene. Several ordered structures were observed on a whole surface by STM. The formation of clear large two-dimensional sheet-like structure has not been confirmed yet, but the ordered alignment of ligand-originated molecules and metal atoms was observed in a restricted area.
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Report
(4 results)
Research Products
(47 results)
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[Journal Article] Oxidation-Promoted Interfacial Synthesis of Redox-Active Bis(diimino)nickel Nanosheet2018
Author(s)
Eunice J H Phua, Kuo-Hui Wu, Keisuke Wada, Tetsuro Kusamoto, Hiroaki Maeda, Jian Cao, Ryota Sakamoto, Hiroyasu Masunaga, Sono Sasaki, Jia-Wei Mei, Wei Jiang, Feng Liu, Hiroshi Nishihara
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Journal Title
Chemistry Letters
Volume: 47
Issue: 2
Pages: 126-129
DOI
NAID
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] The coordination nanosheet (CONASH)2016
Author(s)
Ryota Sakamoto, Kenji Takada, Xinsen Sun, Tigmansu Pal, Takamasa Tsukamoto, Eunice Jia Han Phua, Amalia Rapakousiou, Ken Hoshiko, Hiroshi Nishihara
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Journal Title
Coord. Chem. Rev.
Volume: 未決定
Pages: 118-128
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Presentation] 配位プログラミングと界面2017
Author(s)
西原 寛
Organizer
分子研研究会「金属錯体の情報制御と機能連動」
Place of Presentation
分子科学研究所（愛知県岡崎市）
Year and Date
2017-03-06
Related Report
Invited
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[Presentation] 配位プログラミングの科学2016
Author(s)
西原 寛
Organizer
新学術領域研究 配位アシンメトリー全体会議
Place of Presentation
東京大学本郷キャンパス （東京都文京区）
Year and Date
2016-09-24
Related Report
Invited
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