| Project/Area Number |
15K13655
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Nagoya University |
|---|
Principal Investigator |
Ohki Yasuhiro 名古屋大学, 理学研究科, 准教授 (10324394)
|
|---|
| Project Period (FY) |
2015-04-01 – 2017-03-31
|
| Project Status |
Completed (Fiscal Year 2016)
|
| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
|---|
| Keywords | クラスター / 鉄 / コバルト / ヒドリド / ホスフィン |
|---|
| Outline of Final Research Achievements |
A series of hydride-supported Co and Fe cluster molecules were synthesized from one-pot, sigma-bond metathesis-type reactions in non-polar organic solvents, by using M(II) amide complexes M{N(SiMe3)2}2 (M = Co, Fe) and pinacolborane in the presence/absence of phosphines. The new Co and Fe clusters were identified by means of an X-ray crystallographic study as well as various spectroscopic techniques including the infrared, mass, and 57Fe Mossbauer spectra, though the NMR spectrum was not useful due to their paramagnetism.
|
