Synthesis and functionality of hydride-based coordination framework
| Project/Area Number |
15K13657
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
HORIKE SATOSHI 京都大学, 物質－細胞統合システム拠点, 准教授 (70552652)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 配位高分子 / X線回折 / ヒドリド / ガス吸着 / 二酸化炭素還元 / 固相合成 / ヒドリドイオン |
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| Outline of Final Research Achievements |
Anion form of hydrogen atom is hydride (H-) and H- is widely used as a reductant agent for organic reaction. They are used in liquid state, whereas the control of reactivity and mobility of H- in solid state is a challenge. We incorporated H- species in solid state by use of coordination polymer crystal composed of metal ions and bridging ligands. Optimized synthetic condition of coordination polymer enabled to accommodate H- with different reactivity, and some materials showed high reductant activity for CO2 and other small gases in solid state.
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Report
(3 results)
Research Products
(20 results)
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[Journal Article] Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application2016
Author(s)
Munehiro Inukai, Satoshi Horike, Tomoya Itakura, Ryota Shinozaki, Naoki Ogiwara, Daiki Umeyama, Sanjog Nagarkar, Yusuke Nishiyama, Michal Malon, Akari Hayashi, Takashi Ohhara, Ryoji Kiyanagi, Susumu Kitagawa
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Journal Title
J. Am. Chem. Soc.
Volume: 138
Issue: 27
Pages: 8505-8511
DOI
Related Report
Peer Reviewed
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