| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
|---|
| Outline of Final Research Achievements |
Anion form of hydrogen atom is hydride (H-) and H- is widely used as a reductant agent for organic reaction. They are used in liquid state, whereas the control of reactivity and mobility of H- in solid state is a challenge. We incorporated H- species in solid state by use of coordination polymer crystal composed of metal ions and bridging ligands. Optimized synthetic condition of coordination polymer enabled to accommodate H- with different reactivity, and some materials showed high reductant activity for CO2 and other small gases in solid state.
|
