| Project/Area Number |
15K13658
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kwansei Gakuin University |
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Principal Investigator |
Tanaka Daisuke 関西学院大学, 理工学部, 准教授 (60589399)
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| Co-Investigator(Renkei-kenkyūsha) |
YAMADA Toyokazu 千葉大学, 大学院融合科学研究科, 准教授 (10383548)
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | STM / 原子価互変異性 / 単分子膜 / 原子価互変異性錯体 / 金属錯体 / ナノ材料化学 |
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| Outline of Final Research Achievements |
Valence tautomerism (VT) is attractive property for single molecular memory devices. In this research, we observed a two dimensional periodic self-assembled monolayer of Co-VT complexes with long alkyl chains, whose cobalt center shows a thermal bistability of VT molecular interconversion in a bulk crystal. The Scanning Tunneling Microscopy (STM) observation have demonstrated the periodic structure of Co-VT complexes on highly ordered pyrolytic graphite (HOPG) at room temperature under nitrogen atmosphere. We also determined the two dimensional crystal structure of PtCl2(C8, 10bpy) (C8, 10bpy =4,4'-bis(3-octytridecyl) -2,2'bipyridine) on HOPG by STM.
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