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Development of transition metal catalytic system converting halosilane into hydrosilane

Research Project

Project/Area Number 15K13662
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

NAKAZAWA Hiroshi  大阪市立大学, 大学院理学研究科, 教授 (00172297)

Co-Investigator(Kenkyū-buntansha) 鎌田 幸司  大阪市立大学, 大学院理学研究科, 特任講師 (20713902) [Withdrawn]
板崎 真澄  大阪市立大学, 大学院理学研究科, 講師 (60382032)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsクロロシラン / ヒドロシラン / 還元反応
Outline of Final Research Achievements

Si-H is an important bond because it is readily converted into various Si-X bonds. An Si-H bond has been prepared by the reaction of an Si-Cl bond with LiAlH4. However, LiAlH4 is too strong to reduce an undesired portion. In this project, we found that NaBH4, a milder reducing reagent, can convert an Si-Cl bond into an Si-H bond without reducing another portion. The reaction was completed by 15 min stirring at room temperature in acetonitrile.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report

Research Products

(62 results)

All 2017 2016 2015 Other

All Int'l Joint Research Journal Article Presentation Book Remarks Patent(Industrial Property Rights)

  • [Int'l Joint Research] CNRS(フランス)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Hydrogenation of Chlorosilanes by NaBH<sub>4</sub>2017

    • Author(s)
      M. Ito, M. Itazaki, T. Abe. H. Nakazawa
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 12 Pages: 1434-1436

    • DOI
      10.1246/cl.160808
    • NAID
      130005475731
    • Year and Date
      2017-03-24
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Saturated Heavier Group 14 Compounds as sigma-Electron Acceptor (Z-type) Ligands2017

    • Author(s)
      K. Kameo, H. Nakazawa
    • Journal Title

      The Chemical Record

      Volume: 17 Pages: 268-286

    • DOI
      10.1002/tcr.201600061
    • NAID
      120006453319
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands2017

    • Author(s)
      Y. Toya, K. Hayasaka, H. Nakazawa
    • Journal Title

      Organometallics

      Volume: 36

    • DOI
      10.1021/acs.organomet.7b00087
    • NAID
      120006464450
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and Theoretical Study of Si-;Cl and Ge-Cl σ-Bond Activation Reactions by Iridium-Hydride2016

    • Author(s)
      Hajime Kameo,* Koki Ikeda, Sakaki Shigeyoshi, Hiroshi Nakazawa, Shin Takemoto, Hiroyuki Matsuzaka
    • Journal Title

      Dalton Trans.

      Volume: 45 Pages: 7570-7580

    • DOI
      10.1039/c6dt00003g
    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tetrahedral cage complex with planar vertices: selective synthesis of Pt4L6 cage complexes involving hydrogen bonds driven by halide binding2016

    • Author(s)
      M. Ito, M. Iseki, M. Itazaki, H. Nakazawa
    • Journal Title

      Chem. Commun.

      Volume: 52 Pages: 7205-7208

    • DOI
      10.1039/c6cc01448h
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective Double-Hydrosilylation of Nitriles Catalyzed by an Iron Complex Containing Indium Trihalide2016

    • Author(s)
      M. Ito, M. Itazaki, H. Nakazawa
    • Journal Title

      ChemCatChem

      Volume: 8 Pages: 3323-3325

    • DOI
      10.1002/cctc.201600940
    • NAID
      120006532430
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] R/X Exchange Reactions on Pd and Pt Complexes Containing Phosphine Ligands, cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a Phosphenium Intermediate and Theoretical Approach2016

    • Author(s)
      M. Itazaki, N. Tsuchida, Y. Shigesato, K. Takano, H. Nakazawa
    • Journal Title

      Dalton Trans.

      Volume: 45 Pages: 19216-19220

    • DOI
      10.1039/c6dt02314b
    • NAID
      120006376423
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Transition Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions2016

    • Author(s)
      Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa
    • Journal Title

      Chem. Euro. J

      Volume: 22 Pages: 2370-2375

    • DOI
      10.1002/chem.201504455
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis and Characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) Containing Two Terminal Indium Fragments2016

    • Author(s)
      Masumi Itazaki, Masaki Ito, Hiroshi Nakazawa
    • Journal Title

      Dalton Trans.

      Volume: 45 Pages: 1327-1330

    • DOI
      10.1039/c5dt03745j
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines2016

    • Author(s)
      Masumi Itazaki, Shinya Katsube, Masahiro Kamitani, Hiroshi Nakazawa
    • Journal Title

      Chem. Commun.

      Volume: 52 Pages: 3163-3166

    • DOI
      10.1039/c5cc10185a
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly Effective Olefin Hydrosilylation Catalyzed by Iron Complexes with Iminobipyridine Ligand2016

    • Author(s)
      K. Hayasaka, K. Kamata, H. Nakazawa
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 89 Pages: 394-404

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Transition Metal-Mediated Ge-F Activation: Inverse Electron Flow in s-Bond Metathesis2016

    • Author(s)
      Hajime Kameo,* Koki Ikeda, Didier Bourissou, Shigeyoshi Sakaki, Shin Takemoto, Hiroshi Nakazawa, Hiroyuki Matsuzaka
    • Journal Title

      Organometallics

      Volume: 35 Pages: 713-719

    • DOI
      10.1021/acs.organomet.5b01000
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Evaluation of the sigma-Donation from Group 11 Metals (Cu, Ag, Au) to Silane, Germane, and Stannane Based on the Experimental / Theoretical Systematic Approach2015

    • Author(s)
      H. Kameo, T. Kawamoto, D. Bourissou, S. Sakaki, H. Nakazawa
    • Journal Title

      Organometallics

      Volume: 34 Pages: 1440-1448

    • DOI
      10.1021/om501159v
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Coordination of a Triphosphine-Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction2015

    • Author(s)
      P. Gualco, S. Mallet-Ladeira, H. Kameo, H. Nakazawa, L. Maron, A. Amgoune, D. Bourissou
    • Journal Title

      Organometallics

      Volume: 34 Pages: 1449-1453

    • DOI
      10.1021/om501154d
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis, Structure and Reactivity of Ruthenium(0) Indane Complex fac-[Ru(NCMe)3(CO)2(InX3)] (X = Cl, Br)2015

    • Author(s)
      M. Itazaki, M. Ito, H. Nakazawa
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 未定 Pages: 2033-2036

    • DOI
      10.1002/ejic.201500112
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dehydrogenative Coupling of Alcohol with Hydrosilane Catalyzed by an Iron Complex2015

    • Author(s)
      K. Fukumoto, M. Kasa, H. Nakazawa
    • Journal Title

      Inorg. Chim. Acta

      Volume: 未定 Pages: 219-221

    • DOI
      10.1016/j.ica.2015.02.019
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] TiCl4-promoted Condensation of Methyl Acetoacetate, Isobutyraldehyde, and Indole: A Theoretical and Experimental Study2015

    • Author(s)
      A. Renzetti, A. Marrone, S. Gerard, J. Sapi, H. Nakazawa, N. Re, A. Fontana
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Pages: 8964-8972

    • DOI
      10.1039/c4cp05412a
    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rhodium(I) and iridium(I) imidazo[1,5-a]pyridine-1-ylalkylalkoxy complexes: synthesis, characterization and application as catalysts for hydrosilylation of alkynes2015

    • Author(s)
      T. Murai, E. Nagaya, F. Shibahara, T. Maruyama, H. Nakazawa
    • Journal Title

      J. Organomet. Chem.

      Volume: 794 Pages: 76-80

    • DOI
      10.1016/j.jorganchem.2015.05.045
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] イミノビピリジン鉄錯体触媒によるカルボニル化合物のヒドロシリル化反応2017

    • Author(s)
      泉森陽介、戸谷有希、早坂和将、中沢 浩
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、神奈川県、横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2-ピリジニルベンジルアルコールをnon-innocent配位子として有する鉄錯体による触媒的アルコール脱水素反応2017

    • Author(s)
      鈴木総一郎、神谷昌弘、中沢 浩、弓削秀隆
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、神奈川県、横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Carbon-Sulfur bond cleavage by an iron complex2017

    • Author(s)
      Fukumoto Kozo, Oshiro Sayaka, Teruya Toshiaki, Nakazawa Hiroshi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、神奈川県、横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] イミノビピリジン鉄錯体を触媒とするジエンのヒドロシリル化反応2017

    • Author(s)
      寺谷清香、戸谷有希、早坂和将、中沢 浩
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、神奈川県、横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Design of Iron Catalyst for Hydrosilylation of Olefin2016

    • Author(s)
      Kazumasa Hayasaka, Yuki Toya, Hiroshi Nakazawa
    • Organizer
      The 23rd International SPACC Symposium -Functional complexes and their new applications-
    • Place of Presentation
      Okayama University of Science, Okayama, Japan
    • Year and Date
      2016-11-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrosilylation of Alkene Mediated by an Iron Complex Bearing an Iminobilyridine Ligand2016

    • Author(s)
      Yuki Toya, Kazumasa Hayasaka, Hiroshi Nakazawa
    • Organizer
      The 23rd International SPACC Symposium -Functional complexes and their new applications-
    • Place of Presentation
      Okayama University of Science, Okayama, Japan
    • Year and Date
      2016-11-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ハロゲン化インジウムを有する鉄錯体を触媒として用いた選択的ダブルヒドロシリル化、ダブルヒドロボリル化およびジヒドロシリルボリル化反応の開発2016

    • Author(s)
      伊藤昌樹、板崎真澄、中沢 浩
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀、東京都、江戸川区
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] イリジウムヒドリド錯体によるSi-FおよびGe-F結合切断反応に関する実験および理論的研究2016

    • Author(s)
      亀尾 肇、榊 茂好、中沢 浩、松坂裕之
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学、西早稲田キャンパス、東京都、新宿区
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉄錯体触媒を用いたC≡C 三重結合への段階的なP-H結合付加反応2016

    • Author(s)
      板崎真澄、勝部伸哉、後田朋哉、中沢 浩
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学、西早稲田キャンパス、東京都、新宿区
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉄錯体を用いた新しい触媒反応の開発2016

    • Author(s)
      中沢 浩
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学、福岡県、福岡市
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Syntheses of Cage-Ahaped Complexes with Platinum or Palladium Planar Vertices and Their Structures -Reactions of Dihalogeno Platium or Palladium Complexes with Phosphinecarboxyakide-2016

    • Author(s)
      M. Ito, M. Iseki, M. Itazaki, T.Otani, H. Nakazawa
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学、福岡県、福岡市
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] ハロゲン化インジウムを配位子とするルテニウム錯体の反応性2016

    • Author(s)
      板崎真澄、土橋由夏子、伊藤昌輝、中沢 浩
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学、福岡県、福岡市
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Non-innocent 配位子を有する鉄錯体触媒によるアルコール脱水素反応2016

    • Author(s)
      鈴木聡一郎、神谷昌宏、小林真道、中沢 浩、弓削秀隆
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学、福岡県、福岡市
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effective Dehydrogenation of Alcohol Catalyzed by Iron Complexes2016

    • Author(s)
      Hiroshi Nakazawa
    • Organizer
      2nd World Chemistry Conference
    • Place of Presentation
      Toronto, Canada
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 平面四配位白金錯体を頂点構造とする白金四核かご状錯体 Pt4L6 の選択的合成2016

    • Author(s)
      伊藤昌輝、井関柾登、板崎真澄、中沢 浩
    • Organizer
      第14回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      高知城ホール、高知県、高知市
    • Year and Date
      2016-06-04
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉄錯体触媒を用いたアリールアルキンの位置選択的はヒドロチオ化反応2016

    • Author(s)
      板崎真澄、後田朋哉、勝部伸哉、中村 渉、中沢 浩
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市多々羅都谷)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 2つの異なるNon-innocent配位子を有する立つ錯体の合成とアルコールに対する反応性2016

    • Author(s)
      小林真道、中沢 浩、弓削秀隆
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市多々羅都谷)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Synthesis of palladium complexes bearing s-electron ligand of silane, germane and stannane2016

    • Author(s)
      K. Kinoshita, T. Kawamoto, H. Kameo, H. Nakazawa, H. Matsuzaka
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市多々羅都谷)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Selective Strong Bond Cleavage Catalyzed by Transition Metal Complexes2016

    • Author(s)
      H. Nakazawa
    • Organizer
      Queen’s University Seminar
    • Place of Presentation
      Kingston, Canada
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Selective Bond Formation between Hetero Atoms Catalyzed by a Transition Metal Complex2015

    • Author(s)
      H. Nakazawa
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Formation of Indium-iron Complexes and the Catalytic Activity toward Double Hydrosilylation of Nitriles2015

    • Author(s)
      M. Ito, M. Itazaki, S. Nakashima, H. Nakazawa
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] R/X Exchange Reaction on Pd and Pt Complexes with Phosphine Ligand, cis-[MR2{P(MeNCH2)2X}2] (M = Pd, Pt) via an Intermediate of Phosphenium Complex2015

    • Author(s)
      M. Itazaki, Y. Shigesato, N Tsuchida, K. Takano, H. Nakazawa
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Amine and Imine from Thioamide through the Desulfurizaiton by Hydrosilane with the Help of an Iron Complex2015

    • Author(s)
      K. Fukumoto, A. Sakai, H. Nakazawa
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] イミノビピリジン鉄触媒によるオレフィンのヒドロシリル化反応―配位子上の置換基が及ぼす影響―2015

    • Author(s)
      戸谷有希、早坂和将、鎌田幸司、中沢 浩
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学(名古屋千種区不老町)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] Regioselective P-H Bond Addition to a Multiple C-C Bond Catalyzed by an Iron Complex2015

    • Author(s)
      S. Katsube, M. Itazaki, H. Nakazawa
    • Organizer
      The 19th Osaka City University International Workshop on Advanced Molecular Materials Science
    • Place of Presentation
      大阪市立大学(大阪府大阪市住吉区杉本
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] C=S Double Bond Cleavage Catalyzed by an Iron Complex2015

    • Author(s)
      H. Nakazawa
    • Organizer
      5th Latin American Symposium on Coordination and Organometallic Chemistry
    • Place of Presentation
      Rio de Janeiro (Brazil)
    • Year and Date
      2015-10-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] インジウム配位子を有する鉄錯体を用いたニトリル化合物の触媒的ダブルヒドロシリル化反応の開発2015

    • Author(s)
      伊藤昌樹、板崎真澄、中沢 浩
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区船堀)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 1,1’-ビス(フェニルホスフィノ)フェロセンと0価白金ホスフィン錯体の反応―生成錯体の構造とホスフィン配位子の関係―2015

    • Author(s)
      板崎真澄、市山友紀、久保田陽子、中沢 浩
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良市北魚屋東町)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 遷移金属錯体によるE-X結合 (E = Si, Ge; X = halogen)の切断とその反応機構の研究2015

    • Author(s)
      池田耕己、亀尾 肇、中沢 浩、松坂裕之
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Catalytic Hydrosilylation of Olefin with Hydrosilane Using an Iminobipyridine Iron Complex2015

    • Author(s)
      K. Hayasaka, K. Kamata, H. Nakazawa
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良市北魚屋東町)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] イミノビピリジン鉄錯体による触媒的オレフィンのヒドロシリル化反応2015

    • Author(s)
      早坂和将、鎌田幸司、中沢 浩
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学(大阪府吹田市山手町)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 3つのホスフィンドナーを有する七配位スズ化合物の合成2015

    • Author(s)
      亀尾 肇、川本達也、松坂裕之、中沢 浩
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学(大阪府吹田市山手町)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] インジウム-鉄混合金属錯体を配位子として用いたニトリルの選択的ダブルヒドロシリル化反応によるジシリルアミン合成反応2015

    • Author(s)
      伊藤昌輝、板崎真澄、中島 覚、中沢 浩
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学(大阪府吹田市山手町)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Dehydrogenation of Alcohol Catalyzed by Iron Complexes2015

    • Author(s)
      H. Nakazawa
    • Organizer
      5th Asian Conference on Coordination Chemistry
    • Place of Presentation
      Hong Kong (China)
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] 高校生・化学宣言PART9~高校化学グランドコンテストドキュメンタリー~2016

    • Author(s)
      中沢 浩、松坂裕之
    • Total Pages
      223
    • Publisher
      遊タイム出版
    • Related Report
      2016 Annual Research Report
  • [Book] Topics in Organometallic Chemistry Vol. 50 "Iron Catalysis II "2015

    • Author(s)
      M. Itazaki and H. Nakazawa
    • Total Pages
      361
    • Publisher
      Springer
    • Related Report
      2015 Research-status Report
  • [Book] 高校生・化学宣言PART8~高校化学グランドコンテストドキュメンタリー~2015

    • Author(s)
      中沢 浩、松坂裕之
    • Total Pages
      215
    • Publisher
      遊タイム出版
    • Related Report
      2015 Research-status Report
  • [Remarks] Coordination Chemistry Lab

    • URL
      http://www.sci.osaka-cu.ac.jp/chem/cc/indedx.html
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法2017

    • Inventor(s)
      中沢 浩、早坂将和、泉森陽介、島田 茂、佐藤一彦
    • Industrial Property Rights Holder
      中沢 浩、早坂将和、泉森陽介、島田 茂、佐藤一彦
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-011219
    • Filing Date
      2017-01-25
    • Application Year
      2017
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 鉄錯体化合物とそれを用いた有機ケイ素化合物の製造方法2016

    • Inventor(s)
      中沢 浩、早坂和将、佐藤一彦、島田 茂
    • Industrial Property Rights Holder
      中沢 浩、早坂和将、佐藤一彦、島田 茂
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-06-21
    • Application Year
      2016
    • Related Report
      2016 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 鉄錯体触媒を用いたヒドロシランの脱水素縮合反応によるポリシランの製造方法2016

    • Inventor(s)
      中沢 浩、早坂和将、西村峻也、島田 茂、佐藤一彦
    • Industrial Property Rights Holder
      中沢 浩、早坂和将、西村峻也、島田 茂、佐藤一彦
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-241493
    • Filing Date
      2016-12-13
    • Application Year
      2016
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素化ケイ素化合物の製造方法2016

    • Inventor(s)
      中沢 浩、阿部 剛
    • Industrial Property Rights Holder
      中沢 浩、阿部 剛
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-046220
    • Filing Date
      2016-03-09
    • Application Year
      2016
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 鉄錯体化合物とそれを用いた有機ケイ素化合物の製造方法2015

    • Inventor(s)
      中沢 浩、島田 茂、佐藤一彦
    • Industrial Property Rights Holder
      中沢 浩、島田 茂、佐藤一彦
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-125522
    • Filing Date
      2015-06-23
    • Application Year
      2015
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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