| Project/Area Number |
15K13684
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
HILL Jonathan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)
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| Co-Investigator(Renkei-kenkyūsha) |
Labuta Jan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 独立研究者 (00720690)
Matsushita Yoshitaka 国立研究開発法人物質・材料研究機構, 技術開発・共用部門 材料分析ステーション 化学分析・X線回折グループ, グループリーダー (70422441)
Wakayama Yutaka 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点 量子デバイス工学グループ, グループリーダー (00354332)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | Acene / Proton conductor / Pyrazinacene / Tautomerism |
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| Outline of Final Research Achievements |
A class of linear acenes containing up to 14 nitrogen atoms has been prepared. These are the longest ‘pyrazinacene’ compounds prepared to date. The compounds have been characterized by chemical methods and crystallography. If compounds contained reduced rings (i.e. have hydrogen atoms) they were found to be delocalized, as predicted. Several compounds were studied for self-assembly on surfaces and were found to form polymeric structures. Some of the compounds were found to be useful for solar cell applications. The compounds were also found to be highly useful as organic catalysts based on the presence of the exchangeable protons and photosensitivity, as discovered in this work.
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