| Project/Area Number |
15K13689
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Koike Takashi 東京工業大学, 科学技術創成研究院, 助教 (30451991)
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| Research Collaborator |
MIYAZAWA Kazuki
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 光触媒 / アミノ化 / 窒素ラジカル / ラジカル反応 / 太陽光 / 可視光 / アミノアルコール / イミダゾリン |
|---|
| Outline of Final Research Achievements |
Photoredox catalysis has been regarded as a useful tool for radical reactions because it can catalyze single-electron-transfer processes under visible light irradiation. We have developed new nitrogen-centered radical precursors, 1-aminopyridinium salts and 1-iminopyridinium ylides. Photocatalytic aminohydroxylation of olefins, which results in production of useful 1,2-aminoalcohols, was achieved by combination of photoredox catalysis and new aminating reagents.
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