Development of a novel synthetic system for preparation of pi-conjugated oligomers
Project/Area Number |
15K13691
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Synthetic chemistry
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Research Institution | Yokohama National University |
Principal Investigator |
Atobe Mahito 横浜国立大学, 大学院環境情報研究院, 教授 (90291351)
|
Project Period (FY) |
2015-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2016)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | 反応場 / マイクロリアクター / 電解合成 |
Outline of Final Research Achievements |
Oligothiophenes have been used in many high-technological applications including OLEDs, OFETs and OPVs. However, their synthesis is usually required complicated multi-step processes and toxic transition metal catalysts. On the other hand, the integrated use of microflow technology for organic electrosynthesis would offer one of the most sophisticated processes in organic chemistry. In the present work, we have successfully developed the novel electrosynthetic system for the preparation of oligothiophenes without their deposition using a flow microreactor. Molecular weight and its distribution of oligothiophenes could be controlled by selecting the reaction conditions.
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Report
(3 results)
Research Products
(34 results)