| Project/Area Number |
15K13755
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 二酸化炭素 / 均一系触媒 / 不均一系触媒 / コバルト / マグネシウム / エポキシド / 環状炭酸エステル / ニッケル / アリールトリフラート / アルケニルトリフラート |
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| Outline of Final Research Achievements |
Transformation that regenerates carbon dioxide into organic resources is one of important research subjects. In this research, we have studied aiming at the development of a catalyst system driven by light energy. We developed cobalt and nickel catalyzed carboxylation reaction of alkenyl and aryl triflates using carbon dioxide. We also found that magnesium chloride, which is inexpensive and easily available, is a useful catalyst for the synthesis of cyclic carbonate from epoxide and carbon dioxide.
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